reagent, catalyst or environment. Asymmetric induction is a key element in asymmetric synthesis. Asymmetric induction was introduced by Hermann Emil Fischer...

through interactions at the transition state. This biasing is known as asymmetric induction and can involve chiral features in the substrate, reagent, catalyst...

effect, change in electron density Asymmetric induction, preferring one stereoisomer over another Grammar induction Inductive bias Inductive probability...

carbonyl groups. The catalysts were found to afford high levels of asymmetric induction in several processes, including the ene reaction of ethyl glyoxylate...

used in Sharpless asymmetric dihydroxylation While the presence of any symmetry element within a ligand intended for asymmetric induction might appear counterintuitive...

Sharpless asymmetric dihydroxylation (also called the Sharpless bishydroxylation) is the chemical reaction of an alkene with osmium tetroxide in the presence...

Asymmetric induction in allylic alkylations." J. Am. Chem. Soc. 1973, 95, 8200–8201. doi:10.1021/ja00805a056. Trost, B. M.; Strege, P. E. "Asymmetric...

"Preparation of an Optically Active Prostaglandin Intermediate via Asymmetric Induction". J. Am. Chem. Soc. 97 (23): 6908–6909. Bibcode:1975JAChS..97.6908C...

Asymmetric hydrogenation is a chemical reaction that adds two atoms of hydrogen to a target (substrate) molecule with three-dimensional spatial selectivity...

predictable stereodirecting effects resulting in high levels of asymmetric induction. Racemization of the newly created carbon-nitrogen stereo center...

structure. He also did work in stereochemistry and Cram's rule of asymmetric induction is named after him. In 1973, Cram collaborated on research with Irish...

chiral auxiliaries and chiral catalysts, and the application of asymmetric induction. The use of enzymes (biocatalysis) may also produce the desired compound...

Bunt, Richard C. (2012). "Investigation of the Electronic Origin of Asymmetric Induction in Palladium-Catalyzed Allylic Substitutions with Phosphinooxazoline...

transfer of an H2 molecule from the reductant to the substrate. Asymmetric induction in transition metal catalyzed reactions is achieved through the use...

employing chiral starting materials have been used to effect either asymmetric induction or simple diastereoselection (1) After carbanion formation, the [2...

2010. Other chiral additives can be used as the initial source of asymmetric induction, with the major product of that first reaction being rapidly amplified...

in particular Rh2[(S)-DOSP]4 and Rh2[(S)-BPTV]4 can induce modest asymmetric induction and was used to synthesize the antifungal agent pseudolaric acid...

= OR*). (1) Asymmetric versions of the above reaction have taken advantage of a number of strategies for achieving asymmetric induction. The highest...

enantioselective way. Ruppert's reagent has been used for this purpose in an asymmetric induction approach to functionalise chiral amino acid derivates, saccharides...

chiral chemical synthesis, and specifically of the phenomenon of asymmetric induction during nucleophilic attack at hindered carbonyl centers (see the...

potential application is its use as a temporary substituent promoting asymmetric induction for example in this diastereoselective one-pot reaction involving...

et al. (1981). "Asymmetric total synthesis of erythromcin. 1. Synthesis of an erythronolide A secoacid derivative via asymmetric induction". J. Am. Chem...

(see below) In 2004 Node obtained (−)-galanthamine via a remote asymmetric induction method with starting chiral compound D-phenylalanine. Brown prepared...

"Studies in Stereochemistry. X. The Rule of "Steric Control of Asymmetric Induction" in the Syntheses of Acyclic Systems". Journal of the American Chemical...

(3 January 2014). "Foldamer-Mediated Remote Stereocontrol: >1,60 Asymmetric Induction" (PDF). Angewandte Chemie International Edition. 53 (1): 151–155...

the imine, which generally results in a trans product. Reviews on asymmetric induction of the Staudinger synthesis, including the use of organic and organometallic...

discrimination between these possible enantiomers that requires asymmetric induction. Torquoselectivity is also used to describe selective electrocyclic...

one enantiomer or diastereomer over the other is formally known as asymmetric induction. In this kind of Lewis acid, the electron-accepting atom is typically...

rearrangement Coupling reaction Crabbé reaction Craig method Cram's rule of asymmetric induction Creighton process Criegee reaction Criegee rearrangement Cross metathesis...

Etter, Jeffrey B. (1987). "Lanthanides in organic synthesis. 8. 1.3-Asymmetric induction in intramolecular Reformatskii-type reactions promoted by samarium...