Metal nitrosyl complexes are complexes that contain nitric oxide, NO, bonded to a transition metal. Many kinds of nitrosyl complexes are known, which vary...
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nitrito complexes by base-hydrolysis of electrophilic metal nitrosyls. Nitro complexes also catalyze the oxidation of alkenes. Metal nitrito complexes figure...
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thiolate ligands are cysteinyl residues or glutathione. These metal nitrosyl complexes have attracted much attention because they serve as biochemical...
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Nitrosonium (section As a source of nitrosyl complexes)
NOBF4 reacts with some metal carbonyl complexes to yield related metal nitrosyl complexes. In some cases, [NO]+ does not bind the metal nucleophile but acts...
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In coordination chemistry, metal ammine complexes are metal complexes containing at least one ammonia (NH3) ligand. "Ammine" is spelled this way for historical...
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turn known as ligands or complexing agents. Many metal-containing compounds, especially those that include transition metals (elements like titanium that...
57 KB (5,547 words) - 18:58, 12 June 2025
chloride is used to prepare metal nitrosyl complexes. With molybdenum hexacarbonyl, NOCl gives the dinitrosyldichloride complex: Mo(CO)6 + 2 NOCl → MoCl2(NO)2...
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Nitric oxide (redirect from Nitrosyl radical)
oxide release. Nitric oxide reacts with transition metals to give complexes called metal nitrosyls. The most common bonding mode of nitric oxide is the...
32 KB (3,143 words) - 13:25, 8 June 2025
form homoleptic and mixed ligand complexes that are analogous to the metal carbonyls.[citation needed] Metal nitrosyls, compounds featuring NO ligands...
71 KB (8,030 words) - 18:18, 28 May 2025
classes of protein. Nitric oxide to a transition metal ion like iron or copper, forming metal nitrosyl complexes. Typical cases involve the nitrosylation of...
70 KB (7,684 words) - 06:35, 2 June 2025
Metal nitrido complexes are coordination compounds and metal clusters that contain an atom of nitrogen bound only to transition metals. These compounds...
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Sodium nitroprusside (category Nitrosyl complexes)
(2002). "Photoinduced Linkage Isomers of Transition-Metal Nitrosyl Compounds and Related Complexes". Chemical Reviews. 102 (4): 861–883. doi:10.1021/cr000031c...
40 KB (4,076 words) - 22:12, 29 May 2025
from the formation of nitrosyl chloride and nitrogen dioxide. It was so named by alchemists because it can dissolve noble metals such as gold and platinum...
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Roussin's red salt (category Nitrosyl complexes)
salt is the inorganic compound with the formula K2[Fe2S2(NO)4]. This metal nitrosyl was first described by Zacharie Roussin in 1858, making it one of the...
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The related pentamethylcyclopentadienyl complex (C5(CH3)5)NiNO is also known. Cyclopentadienyl nickel nitrosyl was the subject of several patents as a...
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Nitrite (section Coordination complexes)
wide variety of coordination complexes by binding to metal ions in several ways. Two examples are the red nitrito complex [Co(NH3)5(ONO)]2+ is metastable...
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the simplest metal nitrosyls. It is highly toxic, reminiscent of the same property for nickel tetracarbonyl. Cobalt tricarbonyl nitrosyl is prepared by...
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SNO-vWF; N-Nitroso compounds (e.g., nitrosamines): SIN-1A Nitrosyl compounds: Metal nitrosyl complexes: Roussin's black salt Roussin's red salt Sodium nitroprusside...
20 KB (1,963 words) - 21:36, 8 June 2025
SNO-vWF; N-Nitroso compounds (e.g., nitrosamines): SIN-1A Nitrosyl compounds: Metal nitrosyl complexes: Roussin's black salt Roussin's red salt Sodium nitroprusside...
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Transition metal sulfate complexes or sulfato complexes are coordination complexes with one or more sulfate ligands. Being the conjugate base of a strong...
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SNO-vWF; N-Nitroso compounds (e.g., nitrosamines): SIN-1A Nitrosyl compounds: Metal nitrosyl complexes: Roussin's black salt Roussin's red salt Sodium nitroprusside...
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SNO-vWF; N-Nitroso compounds (e.g., nitrosamines): SIN-1A Nitrosyl compounds: Metal nitrosyl complexes: Roussin's black salt Roussin's red salt Sodium nitroprusside...
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redox reaction of nitrosonium and the metal can give rise to nitrogen oxide which forms strong metal nitrosyl complexes; nitronium ions (NO2+) are similarly...
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process as adding a nitrosyl radical NO•. Nitrosylation commonly occurs in the context of a metal (e.g. iron) or a thiol, leading to nitrosyl iron Fe−NO (e...
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SNO-vWF; N-Nitroso compounds (e.g., nitrosamines): SIN-1A Nitrosyl compounds: Metal nitrosyl complexes: Roussin's black salt Roussin's red salt Sodium nitroprusside...
40 KB (4,207 words) - 03:17, 11 June 2025
SNO-vWF; N-Nitroso compounds (e.g., nitrosamines): SIN-1A Nitrosyl compounds: Metal nitrosyl complexes: Roussin's black salt Roussin's red salt Sodium nitroprusside...
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SNO-vWF; N-Nitroso compounds (e.g., nitrosamines): SIN-1A Nitrosyl compounds: Metal nitrosyl complexes: Roussin's black salt Roussin's red salt Sodium nitroprusside...
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inhibitor of arginase. Crystal structure of its complex with the enzyme reveals that it displaces the metal-bridging hydroxide ion and bridges the binuclear...
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SNO-vWF; N-Nitroso compounds (e.g., nitrosamines): SIN-1A Nitrosyl compounds: Metal nitrosyl complexes: Roussin's black salt Roussin's red salt Sodium nitroprusside...
2 KB (67 words) - 07:43, 10 June 2024