In coordination chemistry, metal ammine complexes are metal complexes containing at least one ammonia (NH3) ligand. "Ammine" is spelled this way for historical...
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Some of the simplest members of such complexes are described in metal aquo complexes, metal ammine complexes, Examples: [Co(EDTA)]−, [Co(NH3)6]3+, [Fe(C2O4)3]3-...
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Hexaamminecobalt(III) chloride (category Ammine complexes)
of coordination chemistry, Alfred Werner. The cation itself is a metal ammine complex with six ammonia ligands attached to the cobalt(III) ion. [Co(NH3)6]3+...
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Hexaammineplatinum(IV) chloride (category Ammine complexes)
[Pt(NH3)6]Cl4. It is the chloride salt of the metal ammine complex [Pt(NH3)6]4+. The cation features six ammonia (called ammines in coordination chemistry) ligands...
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cationic metal ammine complexes such as [Pt(NH3)6]4+ spontaneously convert to the amido derivative: [Pt(NH3)6]4+ ↔ [Pt(NH3)5(NH2)]3+ + H+ Transition metal amides...
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[LnMNO] + OH− The reaction is reversible in some cases. In some metal-ammine complexes, the ammonia ligand can be oxidized to nitrosyl: H2O + [Ru(terpy)(bipy)(NH3)]+...
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Hexaamminenickel chloride (category Ammine complexes)
[Ni(NH3)6]Cl2. It is the chloride salt of the metal ammine complex [Ni(NH3)6]2+. The cation features six ammonia (called ammines in coordination chemistry) ligands...
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complex. For example, water exchange in [Al(H2O)5OH]2+ is 20000 times faster than in [Al(H2O)6]3+. Hydration number Ligand field theory Metal ammine complex...
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2 H2O Phosphines are L-type ligands. Unlike most metal ammine complexes, metal phosphine complexes tend to be lipophilic, displaying good solubility in...
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prominent examples of metal-ammine-chlorides. As indicated in the table below, many hydrates of metal chlorides are molecular complexes. These compounds are...
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(disambiguation) Amino (disambiguation) Anime, Japanese animation Metal ammine complex This disambiguation page lists articles associated with the title...
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Azanide (section Alkali metal derivatives)
Transition metal complexes of the amido ligand are often produced by salt metathesis reaction or by deprotonation of metal ammine complexes. Bergstrom...
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like most ions, have integer oxidation states. For example, ruthenium ammine complexes are typically +2 or +3. The fact that the oxidation states are half-integer...
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In organometallic chemistry, transition metal complexes of nitrite describes families of coordination complexes containing one or more nitrite (−NO2) ligands...
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Pentaamine(dinitrogen)ruthenium(II) chloride (category Ammine complexes)
the pi backbonding, the donation of metal d-electrons into the N2 π* orbitals. The related metal ammine complex [Os(NH3)5(N2)]2+ is also known. The dinitrogen...
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Schweizer's reagent (category Ammine complexes)
Schweizer's reagent is a metal ammine complex with the formula [Cu(NH3)4(H2O)2](OH)2. This deep-blue compound is used in purifying cellulose. This salt...
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sulfate. Well characterized xamples are found with cobalt(III) ammines since these complexes are exchange inert. Monodentate sulfate is found in [Co(tren)(NH3)(SO4)]+...
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Magnus's green salt (category Ammine complexes)
"Vauquelin’s salt". Magnus's green salt was one of the first examples of a metal ammine complex. Atoji, Masao; Richardson, James W.; Rundle, R. E. (June 1957). "Pt(NH3)4PtCl41"...
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A transition metal imidazole complex is a coordination complex that has one or more imidazole ligands. Complexes of imidazole itself are of little practical...
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forming metal ammine complexes. For historical reasons, ammonia is named ammine in the nomenclature of coordination compounds. One notable ammine complex is...
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general method for the determination of stability constants of metal-ammine complexes in 1941. The reasons why this occurred at such a late date, nearly...
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Rhodium(III) chloride (section Coordination complexes)
chloride, [RhCl(NH3)5]Cl2. As for other metal-ammine complexes, the term "ammine" refers to ammonia bound to a metal ion as a ligand. Zinc reduction of this...
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coordination chemistry and organometallic chemistry, transition metal imido complexes is a coordination compound containing an imido ligand. Imido ligands...
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Ligand (section Metal–ligand multiple bond)
in the cobalt ammine chlorides and to explain many of the previously inexplicable isomers. He resolved the first coordination complex called hexol into...
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Platinosis (category Toxic effects of metals)
and ammine and nitro complexes such as [Pt(NH3)4]Cl2, K2[Pt(NO2)4] and platinum nitrate are not considered to be allergenic; neither is the metal. Heavy...
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Reinecke's salt (category Ammine complexes)
boiling water, acetone, and ethanol. It can be classified as a metal isothiocyanate complex. The chromium atom is surrounded by six nitrogen atoms in an...
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Pentaamminenitritocobalt(III) chloride (category Ammine complexes)
academic interest as a source of the transition metal nitrite complex [Co(NH3)5(NO2)]2+. The coordination complexes [Co(NH3)5(NO2)]2+ and [Co(NH3)5(ONO)]2+ were...
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which features a pair of S-bonded thiosulfate ligands. Simple aquo and ammine complexes are also known. Three binding modes are common: monodentate (κ1-),...
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Cisplatin (category Ammine complexes)
chemical name of this molecule is cis–diamminedichloroplatinum,: 286 where ammine with two m's indicates an ammonia (NH3) ligand, as opposed to an organic...
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Chloropentamminecobalt chloride (category Ammine complexes)
coordination complexes feature metal atoms of octahedral and tetrahedral shapes, with ammonia and other ligands attached individually to the metal. Werner's...
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