Inner sphere complex is a type of surface complex that refers to the surface chemistry changing a water-surface interface to one without water molecules...
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Inner Sphere may refer to: Inner sphere complex, a type of ion-surface binding Inner sphere electron transfer, a chemical reaction involving closely associated...
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Inner sphere electron transfer (IS ET) or bonded electron transfer is a redox chemical reaction that proceeds via a covalent linkage—a strong electronic...
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fixation on iron and aluminium oxides (ligand exchange mechanism; inner sphere complex with phosphate). However, many oxisols can be cultivated over a wide...
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by favoring the formation of an inner sphere complex giving rise to a possible reorganisation of the activated complex. The resulting high activation energy...
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coordination sphere is of interest in computational chemistry. The second coordination sphere can consist of ions (especially in charged complexes), molecules...
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Manfred Eigen to be present in seawater as both an inner sphere complex and an outer sphere complex. The solubility of such salts is calculated by the...
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ion-pair Solvent-separated ion-pair Cation outer-sphere complex Contact ion-pair (CIP) Cation inner-sphere complex Ion pairs are formed when a cation and anion...
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Marcus theory (section Inner sphere electron transfer)
do not undergo large structural changes. It was extended to include inner sphere electron transfer contributions, in which a change of distances or geometry...
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complexes. In organic chemistry ET is a step in some industrial polymerization reactions. It is foundational to photoredox catalysis. In inner-sphere...
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function in the complex plane. It can be useful to think of the complex plane as if it occupied the surface of a sphere. Given a sphere of unit radius...
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hexa-aquo complex in solution. The high activation energy of the cation binding with perchlorate to form a transient inner sphere complex more favourable...
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the metal ion are replaced by ligands, L. The complex is described as an inner-sphere complex. A complex such as [ML](p-q)+ may be described as a contact...
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Stephen's inner conflict and eventual transformation towards the end of the novel. In film, Alfred Hitchcock used the Madonna–whore complex as an important...
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ions can occur via two distinct mechanisms, inner and outer sphere electron transfers. In an inner sphere reaction, a bridging ligand serves as a conduit...
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armillary sphere (variations are known as spherical astrolabe, armilla, or armil) is a model of objects in the sky (on the celestial sphere), consisting...
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coordinated water molecules to form an inner sphere complex or just some of them for an outer-sphere complex. The complexation reaction is theoretically based...
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their interlayer like clay minerals and surface complexation by formation of inner sphere complexes at the oxide surface as it is also the case with...
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6-dimensional sphere S6 has a natural almost complex structure arising from the fact that it is the orthogonal complement of i in the unit sphere of the octonions...
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The celestial spheres, or celestial orbs, were the fundamental entities of the cosmological models developed by Plato, Eudoxus, Aristotle, Ptolemy, Copernicus...
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for inner sphere electron transfer the participating redox sites undergoing ET become connected by a chemical bridge. Because the ET in outer sphere electron...
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Hopf fibration (section Fibrations between spheres)
bundle or Hopf map) describes a 3-sphere (a hypersphere in four-dimensional space) in terms of circles and an ordinary sphere. Discovered by Heinz Hopf in...
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understand the intimate details of inner sphere electron transfer, that is, how electrons move from one metal complex to another. The ion is named after...
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transition metal complexes. For metal catalyzed reactions, the transfer of H2 to the imine can proceed by either inner sphere or outer sphere mechanisms. Relevant...
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sphere mechanism relying on MLC and an inner sphere mechanism is exemplified by cobalt hydrogenation with an amine pincer ligand. In the outer sphere...
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Chloropentamminecobalt chloride (category Cobalt complexes)
Werner's model accounted for the inner sphere ligands being less reactive. In [Co(NH3)5Cl]Cl2, two chloride ions are outer sphere (counter ions) and one is bound...
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additional atoms, ions, or clusters enclosed within their inner spheres. The first lanthanum C60 complex called La@C60 was synthesized in 1985. The @ (at sign)...
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positive-definite inner product on the Lie algebra determines a left-invariant Riemannian metric on the Lie group. A Berger sphere is a metric so obtained...
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the decline of the Mongolian language in some of Inner Mongolia's urban areas and educational spheres, the ethnic identity of the urbanised Chinese-speaking...
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