In coordination chemistry, metal ammine complexes are metal complexes containing at least one ammonia (NH3) ligand. "Ammine" is spelled this way for historical...

Some of the simplest members of such complexes are described in metal aquo complexes, metal ammine complexes, Examples: [Co(EDTA)]−, [Co(NH3)6]3+, [Fe(C2O4)3]3-...

of coordination chemistry, Alfred Werner. The cation itself is a metal ammine complex with six ammonia ligands attached to the cobalt(III) ion. [Co(NH3)6]3+...

[Pt(NH3)6]Cl4. It is the chloride salt of the metal ammine complex [Pt(NH3)6]4+. The cation features six ammonia (called ammines in coordination chemistry) ligands...

2 H2O Phosphines are L-type ligands. Unlike most metal ammine complexes, metal phosphine complexes tend to be lipophilic, displaying good solubility in...

[LnMNO] + OH− The reaction is reversible in some cases. In some metal-ammine complexes, the ammonia ligand can be oxidized to nitrosyl: H2O + [Ru(terpy)(bipy)(NH3)]+...

cationic metal ammine complexes such as [Pt(NH3)6]4+ spontaneously convert to the amido derivative: [Pt(NH3)6]4+ ↔ [Pt(NH3)5(NH2)]3+ + H+ Transition metal amides...

[Ni(NH3)6]Cl2. It is the chloride salt of the metal ammine complex [Ni(NH3)6]2+. The cation features six ammonia (called ammines in coordination chemistry) ligands...

complex. For example, water exchange in [Al(H2O)5OH]2+ is 20000 times faster than in [Al(H2O)6]3+. Hydration number Ligand field theory Metal ammine complex...

prominent examples of metal-ammine-chlorides. As indicated in the table below, many hydrates of metal chlorides are molecular complexes. These compounds are...

(disambiguation) Amino (disambiguation) Anime, Japanese animation Metal ammine complex This disambiguation page lists articles associated with the title...

Transition metal complexes of the amido ligand are often produced by salt metathesis reaction or by deprotonation of metal ammine complexes. Bergstrom...

the pi backbonding, the donation of metal d-electrons into the N2 π* orbitals. The related metal ammine complex [Os(NH3)5(N2)]2+ is also known. The dinitrogen...

In organometallic chemistry, transition metal complexes of nitrite describes families of coordination complexes containing one or more nitrite (−NO2) ligands...

like most ions, have integer oxidation states. For example, ruthenium ammine complexes are typically +2 or +3. The fact that the oxidation states are half-integer...

Schweizer's reagent is a metal ammine complex with the formula [Cu(NH3)4(H2O)2](OH)2. This deep-blue compound is used in purifying cellulose. This salt...

sulfate. Well characterized xamples are found with cobalt(III) ammines since these complexes are exchange inert. Monodentate sulfate is found in [Co(tren)(NH3)(SO4)]+...

chloride, [RhCl(NH3)5]Cl2. As for other metal-ammine complexes, the term "ammine" refers to ammonia bound to a metal ion as a ligand. Zinc reduction of this...

A transition metal imidazole complex is a coordination complex that has one or more imidazole ligands. Complexes of imidazole itself are of little practical...

general method for the determination of stability constants of metal-ammine complexes in 1941. The reasons why this occurred at such a late date, nearly...

"Vauquelin’s salt". Magnus's green salt was one of the first examples of a metal ammine complex. Atoji, Masao; Richardson, James W.; Rundle, R. E. (June 1957). "Pt(NH3)4PtCl41"...

forming metal ammine complexes. For historical reasons, ammonia is named ammine in the nomenclature of coordination compounds. One notable ammine complex is...

coordination chemistry and organometallic chemistry, transition metal imido complexes is a coordination compound containing an imido ligand. Imido ligands...

in the cobalt ammine chlorides and to explain many of the previously inexplicable isomers. He resolved the first coordination complex called hexol into...

which features a pair of S-bonded thiosulfate ligands. Simple aquo and ammine complexes are also known. Three binding modes are common: monodentate (κ1-),...

boiling water, acetone, and ethanol. It can be classified as a metal isothiocyanate complex. The chromium atom is surrounded by six nitrogen atoms in an...

directly to the metal. The interactions between the first and second coordination spheres usually involve hydrogen-bonding. For charged complexes, ion pairing...

reconciled the low reactivity of the ammonia molecules present in metal ammine complexes by theorizing that the ammonia molecules were chemically linked...

coordination complexes feature metal atoms of octahedral and tetrahedral shapes, with ammonia and other ligands attached individually to the metal. Werner's...

and ammine and nitro complexes such as [Pt(NH3)4]Cl2, K2[Pt(NO2)4] and platinum nitrate are not considered to be allergenic; neither is the metal. Heavy...