Reductive elimination is an elementary step in organometallic chemistry in which the oxidation state of the metal center decreases while forming a new...

of sulfones are typically reductive in nature. Olefination or replacement with hydrogen may be accomplished using reductive desulfonylation methods. The...

R1-Pdll-X (B). The final step is the reductive elimination step where the palladium(II) complex (E) eliminates the product (3) and regenerates the palladium(0)...

catalyst (1), transmetalation of 3 with an organotin reagent (4), and reductive elimination of 5 to yield the coupled product (7) and the regenerated palladium...

by reductive elimination. An unproductive side reaction can compete with reductive elimination wherein the amide undergoes beta-hydride elimination to...

units in a process known as reductive elimination. (Confusingly, in organometallic terminology, the terms α-elimination and α-abstraction refer to processes...

addition, transmetalation, and reductive elimination. Both systems also have to address issues of β-hydride elimination and difficult oxidative addition...

In mathematics, Gaussian elimination, also known as row reduction, is an algorithm for solving systems of linear equations. It consists of a sequence of...

Oxidative addition and reductive elimination are two important and related classes of reactions in organometallic chemistry. Oxidative addition is a process...

electrophilic partner. In such cases, the mechanism generally involves reductive elimination of R-R' from LnMR(R') (L = spectator ligand). This intermediate...

ligands undergoing reductive elimination must be cis to each other or otherwise must rearrange to be cis before they can reductively eliminate. Finally, in...

trans-metalation step is a bis-aryl palladium(II), which then undergoes reductive elimination to form the desired bis-aryl species as well as the starting Pd(0)...

Reductive amination (also known as reductive alkylation) is a form of amination that converts a carbonyl group to an amine via an intermediate imine. The...

these bonds once they are activated through oxidative addition and reductive elimination. This investigation provided detailed mechanisms, intermediates...

complex C depends on the properties of the ligands. For the facile reductive elimination to occur, the substrate motifs need to be in close vicinity, i.e...

elimination to form an alkene from the other carbon-rhodium bond leads to a rhodacyclohexanone intermediate with an exocyclic double bond. Reductive elimination...

concerted manner. Allylic diazene rearrangement as the final step in the reductive 1,3-transposition of α,β-unsaturated tosylhydrazones to the reduced alkenes...

are believed to proceed through a standard Pd (0/II) pathway with reductive elimination forging the key C-C bond. Deactivation of Pd(II) with excess cyanide...

to give alkenes (olefins)(3) after alcohol functionalization and reductive elimination using sodium amalgam[1][2] or SmI2.[3] The reaction is named after...

place, generating a copper(III) intermediate which then undergoes reductive elimination to generate the coupled product. Both of these mechanisms predict...

Nucleophilic abstraction Organic redox reaction Oxidative addition and reductive elimination Oxidative phosphorylation Partial oxidation Pro-oxidant Redox gradient...

can undergo reductive elimination of the cross coupled product. Reduction of Ni(II) to Ni(0) by Mn closes the catalytic cycle. Reductive cross coupling...

can undergo reductive elimination (3) to afford the desired isopropyl arene C. However, intermediate B can also undergo β-hydride elimination (4) to afford...

bismuth(III)-ligand bonds facilitates ligand exchange and ultimately reductive elimination to release the product, reform the bismuthinidene, and create a...

intermediate, which undergoes reductive elimination to forge the first C–C bond of the product. After β-carbon elimination of norbornene, the resultant...

and water cases, the oxidative added product could also undergo reductive elimination, yielding O- or N-B bond formation. Carbene analogs Silylene Sasamori...

to form the six-coordinate dicarbonyl complex, which undergoes reductive elimination to release acetyl iodide (CH3C(O)I). The catalytic cycle involves...

stage a molecule of carbon monoxide is lost to 6. The final step is reductive elimination to form the cycloalkene. Organic Chemistry Portal Wikimedia Commons...

kinetic studies implicate oxidative addition reaction followed by reductive elimination from Cu(III) intermediates (Ln = one or more spectator ligands):...

copper(III)-aryl-alkoxide or copper(III)-aryl-amide intermediate undergoes Reductive elimination to give the aryl ether or aryl amine, respectively: Ar-Cu(III)-NHR-L2...