Transition metal dinitrogen complexes are coordination compounds that contain transition metals as ion centers the dinitrogen molecules (N2) as ligands...

Pentaamine(dinitrogen)ruthenium(II), the first metal dinitrogen complex. Hexamminecobalt(III) chloride, the trichloride salt of the hexammine complex [Co(NH3)6]3+...

Metal nitrido complexes are coordination compounds and metal clusters that contain an atom of nitrogen bound only to transition metals. These compounds...

A transition metal nitrate complex is a coordination compound containing one or more nitrate ligands. Such complexes are common starting reagents for the...

In chemistry, a transition metal ether complex is a coordination complex consisting of a transition metal bonded to one or more ether ligand. The inventory...

laboratory setting. Dinitrogen tetroxide can also be produced by heating metal nitrates. The oxidation of copper by nitric acid is a complex reaction forming...

Nitrogenase: enzymes used by organisms to fix nitrogen Transition metal dinitrogen complex Metal nitrido complex Chalkley, Matthew J.; Drover, Marcus W.; Peters...

While the first dinitrogen complex was discovered in 1965, reports of dinitrogen complexes of main group elements have been significantly limited relative...

accomplished than side-on (η2) donation. Today, dinitrogen complexes are known for almost all the transition metals, accounting for several hundred compounds...

Light on Dinitrogen Cleavage: Structural Features, Redox Chemistry, and Photochemistry of the Key Intermediate Bridging Dinitrogen Complex". Journal...

the only stable alkali metal nitride. Nitrogen is an unreactive gas because breaking the strong triple bond in the dinitrogen molecule (N2) requires a...

−196 °C. Dinitrogen is mostly unreactive at room temperature, but it will nevertheless react with lithium metal and some transition metal complexes. This...

Retrieved 21 September 2014. Crabtree, Robert Howard (1973). Transition Metal Dinitrogen Complexes Adduct Formation and Base Character (PhD thesis). University...

silylated. Transition metal dinitrogen complex Nitrogen fixation Hidai, Masanobu.; Mizobe, Yasushi. (1995). "Recent Advances in the Chemistry of Dinitrogen Complexes"...

the Greenhouse Gas Dinitrogen Monoxide by Nitrous Oxide Reductase". In Peter M.H. Kroneck; Martha E. Sosa Torres (eds.). The Metal-Driven Biogeochemistry...

salt, and molybdenum and iron dinitrogen complexes. The electrons are partially transferred from a d-orbital of the metal to anti-bonding molecular orbitals...

number of transition-metal species have been found to bind (and even functionalize) N2. The prevalence of transition metals in dinitrogen activation...

concerned with the activation of main group and transition metal compounds; in the case of transition metal complexes, As4 has demonstrated competent reactivity...

necessary, without the inevitable oxidation (breaking down) of everything. Transition metal ions, due to their multiple oxidation states, were the only elements...

such as free radicals or isolated atoms. One use is to study dinitrogen complexes of metals in isolation from other molecules. When solid nitrogen is irradiated...

Council. Using the transition metal dinitrogen complex W(N2)2(dppe)2, his group first demonstrated the conversion of a dinitrogen ligand into ammonia...

borylene complex [(OC)5WBN(SiMe3)2] was reported by Holger Braunschweig et al. in 1998. In this compound a borylene is coordinated to a transition metal. Borylenes...

tetrafluoroborate is 1.083(3) Å, which is almost identical to that for dinitrogen molecule (N≡N). The linear free energy constants σm and σp indicate that...

the activation of dinitrogen. Floriani et al. attempted the reduction of dinitrogen by using V(Mes)3(THF). After reducing with Na metal in diglyme, Na[V(Mes)3]...

activation including carbon dioxide complexes and dinitrogen complexes. He prepared several transition metal mesityl complexes such as tetramesityldiiron and...

28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive...

5, hydrated 18-crown-6 ether alkali metal ions, hydrated alkali metal ions, transition metal acetylene complexes, protonated ethylene, and IrO4+. Argon...

oleylamine—can create false positives in the photocatalytic “fixation’’ of dinitrogen (N₂) on metal-oxide nanocrystals. Ligands that remain bound after nanoparticle...

Dehnicke, Kurt; Strähle, Joachim (1989). "Phosphorane iminato complexes of transition metals". Polyhedron. 8 (6): 707–726. doi:10.1016/s0277-5387(00)83838-3...

Y. Nishibayashi (2015), "Recent progress in transition-metal-catalyzed reduction of molecular dinitrogen under ambient reaction conditions", Inorg. Chem...