Diglyme, or bis(2-methoxyethyl) ether, is an organic compound with the chemical formula (CH3OCH2CH2)2O. It is a colorless liquid with a slight ether-like...

to brown. The structure of K2(diglyme)C8H8 has been characterized by X-ray crystallography of the derivatives with diglyme complexed to the potassium cations...

forms lumps. It can be purified by recrystallization from warm (50 °C) diglyme. Sodium borohydride is soluble in protic solvents such as water and lower...

Triethylene glycol dimethyl ether (also called triglyme) is a glycol ether used as a solvent. Monoglyme Diglyme Tetraglyme v t e...

reaction is conducted in a hot solution also containing the substrate. Diglyme is a typical solvent. The conversion of sodium chlorodifluoroacetate is...

typically diglyme, CH3OCH2CH2OCH2CH2OCH3. This triether solubilizes sodium salts, akin to the behavior of a crown ether: 4 Na + VCl3 + 6 CO + 2 diglyme →...

Diethylene glycol dimethyl ether (1-Methoxy-2-(2-methoxyethoxy)ethane, diglyme, CH3OCH2CH2OCH2CH2OCH3) Triethylene glycol dimethyl ether (2,5,8,11-Tetraoxadodecane...

reactor, temperatures also increased in the reactor until the solvent (diglyme) reached decomposition temperature. The pressure and temperature continued...

alkali metals to give a deeply colored radical anion and a dianion. The diglyme solvates of these salts have been characterized by X-ray crystallography...

code for Decigram, a unit of measure Dentate gyrus, a brain structure Diglyme, an organic solvent Directional gyroscope, a heading indicator use in aircraft...

such as toluene and N,N-dimethylethylamine give dimers, where as THF and diglyme gave monomers at high dilution. In the solid state, the unsolvated compound...

Other names Diethyl carbitol Bis(2-ethoxyethyl) ether Ethyl diglyme Diethyldiethylene glycol 3,6,9-Trioxaundecane Diethyldiglycol Identifiers...

chelating ether ligands include the glymes, dimethoxyethane (dme) and diglyme, and the crown ethers. Being lipophilic, metal-ether complexes often exhibit...

+ LiH Potassium aluminium hydride (KAlH4) can be produced similarly in diglyme as a solvent: LiAlH4 + KH → KAlH4 + LiH The reverse, i.e., production of...

ethylene glycol dimethyl ether (monoglyme), diethylene glycol dimethyl ether (diglyme), and tetraethylene glycol dimethyl ether (tetraglyme). Glymes pose minimal...

as a reducing agent in chelating solvents such as diglyme. VCl3 + 4 Na + 6 CO + 2 diglyme → Na(diglyme)2[V(CO)6] + 3 NaCl [V(CO)6]− + H+ → H[V(CO)6] → ⁠1/2⁠ H2...

48 °F; 180.66 K) Solubility in water Reacts Solubility in other solvents Diglyme and Diethyl Ether, Vapor pressure 39.5 atm (16.6 °C) Structure Coordination...

C6H14O3 (molar mass: 134.17 g/mol, exact mass: 134.0943 u) may refer to: Diglyme Dipropylene glycol 2-(2-Ethoxyethoxy)ethanol Trimethylolpropane This set...

429 K) Solubility in water insoluble Solubility slightly soluble in THF, diglyme, acetonitrile Structure Crystal structure Orthogonal Coordination geometry...

Lithium tetrahydridogallate can also be dissolved in tetrahydrofuran and diglyme. Lithium tetrahydridogallate slowly decomposes at room temperature. The...

formed can then be reduced to secondary amines with sodium borohydride in diglyme. This is a convenient route to secondary amines of the form RCH2—NH—R′...

Mo(CO)3(CH3CN)3 instead of Mo(CO)6. Thermolysis of this compound in hot solution of diglyme (bis(2-methoxyethyl)ether) results in decarbonylation, giving the tetracarbonyl...

ReH(CO)5 + ZnBrO2CCH3 It also reacts with tetraethylammonium bromide in diglyme to give [NEt4]2[ReBr3(CO)3)], an important precursor to compounds containing...

simple ethers. Crystal structures of the complexes Ph2Zn·glyme and Ph2Zn·diglyme". J. Organomet. Chem. 430: 1–13. doi:10.1016/0022-328X(92)80090-K. Pelletier...

in water 212 g/(100 mL) (29 °C) Solubility soluble in water, ethanol, diglyme, tetrahydrofuran, methanol slightly soluble in methanol insoluble in diethyl...

simple ethers. Crystal structures of the complexes Ph2Zn·glyme and Ph2Zn·diglyme". J. Organomet. Chem. 430: 1–13. doi:10.1016/0022-328X(92)80090-K. Lu,...

by Ashby et al. by one-step synthesis in toluene, tetrahydrofuran, and diglyme. Concerning the hydrogen absorption and desorption properties, this alanate...

reduction of dinitrogen by using V(Mes)3(THF). After reducing with Na metal in diglyme, Na[V(Mes)3] is reacted with N2 to form N2-bound species V(Mes)3N2Na. This...

without a catalyst present. Attempts to substitute THF with diethyl ether, diglyme, or benzene resulted only in polymerization of cyclopentadiene. The syntheses...

or Z-phosphoalkene isomers. Carrying out the phosphoalkene reaction in diglyme at 20 °C in the presence of catalytic amounts of solid NaOH forms the final...