chemistry, a reaction intermediate, or intermediate, is a molecular entity arising within the sequence of a stepwise chemical reaction. It is formed...

cationic intermediate loses a proton to give an allylic alcohol (4). With an excess of formaldehyde and a low reaction temperature the reaction product...

than that of the intermediate. Instead, the rate equation may be more accurately described using steady-state kinetics. The reaction involves a carbocation...

intermediates (see next section) or other quantitative and qualitative characteristics of the reaction. It also describes each reactive intermediate,...

A tetrahedral intermediate is a reaction intermediate in which the bond arrangement around an initially double-bonded carbon atom has been transformed...

a reactive intermediate or an intermediate is a short-lived, high-energy, highly reactive molecule. When generated in a chemical reaction, it will quickly...

equilibration of Wittig intermediates and termed the process "stereochemical drift". For many years, the stereochemistry of the Wittig reaction, in terms of carbon-carbon...

a reaction intermediate is a reaction product that serves as a precursor for other reactions A reactive intermediate is a highly reactive reaction intermediate...

Bischler–Napieralski reaction. Mechanism I involves a dichlorophosphoryl imine-ester intermediate, while Mechanism II involves a nitrilium ion intermediate (both shown...

reduction-sensitive intermediates may form in the reaction which can affect chemoselectivity. The amine substrate, imine intermediate, or amine product...

reaction in which a reaction intermediate (or, for the first step, the reactants) is converted into the next reaction intermediate (or, for the last step...

The Simmons–Smith reaction is an organic cheletropic reaction involving an organozinc carbenoid that reacts with an alkene (or alkyne) to form a cyclopropane...

Shapiro reaction or tosylhydrazone decomposition is an organic reaction in which a ketone or aldehyde is converted to an alkene through an intermediate hydrazone...

imine product. Throughout the development of the reaction the group sought to identify reaction intermediates through fundamental mechanistic studies. These...

organopalladium intermediate B. Reaction (metathesis) with base gives intermediate C, which via transmetalation with the boron-ate complex D (produced by reaction of...

effect of simplifying a single chemical entity (normal molecule, reaction intermediate, etc.) into two or more fragments. Chemical decomposition is usually...

aromatic hydrocarbon is important in the petrochemical industry as a reaction intermediate in the production of styrene, the precursor to polystyrene, a common...

an additional covalent intermediate to the reaction, and helps to reduce the energy of later transition states of the reaction. The covalent bond must...

formation of the oxyphosphonium intermediate 8 is slow and facilitated by the alkoxide. Therefore, the overall rate of reaction is controlled by carboxylate...

intermediate in the synthesis of the antipsychotic drug Fluanxol is synthesized by a cyanation through the Sandmeyer reaction. The Sandmeyer reaction...

typical reaction above. Also, V is the volume of reaction and Ci is the concentration of substance i. When side products or reaction intermediates are formed...

products, and sometimes intermediate products and reaction conditions. Chemical reactions happen at a characteristic reaction rate at a given temperature...

subsequent reaction occurs only in virtue of the chemical functionality formed in the previous step. In cascade reactions, isolation of intermediates is not...

enzyme-catalysed chemical reactions. In enzyme kinetics, the reaction rate is measured and the effects of varying the conditions of the reaction are investigated...

factors in reaction rate. Catalysts generally react with one or more reactants to form intermediates that subsequently give the final reaction product,...

octacarbonyl to the alkyne of propargylic ether (1) gives the dicobalt intermediate 2. Reaction with tetrafluoroboric acid or a Lewis acid gives the key dicobalt...

a concerted reaction is a chemical reaction in which all bond breaking and bond making occurs in a single step. Reactive intermediates or other unstable...

depending upon the reagent involved, whether a reactive intermediate involved in the reaction is a carbocation, a carbanion or a free radical, and whether...

concerted mechanism. There is no perepoxide intermediate as in the classical sense of reaction intermediates, for there exists no energy barrier between...

The Stille reaction is a chemical reaction widely used in organic synthesis. The reaction involves the coupling of two organic groups, one of which is...