Formylation refers to any chemical processes in which a compound is functionalized with a formyl group (-CH=O). In organic chemistry, the term is most...

In organic synthesis, the Casiraghi formylation is the formation of a salicylaldehyde from a phenol and paraformaldehyde. The reaction requires a strong...

chlorodimethyl ether. The compound is used in the formylation of aromatic compounds (Rieche formylation) and as a chlorination agent in the formation of...

Rieche formylation is a type of formylation reaction. The substrates are electron rich aromatic compounds, such as mesitylene or phenols, with dichloromethyl...

is hydrolyzed to the corresponding ketone or aldehyde during workup. Formylation reaction Mallegol, T.; Gmouh, S.; Aït Amer Meziane, M.; Blanchard-Desce...

The Duff reaction or hexamine aromatic formylation is a formylation reaction used in organic chemistry for the synthesis of benzaldehydes with hexamine...

being a commercial flavorant. 2-Anisaldehyde is prepared commercially by formylation of anisole. A. J. Sisti (1964). "o-Anisaldehyde". Org. Synth. 44: 4....

acetylation, the addition of the acetyl group. Closely related to acylation is formylation, which employ sources of "HCO+ in place of "RCO+". Because they form...

The Reimer–Tiemann reaction is a chemical reaction used for the ortho-formylation of phenols. with the simplest example being the conversion of phenol...

The Gattermann reaction (also known as the Gattermann formylation and the Gattermann salicylaldehyde synthesis) is a chemical reaction in which aromatic...

distillation at ≤30 °C under reduced pressure. Acetic formic anhydride is a formylation agent for amines, amino acids, and alcohols. It is also a starting material...

Commercially available, it may be prepared from the Friedel-Crafts formylation of toluene with carbon monoxide and hydrogen chloride under Gattermann-Koch...

organic solvents. Vilsmeier reagent is the active intermediate in the formylation reactions, the Vilsmeier reaction or Vilsmeier-Haack reaction that use...

3-thiazolines. Alfred Rieche – chemist who discovered the Rieche formylation, a type of formylation reaction. Kurt Magnus – professor of applied mechanics and...

ISBN 978-1-58829-173-8. US patent 2785162, Swidinsky J, Baizer MM, "Process for the formylation of a 5-nitrouracil", published 12 March 1957, assigned to New York Quinine...

ring-opened enolate-isonitrile, which can be trapped by silylation. Formylation with dimethylformamide gives 2-formyloxazole. Electrophilic aromatic...

cyanohydrins, for the transformation of HCN to Michael acceptors, and for the formylation of arenes. Treatment of this cyanohydrin with lithium hydride affords...

viral sensing pathways through RIG-I-like receptors. Additionally, the N-formylation of mitochondrial proteins, similar to that of bacterial proteins, can...

Methanofurans (MFRs) are a family of chemical compounds found in methanogenic archaea. These species feature a 2-aminomethylfuran linked to phenoxy group...

synthetically by the reduction of 4-isopropylbenzoyl chloride or by the formylation of cumene. The thiosemicarbazone of cuminaldehyde has antiviral properties...

electron-deficient. Nitration, nitrosation, azo coupling, halogenation, sulfonation, formylation, hydroxymethylation, and aminomethylation have been observed with substituted...

electrophilic aromatic substitution pattern are a group of aromatic formylation reactions including the Vilsmeier–Haack reaction, the Gattermann Koch...

n-butyllithium to yield the tetrahydrobenzodifuran ring system. After formylation of the ring system, the nitropropene derivative was obtained by condensation...

chemicals used, produces higher yields and higher purity of the product. Formylation of octabase prior to cyclization avoids ether cleavage as a side reaction...

that is soluble in common organic solvents. It is prepared by Vilsmeier formylation of anthracene. The compound is also used as a building block for supramolecular...

versatile reagent in organic synthesis. It is used in the Duff reaction (formylation of arenes), the Sommelet reaction (converting benzyl halides to aldehydes)...

catalyst, to produce dichlorocarbene, CCl2. This reagent effects ortho-formylation of activated aromatic rings, such as phenols, producing aryl aldehydes...

to a Grignard reagent: PhCH2CH2MgCl + C6H11NO → PhCH2CH2CHO In some formylation reaction of alkyllithium compounds, N-formylpiperidine gives higher yields...

biosynthesis (early stages) Folate biosynthesis (later stages) Folate coenzymes Formylation, hydroxymethylation and methylation using folate C1 metabolism with folate...

Wittig reaction using methoxymethylenetriphenylphosphine as a reagent. Formylation reactions Nucleophilic arenes Various reactions, for example the Vilsmeier-Haack...