A cyclopentadienyl complex is a coordination complex of a metal and cyclopentadienyl groups (C 5H− 5, abbreviated as Cp−). Cyclopentadienyl ligands almost...
7 KB (818 words) - 04:02, 11 November 2024
Ferrocene (redirect from Iron cyclopentadienyl)
compound with the formula Fe(C5H5)2. The molecule is a complex consisting of two cyclopentadienyl rings sandwiching a central iron atom. It is an orange...
55 KB (5,401 words) - 20:11, 4 May 2025
Sodium cyclopentadienide (redirect from Cyclopentadienyl radical)
Johannes Thiele. In 1901 there was not much interest in the topic. Sodium cyclopentadienyl is prepared by treating cyclopentadiene with sodium: 2 Na + 2 C5H6...
8 KB (797 words) - 19:12, 28 April 2025
"WCl4(DME): a facile entry into bis(cyclopentadienyl) complexes of tungsten(IV). Synthesis of bis(cyclopentadienyl)tungsten dihydride". Organometallics...
59 KB (6,130 words) - 02:50, 3 March 2025
Methylcyclopentadienyl manganese tricarbonyl (redirect from Cyclopentadienyl manganese thiocarbonate)
thermal runaway. MMT is a so-called half-sandwich complex, or more specifically a "piano-stool" complex (since the three CO ligands are like the legs of...
19 KB (2,079 words) - 22:26, 15 February 2025
Nickelocene (redirect from Bis(cyclopentadienyl)nickel(II))
organonickel compound with the formula Ni(η5-C5H5)2. Also known as bis(cyclopentadienyl)nickel or NiCp2, this bright green paramagnetic solid is of enduring...
8 KB (650 words) - 03:53, 12 December 2024
η5cyclopentadienyl anion (Cp), thus indenyl analogues of many cyclopentadienyl complexes are known. Indenyl ligands lack the 5-fold symmetry of Cp, so...
12 KB (1,349 words) - 17:46, 30 September 2023
structure of dicarbonyl-η5-cyclopentadienyl-(η2-tetramethylallenyl)iron tetrafluoroborate. A sterically crowded allene complex". Journal of the Chemical...
25 KB (2,548 words) - 20:07, 4 April 2025
The Knölker complex is an organoiron compound, which is a catalyst for transfer hydrogenation. The complex features an hydroxycyclopentadienyl ligand bound...
3 KB (198 words) - 05:34, 22 January 2025
Cyclopentadienyl magnesium bromide is a chemical compound with the molecular formula C5H5MgBr. The molecule consists of a magnesium atom bonded to a bromine...
2 KB (173 words) - 18:47, 18 July 2023
dichloride are more prevalent. Complexes are typically prepared by treatment of NbCl5 with NaCp to form the bis(cyclopentadienyl) complex followed by further functionalization...
9 KB (906 words) - 21:35, 27 March 2025
Bis(cyclopentadienyl)titanium(III) chloride, also known as the Nugent–RajanBabu reagent, is the organotitanium compound which exists as a dimer with the...
25 KB (2,319 words) - 00:35, 22 November 2024
popularly used as a precursor to the cyclopentadienyl anion (Cp−), an important ligand in cyclopentadienyl complexes in organometallic chemistry. Cyclopentadiene...
13 KB (1,043 words) - 05:40, 13 August 2024
Zirconocene dichloride (category Cyclopentadienyl complexes)
organozirconium compound composed of a zirconium central atom, with two cyclopentadienyl and two chloro ligands. It is a colourless diamagnetic solid that is...
11 KB (986 words) - 20:26, 6 August 2024
Vinylferrocene (category Cyclopentadienyl complexes)
It is a derivative of ferrocene, with a vinyl group attached to one cyclopentadienyl ligand. As the ferrocene analogue of styrene, it is the precursor to...
2 KB (192 words) - 14:10, 2 November 2024
related complex is tris(acetonitrile)cyclopentadienylruthenium hexafluorophosphate, which has three labile MeCN ligands. Chloro(cyclopentadienyl...
5 KB (343 words) - 18:54, 9 June 2024
In the area of organometallic chemistry, a bulky cyclopentadienyl ligand is jargon for a ligand of the type C 5H 5−nR− n where R is a branched alkyl and...
4 KB (328 words) - 19:01, 27 September 2020
Sandwich compound (redirect from Sandwich complex)
are also called bis(cyclopentadienyl)metal complexes. Other arenes can serve as ligands as well. Mixed cyclopentadienyl complexes: M(C5H5)(CnHn). Some...
16 KB (1,590 words) - 11:28, 11 May 2025
Chromocene (redirect from Bis(cyclopentadienyl)chromium(II))
in non-polar organic solvents. It is more formally known as bis(η5-cyclopentadienyl)chromium(II). Ernst Otto Fischer, who shared the 1973 Nobel Prize in...
8 KB (653 words) - 08:07, 29 March 2025
A metallocene is a compound typically consisting of two cyclopentadienyl anions (C 5H− 5, abbreviated Cp) bound to a metal center (M) in the oxidation...
22 KB (2,174 words) - 00:45, 15 January 2025
air-stable red liquid. It has been reported to be the simplest mono-cyclopentadienyl metal complex. It is prepared by treating nickelocene with nitric oxide. Its...
5 KB (316 words) - 08:58, 11 July 2024
Intermetallic (section Complexes)
to describe compounds involving two or more metals such as the cyclopentadienyl complex Cp6Ni2Zn4. A B2 intermetallic compound has equal numbers of atoms...
11 KB (1,130 words) - 14:07, 19 March 2025
Cobaltocene (redirect from Bis(cyclopentadienyl)cobalt(II))
Cobaltocene, known also as bis(cyclopentadienyl)cobalt(II) or even "bis Cp cobalt", is an organocobalt compound with the formula Co(C5H5)2. It is a dark...
8 KB (620 words) - 19:45, 11 April 2025
Magnesocene (category Cyclopentadienyl complexes)
Magnesocene, also known as bis(cyclopentadienyl)magnesium(II) and sometimes abbreviated as MgCp2, is an organometallic compound with the formula Mg(η5-C5H5)2...
15 KB (1,573 words) - 16:01, 4 May 2025
1,1'-Dilithioferrocene (category Cyclopentadienyl complexes)
1,1'-Dilithioferrocene is the organoiron compound with the formula Fe(C5H4Li)2. It is exclusively generated and isolated as a solvate, using either ether...
4 KB (323 words) - 11:59, 11 December 2024
Vanadocene (category Cyclopentadienyl complexes)
Vanadocene, bis(η5-cyclopentadienyl) vanadium, is the organometallic compound with the formula V(C5H5)2, commonly abbreviated Cp2V. It is a violet crystalline...
5 KB (467 words) - 05:36, 16 May 2025
N,N-Dimethylaminomethylferrocene (category Cyclopentadienyl complexes)
N,N-Dimethylaminomethylferrocene is the dimethylaminomethyl derivative of ferrocene, (C5H5)Fe(C5H4CH2N(CH3)2. It is an air-stable, dark-orange syrup that...
3 KB (234 words) - 09:48, 11 February 2025
tantalum alkylidene complexes to yield olefin metathesis products. Some of the first reported organotantalum complexes were cyclopentadienyl derivatives. These...
11 KB (1,148 words) - 21:59, 27 March 2025
Biferrocene (category Cyclopentadienyl complexes)
wherein all cyclopentadienyl rings are coupled into two fulvalene ligands. Biferrocene can easily be converted into a mixed-valence complex, which is called...
4 KB (287 words) - 12:02, 22 April 2025
Titanocene dichloride (redirect from Dichloridobis(η5-cyclopentadienyl)titanium)
effected with TiCl4 or by reaction with SOCl2. The sandwich complex (Cycloheptatrienyl)(cyclopentadienyl)titanium is prepared by treatment of titanocene dichloride...
21 KB (1,771 words) - 20:25, 6 August 2024