Transition metal carboxylate complexes are coordination complexes with carboxylate (RCO2−) ligands. Reflecting the diversity of carboxylic acids, the inventory...

Transition metal carboxylate complex Oxalatonickelate Krishnamurty, Kotra V.; Harris, Gordon M. (1961). "The Chemistry of the Metal Oxalato Complexes"...

In coordination chemistry, a transition metal NHC complex is a metal complex containing one or more N-heterocyclic carbene ligands. Such compounds are...

lacking direct metal-carbon bonds. Metal β-diketonates, metal alkoxides, metal dialkylamides, transition metal carboxylate complexes, metal acetylacetonates...

Transition metal phosphate complexes are coordination complexes with one or more phosphate ligands. Phosphate binds to metals through one, two, three...

In chemistry, a transition metal chloride complex is a coordination complex that consists of a transition metal coordinated to one or more chloride ligand...

cyclopropanation of alkenes. It is a widely studied example of a transition metal carboxylate complex. Rhodium(II) acetate is usually prepared by the heating of...

hemoglobin, hemerythrin, and hemocyanin. Several transition metals form complexes with O2, and many of these complexes form reversibly. The binding of O2 is the...

A transition metal imidazole complex is a coordination complex that has one or more imidazole ligands. Complexes of imidazole itself are of little practical...

classified as CMD, the transition state does not need to involve the carboxylate as a ligand on the metal. Common sources of carboxylate include pivalate,...

Transition metal amino acid complexes are a large family of coordination complexes containing the conjugate bases of the amino acids, the 2-aminocarboxylates...

Carboxylate–based metal–organic frameworks are metal–organic frameworks that are based on organic molecules comprising carboxylate functional groups. The...

intramolecular variant of this reaction was first reported in 1961. Rhodium carboxylate complexes, such as dirhodium tetraacetate, are common catalysts. Enantioselective...

The Das cubane is a transition metal carboxylate complex with the formula [CoO(OAc)py]4 where OAc is acetate and py is pyridine. The compound is named...

Metal carbon dioxide complexes are coordination complexes that contain carbon dioxide ligands. Aside from the fundamental interest in the coordination...

pores. The most common transition metals employed in carboxylate-based frameworks are Cu2+ and Zn2+. Lighter main-group metal ions have also been explored...

Tolstikov, S. E.; Ovcharenko, V. I. (2019). "Mononuclear Transition Metal Adamantane-1-Carboxylates". Russian Chemical Bulletin. 68 (9): 1669–1674. doi:10...

was introduced by Georg Wittig in 1958. Ate complexes are common for metals, including the transition metals (groups 3-11), as well as the metallic or semi-metallic...

iconic example of a compound with a metal-metal quadruple bond. Like several other transition metal carboxylate complexes, Mo2(O2CCH3)4 adopts a Chinese lantern...

reacted with an alkali-metal amide such as sodium amide to form 2-aminopyridine. In the compound methyl 3-nitropyridine-4-carboxylate, the meta nitro group...

Saponification is a process of cleaving esters into carboxylate salts and alcohols by the action of aqueous alkali. Typically aqueous sodium hydroxide...

functional group: Transition metal salts, especially copper compounds, facilitate decarboxylation via carboxylate complex intermediates. Metals that catalyze...

functional group that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one...

difficult in part because of the complex effect of environment on electron density distribution. Transition metals are commonly used as nodes. Partially...

whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. Silver is found...

of complex: compounds formed by the interaction of a metal ion with a ligand and supramolecular complexes, such as host–guest complexes and complexes of...

equilibria with the carboxylate anions, LnMCO2−. Metallacarboxylate esters (LnMCO2R) arise by the addition of alkoxide to metal carbonyl: [LnM-CO]+ +...

known as ferrioxalate. Other carboxylate sources, e.g., citrate and tartrate, bind as well to give carboxylate complexes. The affinity of iron(III) for...

a bidentate chelating ligand, forming complexes with many transition metals. Ruthenium and platinum complexes of bipy exhibit intense luminescence. 2...

weaker complexes with nitrogen-donor ligands than with fluoride and oxygen donor ligands, such as hydroxide, carbonate, nitrate, sulfate and carboxylate. There...