Lithium aluminium hydride, commonly abbreviated to LAH, is an inorganic compound with the chemical formula Li[AlH4] or LiAlH4. It is a white solid, discovered...

generated in THF from lithium aluminium hydride. The reaction with lithium hydride in ether produces lithium aluminium hydride: AlH3 + LiH → Li[AlH4]...

Lithium hydride is an inorganic compound with the formula LiH. This alkali metal hydride is a colorless solid, although commercial samples are grey. Characteristic...

metal hydrides react with metal halides. Lithium aluminium hydride (often abbreviated as LAH) arises from reactions of lithium hydride with aluminium chloride...

reagent, SMEAH is comparable with lithium aluminium hydride (LAH, LiAlH4). It is a safer alternative to LAH and related hydrides. SMEAH exhibits similar reducing...

sodium hydride (NaH), lithium hydride (LiH) or lithium aluminium hydride (LiAlH4): 8 BF3 + 6 LiH → B2H6 + 6 LiBF4 Lithium hydride used for this purpose must...

suspension in diethyl ether, it reacts with lithium chloride to give the popular reagent lithium aluminium hydride: LiCl + NaAlH4 → LiAlH4 + NaCl The compound...

stronger reducing agent than lithium borohydride and lithium aluminium hydride. LiBHEt3 is prepared by the reaction of lithium hydride (LiH) and triethylborane...

soluble in ethers, whilst remaining safer to handle than lithium aluminium hydride. Lithium borohydride may be prepared by the metathesis reaction, which...

Mg(anthracene) + H2 → MgH2 the reaction of diethylmagnesium with lithium aluminium hydride product of complexed MgH2 e.g. MgH2.THF by the reaction of phenylsilane...

refer to the reduction of a ketone by lithium aluminium hydride, but not to the oxidation of lithium aluminium hydride by a ketone. Many oxidations involve...

Metal hydrides (sodium hydride, lithium aluminium hydride, uranium trihydride) Partially or fully alkylated derivatives of metal and nonmetal hydrides (diethylaluminium...

(nitro group, nitrile, ester). In their handling properties, lithium aluminium hydride and sodium borohydride (and their derivatives) strongly differ...

agents for the non-catalytic conversion to amines include lithium aluminium hydride, lithium borohydride, diborane, or elemental sodium in alcohol solvents...

group with hydrogen by metal alkoxyaluminium hydride reagents. Sodium borohydride and lithium aluminium hydride are commonly used for the reduction of organic...

synthesized in 1951 by treating dimethylberyllium, Be(CH3)2, with lithium aluminium hydride, LiAlH4. Purer BeH2 forms from the pyrolysis of di-tert-butylberyllium...

include lithium aluminium hydride (LiAlH4), lithium triethylborohydride, n-butyllithium and tert-butyllithium. Metallic lithium and its complex hydrides, such...

azetidinones (β-lactams) with lithium aluminium hydride. Even more effective is a mixture of lithium aluminium hydride and aluminium trichloride, a source of...

tri-sec-butylborohydride), a more strongly reducing derivative. Lithium aluminium hydride, a more strongly reducing reagent, capable of reducing esters...

important aluminium hydride is lithium aluminium hydride (LiAlH4), which is used as a reducing agent in organic chemistry. It can be produced from lithium hydride...

synthesis include the reaction of polonium tetrachloride (PoCl4) with lithium aluminium hydride (LiAlH4), which only produces elemental polonium, and the reaction...

agents able to effect this reaction include metal hydrides such as lithium aluminium hydride, or lithium borohydride in mixed solvents of tetrahydrofuran...

Zinc(II) hydride was first synthesized in 1947 by Hermann Schlesinger, via a reaction between dimethylzinc Zn(CH3)2 and lithium aluminium hydride Li[AlH4];...

laboratory scale reactions it was made obsolete by the introduction of lithium aluminium hydride. Sodium metal is a one-electron reducing agent. Four equivalents...

synthesized by a reduction of tributyltin chloride with lithium aluminium hydride. The hydride is a distillable liquid that is mildly sensitive to air...

accomplish this task include lithium aluminium hydride, sodium borohydride, alkoxy borohydrides, alkoxy aluminium hydrides, and boranes. Although stoichiometric...

tetracarbonyl. The complex has C5v symmetry. The compound reacts with lithium aluminium hydride to give the paramagnetic cluster (C5H5)4Ni4H3. The related...

nitro compounds with metal hydrides gives good yields of azo compounds. For example, one could use: Lithium aluminium hydride Zinc metal with sodium hydroxide...

similar fashion. Organoperoxides can be reduced to alcohols with lithium aluminium hydride, as described in this idealized equation: 4 ROOH + LiAlH4 → LiAlO2...

devised by Wurtz. Molecular copper hydride can be formed by reducing copper iodide with lithium aluminium hydride in ether and pyridine. 4CuI + LiAlH4...