Amide reduction is a reaction in organic synthesis where an amide is reduced to either an amine or an aldehyde functional group. Catalytic hydrogenation...
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In organic chemistry, an amide, also known as an organic amide or a carboxamide, is a compound with the general formula R−C(=O)−NR′R″, where R, R', and...
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Organic redox reaction (redirect from Organic reduction)
compounds Carbonyl reduction Amide reduction Nitrile reduction Reduction of nitro compounds Reduction of imines and Schiff bases Reduction of aromatic compounds...
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substrates for the Wolff–Kishner reduction as demonstrated by the example above. Coe and coworkers found however that a twisted amide can be efficiently reduced...
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Nicotinamide (redirect from Nicotinic acid amide)
B family of medications, specifically the vitamin B3 complex. It is an amide of nicotinic acid. Foods that contain niacinamide include yeast, meat, milk...
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Weinreb ketone synthesis (redirect from Weinreb amide)
reported the synthesis of aldehydes by reduction of the amide with an excess of lithium aluminum hydride (see amide reduction). The major advantage of this method...
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reductive amination. Ester reduction of Eudesmic acid's methyl ester followed by halogenation, Kolbe nitrile synthesis, and nitrile reduction. Amide reduction...
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Stephen aldehyde synthesis (redirect from Stephen reduction)
salt is obtained from reaction of an amide PhCONHPh with phosphorus pentachloride. Amide reduction Nitrile reduction Pinner reaction – a similar reaction...
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in organic synthesis as a catalyst for ethenolysis, carbonyl reduction and amide reduction. "Rhenium(VII) oxide". pubchem.ncbi.nlm.nih.gov. Retrieved 14...
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(see: carbonyl reduction). Similarly, it converts amide, nitro, nitrile, imine, oxime, and organic azides into the amines (see: amide reduction). It reduces...
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Ergine (redirect from Lysergic acid amide)
Ergine, also known as d-lysergic acid amide (LSA) and d-lysergamide, is an ergoline alkaloid that occurs in various species of vines of the Convolvulaceae...
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requires the chemist to use a higher ratio of catalyst to reagents. Amide reduction Elements, American. "Copper Chromite". American Elements. Retrieved...
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Rhenium trioxide finds some use in organic synthesis as a catalyst for amide reduction. H. Nechamkin, C. F. Hiskey, "Rhenium(VI): Oxide (Rhenium Trioxide)"...
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Amine (section Reductive routes)
substituted-ammonium carboxylate salt → dehydration heat N | R 2 R 1 | − C O ‖ − R 3 ⏟ amide + H 2 O ⏟ water {\displaystyle {\underbrace {\ce {H-\!\!{\overset {\displaystyle...
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forming a thioester or a Weinreb amide, then reducing the new species to an aldehyde through the Fukuyama reduction or Weinreb reaction respectively,...
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Acetamide (redirect from Acetic acid amide)
methyl (CH3) groups either side of the carbonyl (CO), and urea which has two amide (NH2) groups in those locations. Acetamide is also a naturally occurring...
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primary amines. In general, oximes can be changed to the corresponding amide derivatives by treatment with various acids. This reaction is called Beckmann...
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and its primary amide, L-glutamine (also a proteinogenic amino acid). Theanine is a derivative of glutamine that is ethylated on the amide nitrogen (as the...
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in place of 'amide' in systematic or retained names of amides. (…) However, names expressing N-substitution by a phenyl group on an amide are preferred...
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Urea (redirect from Carbonyl amide)
formula CO(NH2)2. This amide has two amino groups (–NH2) joined by a carbonyl functional group (–C(=O)–). It is thus the simplest amide of carbamic acid. Urea...
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Metal bis(trimethylsilyl)amides (redirect from Metal bis(trimethylsilyl)amide)
complexes composed of a cationic metal M with anionic bis(trimethylsilyl)amide ligands (the −N(Si(CH3)3)2 monovalent anion, or −N(Si(CH3)3)2 monovalent...
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from the Sanskrit word ananda, which means "joy, bliss, delight", plus amide. Anandamide is derived from the non-oxidative metabolism of arachidonic...
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the brand name Xylocaine among others, is a local anesthetic of the amino amide type. It is also used to treat ventricular tachycardia. When used for local...
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Anesthetic (section Amide-Based)
suffix "–caine" in their names. Local anesthetics can be either ester- or amide-based. Ester local anesthetics are generally unstable in solution and fast-acting...
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may also increase the length of labor. It is a local anaesthetic of the amide group. Bupivacaine was discovered in 1957. It is on the World Health Organization's...
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(2E,6Z,8E)-deca-2,6,8-trienoic acid isobutyl amide (2E,7Z,9E)-Undeca-2,7,9-trienoic acid isobutyl amide, another alkylamide from Acmella oleracea (2E)-Undeca-2-en-8...
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deprotonation followed by reductive elimination. An unproductive side reaction can compete with reductive elimination wherein the amide undergoes beta hydride...
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with thionyl chloride and amide formation with ammonia gives 4,5-dimethoxy-2-nitrobenzamide [4959-60-8] (3). Béchamp reduction of the nitro group gives...
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