chemistry the reactivity–selectivity principle or RSP states that a more reactive chemical compound or reactive intermediate is less selective in chemical...

in pharmacology Functional selectivity, in pharmacology Natural selection, in biology Reactivity–selectivity principle, in general chemistry Chemoselectivity...

the same relative reactivity regardless of the nature of the electrophile, which is in violation of the reactivity–selectivity principle. For this reason...

pedagogical demonstration of the reactivity–selectivity principle and the Hammond postulate. A bromine radical is not very reactive and the transition state for...

distribution of the two intermediates. The Curtin–Hammett principle has been invoked to explain selectivity in a variety of stereo- and regioselective reactions...

Maria F. Rubino (1995). "Dioxirane oxidations: Taming the reactivity-selectivity principle" (PDF). Pure Appl. Chem. 67 (5): 811–822. doi:10.1351/pac199567050811...

the reactivity volcano. In addition to studying catalytic reactivity, scaling relations can be used to study and screen materials for selectivity toward...

neighboring ester. The reactivity of NaBH4 can be enhanced or augmented by a variety of compounds. Many additives for modifying the reactivity of sodium borohydride...

catalytic activity and selectivity. The primary concern of this methodology is to establish structure-reactivity/selectivity relationships of catalysts...

ISBN 978-0-471-72091-1 Seebach, Dieter (1988). "Structure and Reactivity of Lithium Enolates. From Pinacolone to SelectiveC-Alkylations of Peptides. Difficulties and Opportunities...

chelating ruthenium catalyst to afford Z macrocycles in high selectivity. The selectivity is attributed to the increased steric clash between the catalyst...

to crotyl alcohol, 80% selectivity was attained at 5-10% conversion and 523 K (250 °C) on Au/ZrO2 and Au/ZnO. The selectivity increased along with Au...

the polymer product; namely, one must consider the reactivity ratio of each component. Reactivity ratios describe whether the monomer reacts preferentially...

describes reactivity of organic compounds perfectly, whereas the HSAB principle fails and should be abandoned in the rationalization of ambident reactivity of...

Ligands in a complex dictate the reactivity of the central atom, including ligand substitution rates, the reactivity of the ligands themselves, and redox...

weighing the relative significance of each) when rationalizing the selectivity or reactivity of a chemical process. In modern form, the Klopman–Salem equation...

ee's and yield of the product, very high selectivity factors are necessary. For example, with a selectivity factor of 10, ee″ above approximately 80%...

Solvents are divided into solvent selectivity groups. Using solvents with different elution strengths or different selectivity groups can often give very different...

pyrocatechol), displays a <100>/<111> selectivity of 17X, does not etch silicon dioxide as KOH does, and also displays high selectivity between lightly doped and...

resistance, durability, versatility, and adhesion. In principle, any molecule containing a reactive hydrogen may react with the epoxide groups of the epoxy...

NaOH FHWA (2010-06-22). "Alkali-Silica Reactivity (ASR) – Concrete – Pavements – FHWA". Alkali-Silica Reactivity (ASR) Development and Deployment Program...

(/ˈɡaɪ.ə/), also known as the Gaia theory, Gaia paradigm, or the Gaia principle, proposes that living organisms interact with their inorganic surroundings...

additions to allyl- and vinylsilanes take advantage of this, and site selectivity generally reflects this property—electrophiles become bound to the carbon...

the reactivity (in analogy to reactance). The magnitude of impedivity is the square root of sum of squares of magnitudes of resistivity and reactivity. Conversely...

receiver application of filtering as Q was a measure of the frequency selectivity of a tuning circuit. From the 1920s filters began to be designed from...

has also been demonstrated that sustained release of DRS could afford selectivity (choice of a particular reactant from a variety, say B from A, B, C and...

important with regard to the selectivity observed in an asymmetric synthesis. Many aspects of the structure-reactivity relationship in organic chemistry...

inert, it becomes highly reactive when scaled down to nanometer scale. One of the properties that govern cluster reactivity is electron affinity. Chlorine...

The reactivity of cobalt- and iron-DIP complexes are similar. Cobalt DIP complexes with azide ligands have been shown to lose N2 to give reactive nitrido...

dressing processes, paints, pyrotechnics, ceramics, and selective laser sintering. It works on the principle of impact and attrition: size reduction is done by...