• Thumbnail for Metal ammine complex
    In coordination chemistry, metal ammine complexes are metal complexes containing at least one ammonia (NH3) ligand. "Ammine" is spelled this way for historical...
    15 KB (1,758 words) - 18:29, 10 February 2025
  • Thumbnail for Coordination complex
    Some of the simplest members of such complexes are described in metal aquo complexes, metal ammine complexes, Examples: [Co(EDTA)]−, [Co(NH3)6]3+, [Fe(C2O4)3]3-...
    57 KB (5,547 words) - 11:29, 21 May 2025
  • Thumbnail for Hexaamminecobalt(III) chloride
    Hexaamminecobalt(III) chloride (category Ammine complexes)
    of coordination chemistry, Alfred Werner. The cation itself is a metal ammine complex with six ammonia ligands attached to the cobalt(III) ion. [Co(NH3)6]3+...
    8 KB (665 words) - 21:00, 6 August 2024
  • Thumbnail for Hexaammineplatinum(IV) chloride
    Hexaammineplatinum(IV) chloride (category Ammine complexes)
    [Pt(NH3)6]Cl4. It is the chloride salt of the metal ammine complex [Pt(NH3)6]4+. The cation features six ammonia (called ammines in coordination chemistry) ligands...
    3 KB (180 words) - 12:16, 13 January 2025
  • Thumbnail for Metal amides
    cationic metal ammine complexes such as [Pt(NH3)6]4+ spontaneously convert to the amido derivative: [Pt(NH3)6]4+ ↔ [Pt(NH3)5(NH2)]3+ + H+ Transition metal amides...
    7 KB (777 words) - 10:45, 29 June 2024
  • Thumbnail for Metal nitrosyl complex
    [LnMNO] + OH− The reaction is reversible in some cases. In some metal-ammine complexes, the ammonia ligand can be oxidized to nitrosyl: H2O + [Ru(terpy)(bipy)(NH3)]+...
    18 KB (2,128 words) - 16:41, 4 April 2025
  • Thumbnail for Hexaamminenickel chloride
    Hexaamminenickel chloride (category Ammine complexes)
    [Ni(NH3)6]Cl2. It is the chloride salt of the metal ammine complex [Ni(NH3)6]2+. The cation features six ammonia (called ammines in coordination chemistry) ligands...
    4 KB (256 words) - 09:21, 6 January 2025
  • complex. For example, water exchange in [Al(H2O)5OH]2+ is 20000 times faster than in [Al(H2O)6]3+. Hydration number Ligand field theory Metal ammine complex...
    15 KB (1,560 words) - 10:27, 14 May 2025
  • Thumbnail for Metal-phosphine complex
    2 H2O Phosphines are L-type ligands. Unlike most metal ammine complexes, metal phosphine complexes tend to be lipophilic, displaying good solubility in...
    14 KB (1,418 words) - 17:55, 22 June 2024
  • Thumbnail for Transition metal chloride complex
    prominent examples of metal-ammine-chlorides. As indicated in the table below, many hydrates of metal chlorides are molecular complexes. These compounds are...
    61 KB (3,492 words) - 19:29, 25 March 2025
  • (disambiguation) Amino (disambiguation) Anime, Japanese animation Metal ammine complex This disambiguation page lists articles associated with the title...
    419 bytes (87 words) - 16:31, 31 October 2022
  • Thumbnail for Azanide
    Transition metal complexes of the amido ligand are often produced by salt metathesis reaction or by deprotonation of metal ammine complexes. Bergstrom...
    4 KB (277 words) - 11:05, 22 October 2024
  • Thumbnail for Creutz–Taube complex
    like most ions, have integer oxidation states. For example, ruthenium ammine complexes are typically +2 or +3. The fact that the oxidation states are half-integer...
    4 KB (464 words) - 15:15, 18 December 2023
  • Thumbnail for Transition metal nitrite complex
    In organometallic chemistry, transition metal complexes of nitrite describes families of coordination complexes containing one or more nitrite (−NO2) ligands...
    9 KB (1,029 words) - 07:15, 5 March 2025
  • Thumbnail for Pentaamine(dinitrogen)ruthenium(II) chloride
    the pi backbonding, the donation of metal d-electrons into the N2 π* orbitals. The related metal ammine complex [Os(NH3)5(N2)]2+ is also known. The dinitrogen...
    5 KB (466 words) - 16:05, 7 April 2024
  • Thumbnail for Schweizer's reagent
    Schweizer's reagent (category Ammine complexes)
    Schweizer's reagent is a metal ammine complex with the formula [Cu(NH3)4(H2O)2](OH)2. This deep-blue compound is used in purifying cellulose. This salt...
    7 KB (734 words) - 16:45, 20 November 2024
  • Thumbnail for Transition metal sulfate complex
    sulfate. Well characterized xamples are found with cobalt(III) ammines since these complexes are exchange inert. Monodentate sulfate is found in [Co(tren)(NH3)(SO4)]+...
    8 KB (826 words) - 02:05, 3 January 2025
  • Thumbnail for Magnus's green salt
    Magnus's green salt (category Ammine complexes)
    "Vauquelin’s salt". Magnus's green salt was one of the first examples of a metal ammine complex. Atoji, Masao; Richardson, James W.; Rundle, R. E. (June 1957). "Pt(NH3)4PtCl41"...
    6 KB (538 words) - 03:55, 3 March 2025
  • Thumbnail for Transition metal imidazole complex
    A transition metal imidazole complex is a coordination complex that has one or more imidazole ligands. Complexes of imidazole itself are of little practical...
    9 KB (1,011 words) - 18:37, 10 February 2025
  • Thumbnail for Ammonia
    forming metal ammine complexes. For historical reasons, ammonia is named ammine in the nomenclature of coordination compounds. One notable ammine complex is...
    139 KB (15,028 words) - 12:45, 23 May 2025
  • general method for the determination of stability constants of metal-ammine complexes in 1941. The reasons why this occurred at such a late date, nearly...
    60 KB (7,556 words) - 10:18, 14 May 2025
  • Thumbnail for Rhodium(III) chloride
    chloride, [RhCl(NH3)5]Cl2. As for other metal-ammine complexes, the term "ammine" refers to ammonia bound to a metal ion as a ligand. Zinc reduction of this...
    19 KB (1,917 words) - 12:33, 22 May 2025
  • Thumbnail for Transition metal imido complex
    coordination chemistry and organometallic chemistry, transition metal imido complexes is a coordination compound containing an imido ligand. Imido ligands...
    6 KB (514 words) - 16:47, 30 September 2023
  • Thumbnail for Ligand
    in the cobalt ammine chlorides and to explain many of the previously inexplicable isomers. He resolved the first coordination complex called hexol into...
    35 KB (3,307 words) - 14:02, 22 November 2024
  • Platinosis (category Toxic effects of metals)
    and ammine and nitro complexes such as [Pt(NH3)4]Cl2, K2[Pt(NO2)4] and platinum nitrate are not considered to be allergenic; neither is the metal. Heavy...
    3 KB (368 words) - 02:48, 13 January 2024
  • Thumbnail for Reinecke's salt
    Reinecke's salt (category Ammine complexes)
    boiling water, acetone, and ethanol. It can be classified as a metal isothiocyanate complex. The chromium atom is surrounded by six nitrogen atoms in an...
    5 KB (264 words) - 13:21, 24 April 2025
  • Thumbnail for Pentaamminenitritocobalt(III) chloride
    Pentaamminenitritocobalt(III) chloride (category Ammine complexes)
    academic interest as a source of the transition metal nitrite complex [Co(NH3)5(NO2)]2+. The coordination complexes [Co(NH3)5(NO2)]2+ and [Co(NH3)5(ONO)]2+ were...
    5 KB (485 words) - 15:32, 31 March 2025
  • which features a pair of S-bonded thiosulfate ligands. Simple aquo and ammine complexes are also known. Three binding modes are common: monodentate (κ1-),...
    6 KB (714 words) - 02:38, 17 December 2024
  • Thumbnail for Cisplatin
    Cisplatin (category Ammine complexes)
    chemical name of this molecule is cis–diamminedichloroplatinum,: 286  where ammine with two m's indicates an ammonia (NH3) ligand, as opposed to an organic...
    39 KB (3,847 words) - 20:22, 29 May 2025
  • Thumbnail for Chloropentamminecobalt chloride
    Chloropentamminecobalt chloride (category Ammine complexes)
    coordination complexes feature metal atoms of octahedral and tetrahedral shapes, with ammonia and other ligands attached individually to the metal. Werner's...
    6 KB (572 words) - 20:36, 7 May 2025