In chemical kinetics, the pre-exponential factor or A factor is the pre-exponential constant in the Arrhenius equation (equation shown below), an empirical...
2 KB (281 words) - 19:54, 27 December 2024
reaction), T is the absolute temperature, A is the pre-exponential factor or Arrhenius factor or frequency factor. Arrhenius originally considered A to be a...
21 KB (2,793 words) - 15:30, 2 June 2025
ratio between the pre-exponential factor and the collision frequency, and it is most often less than unity. Physically, the steric factor can be interpreted...
2 KB (263 words) - 17:43, 23 May 2021
pre-exponential factor and the activation energy at several coverages. This calculation can be simplified. First we assume the pre-exponential factor...
12 KB (1,730 words) - 16:39, 18 October 2024
to understand the two parameters associated with this law, the pre-exponential factor (A) and the activation energy (Ea). TST, which led to the Eyring...
41 KB (5,711 words) - 03:35, 26 May 2025
gives a straight line, from which the activation energy and the pre-exponential factor can both be determined. The Arrhenius equation can be given in the...
6 KB (848 words) - 06:53, 5 March 2025
{\displaystyle k=Ae^{{-E_{\textrm {a}}}/{(RT)}}} where A is the pre-exponential factor for the reaction, R is the universal gas constant, T is the absolute...
19 KB (2,166 words) - 23:34, 15 June 2025
{-(\Delta G^{0}+\lambda )^{2}}{4\lambda kT}}\right],} with A being the pre-exponential factor, which is usually experimentally determined, although a semi-classical...
43 KB (5,186 words) - 19:45, 22 May 2025
the Arrhenius equation. The Evans–Polanyi model assumes that the pre-exponential factor of the Arrhenius equation and the position of the transition state...
3 KB (326 words) - 13:24, 31 July 2024
or A) magnetic vector potential (A) mass number of a nuclide (A) pre-exponential factor (A) one of the reciprocal lattice vectors (a*) relative atomic mass...
12 KB (1,651 words) - 23:18, 26 June 2025
positive pre-exponential factor and will be equivalent to τ {\displaystyle \tau } but the second one will have a negative pre-exponential factor resulting...
14 KB (2,049 words) - 00:14, 16 March 2025
the subsurface at x = 0 {\displaystyle x=0} is simplified to the pre-exponential factor of the distribution ( ∂ C ∂ x ) x = 0 = C b π D t . {\displaystyle...
58 KB (8,249 words) - 16:41, 24 May 2025
with e−Ea⁄RT. The constant of proportionality A is the pre-exponential factor, or frequency factor (not to be confused here with the reactant A) takes into...
17 KB (2,387 words) - 12:44, 3 February 2025
of the activation energy, but mainly because of the unfavorable pre-exponential factor of the rate constant. Although hydrogenation is endothermic, this...
72 KB (8,389 words) - 12:38, 29 June 2025
Reaction rate (section Influencing factors)
{E_{\mathrm {a} }}{RT}}\right)} where A, is the pre-exponential factor or frequency factor, exp is the exponential function, Ea is the activation energy, R is...
26 KB (3,726 words) - 15:07, 12 June 2025
{\displaystyle k=Ae^{-E_{\rm {a}}/(RT)}} , where A is the pre-exponential factor or A-factor, Ea is the activation energy, R is the molar gas constant...
24 KB (3,326 words) - 20:37, 18 March 2025
^{-6285.5/RT}\\k_{3f}&=3.80\times 10^{13}\end{aligned}}} where the pre-exponential factor is measured in units of cm, mol, s and K (these units are incorrect)...
3 KB (638 words) - 10:08, 28 May 2024
every kind of diffusion process for the de-trapped carriers, the pre-exponential factor in the Poole–Frenkel formula is thus proportional to E {\displaystyle...
22 KB (3,262 words) - 21:06, 23 May 2025
{S_{\mathrm {eff} }}{\hbar }}\right)} with the effective action Seff and pre-exponential factor Ao. This form is specifically useful in a dissipative system, in...
86 KB (14,277 words) - 08:57, 19 May 2025
parameters for describing the reactions: Between the logarithm of the pre-exponential factors (or prefactors) and the activation energies ln A i = α + E a...
19 KB (2,793 words) - 16:36, 28 May 2025
n is the order of desorption, υ {\displaystyle \upsilon } the pre-exponential factor, E is the activation energy, R is the gas constant and T is the...
20 KB (2,904 words) - 19:29, 16 April 2025
{2a_{1}a_{2}}{a_{1}+a_{2}}}\right]e^{\frac {-(R-a_{1}-a_{2})}{L}}} where As is the pre-exponential factor (1.5 × 10−3 J⋅m−2) and L is the decay length (1 × 10−9 m). This...
46 KB (5,510 words) - 07:24, 26 June 2025
without making the charge transfer. 2. It provides a formula for the pre-exponential factor in the Arrhenius equation, based on the electronic coupling between...
40 KB (5,730 words) - 14:45, 1 July 2025
Y_{O_{2}}}{W_{O_{2}}}}\right)^{n}e^{-E_{a}/RT},} where B {\displaystyle B} is the pre-exponential factor, ρ {\displaystyle \rho } is the density, Y F {\displaystyle Y_{F}}...
11 KB (1,869 words) - 00:54, 20 March 2025
Fowler–Nordheim Constant, is given by This shows clearly that the pre-exponential factor aφ−1F2, that appears in Fowler–Nordheim-type equations, relates...
124 KB (15,721 words) - 17:55, 24 May 2025
constant atomic weight, denoted by Ar work in classical mechanics the pre-exponential factor in the Arrhenius Equation electron affinity A {\displaystyle \mathbb...
43 KB (4,242 words) - 02:13, 25 May 2025
numerical calculations of liquid molar volume by an imperfect EOS. The pre-exponential factor A is now a function and becomes A = L c ρ ( α ρ + P V ) 3 M R T...
127 KB (23,318 words) - 23:51, 24 May 2025
curve which is described using the Power Law model where ‘A’ is a pre-exponential factor. d a / d N = A ( K ) m {\displaystyle da/dN=A(K)^{m}} (Power Law...
23 KB (3,316 words) - 17:10, 18 June 2025
energy) Reaction still proceeds at lower temperatures. The Arrhenius pre-exponential factors AD/AH is not equal to 1. A large negative entropy of activation...
100 KB (14,024 words) - 20:28, 24 May 2025
{\displaystyle A_{k}} and E k {\displaystyle E_{k}} , the Arrhenius pre-exponential factor and activation energy, respectively, are adjusted for specific reactions...
3 KB (483 words) - 12:51, 14 April 2022