• Inner sphere complex is a type of surface complex that refers to the surface chemistry changing a water-surface interface to one without water molecules...
    10 KB (1,360 words) - 09:29, 27 December 2023
  • Inner Sphere may refer to: Inner sphere complex, a type of ion-surface binding Inner sphere electron transfer, a chemical reaction involving closely associated...
    284 bytes (67 words) - 16:36, 16 January 2013
  • Inner sphere electron transfer (IS ET) or bonded electron transfer is a redox chemical reaction that proceeds via a covalent linkage—a strong electronic...
    5 KB (636 words) - 12:30, 17 October 2024
  • Thumbnail for Oxisol
    fixation on iron and aluminium oxides (ligand exchange mechanism; inner sphere complex with phosphate). However, many oxisols can be cultivated over a wide...
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  • Thumbnail for Iron(II) perchlorate
    by favoring the formation of an inner sphere complex giving rise to a possible reorganisation of the activated complex. The resulting high activation energy...
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  • Thumbnail for Coordination sphere
    coordination sphere is of interest in computational chemistry. The second coordination sphere can consist of ions (especially in charged complexes), molecules...
    7 KB (723 words) - 07:50, 6 May 2024
  • Manfred Eigen to be present in seawater as both an inner sphere complex and an outer sphere complex. The solubility of such salts is calculated by the...
    29 KB (4,103 words) - 20:14, 13 February 2025
  • ion-pair Solvent-separated ion-pair Cation outer-sphere complex Contact ion-pair (CIP) Cation inner-sphere complex Ion pairs are formed when a cation and anion...
    19 KB (2,555 words) - 17:45, 3 April 2024
  • do not undergo large structural changes. It was extended to include inner sphere electron transfer contributions, in which a change of distances or geometry...
    40 KB (5,700 words) - 13:05, 22 December 2024
  • Thumbnail for Electron transfer
    complexes. In organic chemistry ET is a step in some industrial polymerization reactions. It is foundational to photoredox catalysis. In inner-sphere...
    8 KB (1,005 words) - 01:06, 11 April 2025
  • Thumbnail for Complex plane
    function in the complex plane. It can be useful to think of the complex plane as if it occupied the surface of a sphere. Given a sphere of unit radius...
    31 KB (4,502 words) - 23:12, 6 May 2025
  • Thumbnail for Perchlorate
    hexa-aquo complex in solution. The high activation energy of the cation binding with perchlorate to form a transient inner sphere complex more favourable...
    80 KB (8,889 words) - 12:20, 4 May 2025
  • the metal ion are replaced by ligands, L. The complex is described as an inner-sphere complex. A complex such as [ML](p-q)+ may be described as a contact...
    71 KB (7,653 words) - 21:25, 1 May 2024
  • Thumbnail for Madonna–whore complex
    Stephen's inner conflict and eventual transformation towards the end of the novel. In film, Alfred Hitchcock used the Madonna–whore complex as an important...
    13 KB (1,551 words) - 08:16, 18 March 2025
  • Thumbnail for Coordination complex
    ions can occur via two distinct mechanisms, inner and outer sphere electron transfers. In an inner sphere reaction, a bridging ligand serves as a conduit...
    57 KB (5,547 words) - 23:59, 15 February 2025
  • Thumbnail for Armillary sphere
    armillary sphere (variations are known as spherical astrolabe, armilla, or armil) is a model of objects in the sky (on the celestial sphere), consisting...
    32 KB (4,240 words) - 02:44, 11 March 2025
  • coordinated water molecules to form an inner sphere complex or just some of them for an outer-sphere complex. The complexation reaction is theoretically based...
    39 KB (4,962 words) - 12:59, 16 November 2024
  • Thumbnail for Manganese nodule
    their interlayer like clay minerals and surface complexation by formation of inner sphere complexes at the oxide surface as it is also the case with...
    57 KB (6,844 words) - 02:38, 9 April 2025
  • 6-dimensional sphere S6 has a natural almost complex structure arising from the fact that it is the orthogonal complement of i in the unit sphere of the octonions...
    10 KB (1,311 words) - 18:37, 9 September 2024
  • Thumbnail for Celestial spheres
    The celestial spheres, or celestial orbs, were the fundamental entities of the cosmological models developed by Plato, Eudoxus, Aristotle, Ptolemy, Copernicus...
    44 KB (5,795 words) - 15:07, 22 April 2025
  • for inner sphere electron transfer the participating redox sites undergoing ET become connected by a chemical bridge. Because the ET in outer sphere electron...
    5 KB (566 words) - 22:04, 17 October 2024
  • Thumbnail for Hopf fibration
    bundle or Hopf map) describes a 3-sphere (a hypersphere in four-dimensional space) in terms of circles and an ordinary sphere. Discovered by Heinz Hopf in...
    36 KB (4,813 words) - 13:13, 9 April 2025
  • Thumbnail for Creutz–Taube complex
    understand the intimate details of inner sphere electron transfer, that is, how electrons move from one metal complex to another. The ion is named after...
    4 KB (464 words) - 15:15, 18 December 2023
  • Thumbnail for Hydrogenation of carbon–nitrogen double bonds
    transition metal complexes. For metal catalyzed reactions, the transfer of H2 to the imine can proceed by either inner sphere or outer sphere mechanisms. Relevant...
    8 KB (1,016 words) - 00:16, 14 November 2023
  • sphere mechanism relying on MLC and an inner sphere mechanism is exemplified by cobalt hydrogenation with an amine pincer ligand. In the outer sphere...
    22 KB (2,601 words) - 20:40, 22 July 2024
  • Thumbnail for Chloropentamminecobalt chloride
    Chloropentamminecobalt chloride (category Cobalt complexes)
    Werner's model accounted for the inner sphere ligands being less reactive. In [Co(NH3)5Cl]Cl2, two chloride ions are outer sphere (counter ions) and one is bound...
    6 KB (572 words) - 20:36, 7 May 2025
  • Thumbnail for Endohedral fullerene
    additional atoms, ions, or clusters enclosed within their inner spheres. The first lanthanum C60 complex called La@C60 was synthesized in 1985. The @ (at sign)...
    19 KB (2,304 words) - 00:59, 7 April 2025
  • positive-definite inner product on the Lie algebra determines a left-invariant Riemannian metric on the Lie group. A Berger sphere is a metric so obtained...
    9 KB (1,196 words) - 20:53, 6 May 2025
  • Thumbnail for Inner Mongolia
    the decline of the Mongolian language in some of Inner Mongolia's urban areas and educational spheres, the ethnic identity of the urbanised Chinese-speaking...
    108 KB (10,004 words) - 03:59, 6 May 2025
  • Thumbnail for Manifold
    Manifold (section Sphere)
    {\displaystyle n-1} is the dimension of the sphere. Further examples can be found in the table of Lie groups. A complex manifold is a manifold whose charts take...
    69 KB (9,559 words) - 17:24, 2 May 2025