A transition metal fullerene complex is a coordination complex wherein fullerene serves as a ligand. Fullerenes are typically spheroidal carbon compounds...

inside a shell. Two types of endohedral complexes exist: endohedral metallofullerenes and non-metal doped fullerenes. In a traditional chemical formula notation...

elongated by 0.2 Å. In the fullerene complex Ru3(CO)9(C60), the fullerene binds to the triangular face of the cluster. In some complexes, the arene binds through...

A fullerene is an allotrope of carbon whose molecules consist of carbon atoms connected by single and double bonds so as to form a closed or partially...

Buckminsterfullerene is a type of fullerene with the formula C60. It has a cage-like fused-ring structure (truncated icosahedron) made of twenty hexagons...

of the late transition metals, where metal-halide bonding is replete. Transition metal halide clusters are prevalent for the heavier metals: Zr, Hf, Nb...

it is for simple metals) n = 3 implies that the resistance is due to s-d electron scattering (as is the case for transition metals) n = 2 implies that...

carbide coatings on a metal piece. The carbides of the group 4, 5 and 6 transition metals (with the exception of chromium) are often described as interstitial...

Transition-metal dichalcogenide (TMD or TMDC) monolayers are atomically thin semiconductors of the type MX2, with M a transition-metal atom (Mo, W, etc...

Different forms (allotropes) of pure carbon, such as diamond, graphite, fullerenes and carbon nanotubes are also excluded because they are simple substances...

(R5C5)M(R′2)C2B4H4) where M is a transition metal and R and R′ are methyl or ethyl. Closely related are the metal complexes containing H3C3B2R2 (diborolyl)...

Vinylidene Transition Metal Complexes. 4.1 Reaction of the Metal−Acetylide [(η5-C5H5)(NO)(CO)WC⋮CR]- with Allyl Halides To Give η3-Allyl Complexes....

encountered in octahedral complexes of the transition metals. The phenomenon is very common in six-coordinate copper(II) complexes. The d9 electronic configuration...

compounds is +4, while +2 is found in carbon monoxide and transition metal carbonyl complexes. The largest sources of inorganic carbon are limestones,...

heating and cooking. For instance, the class of nanomaterials called fullerenes are generated by burning gas, biomass, and candle. It can also be a byproduct...

Zeise's salt or with fullerene, which is bonded through donation of the π-bonding electrons: K[PtCl3(η2-C2H4)].H2O Related complexes containing bridging...

transition metal ligand. A similar mercury complex (HgXe)(Sb3F17) (formulated as [HgXe2+][Sb2F11–][SbF6–]) is also known. Xenon reversibly complexes gaseous...

of functionalization of single-walled carbon nanotubes. Reactivity of fullerene molecules with respect to addition chemistries is strongly dependent on...

slowly replace the transition metal as the metal nodes, incorporating themselves into the crystal itself. Another known method by which metal-organic frameworks...

complexes between transition metals and carbonyl ligands. Metal carbonyls are complexes that are formed with the neutral ligand CO. These complexes are...

example, diamond, graphite, and fullerenes are different allotropes of carbon. When a substance undergoes a phase transition (changes from one state of matter...

(such as C25, a 25-carbon fullerene spheroid). The term is sometimes also used in reference to reactivity – for example, a complex that quickly reaches equilibrium...

dendrimer molecules can be functionalized with porphyrins, fullerenes and metal complexes. Some reported dendrimer systems can achieve up to 99% energy...

copper(II) complexes oxidized H2. The 1960s witnessed the development of well defined homogeneous catalysts using transition metal complexes, e.g., Wilkinson's...

are stronger for endohedral metallo-fullerenes, in which a positively charged metal ion is trapped inside a fullerene cage and makes it more electronegative...

interactions between these molecules or sheets. Metal dichalcogenides have the formula ME2, where M = a transition metal and E = S, Se, Te. In terms of their electronic...

"(Cyclopentadienyl)dicarbonylmethyliron ((η5-C5H5)Fe(CO)2CH3, FpMe), a Seminal Transition-Metal Alkyl Complex: Mobility of the Methyl Group". Organometallics. 29 (21): 4741–4745...

helium atoms can be confined together without bonding in the cage of a fullerene. Based on molecular orbital theory, He2 should not exist, and a chemical...

Noble gases can also form endohedral fullerene compounds where the noble gas atom is trapped inside a fullerene molecule. In 1993, it was discovered that...

5, hydrated 18-crown-6 ether alkali metal ions, hydrated alkali metal ions, transition metal acetylene complexes, protonated ethylene, and IrO4+. Argon...