organic chemistry, enone–alkene cycloadditions are a version of the [2+2] cycloaddition. This reaction involves an enone and alkene as substrates. Although...
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formal cycloadditions to make the distinction with true pericyclic cycloadditions. One example of a formal [3+3]cycloaddition between a cyclic enone and...
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aza-equivalent of the Paternò–Büchi reaction Enone–alkene cycloadditions - photochemical reaction of an enone with an alkene to give a cyclobutene ring unit Paterno...
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Photoredox catalysis (section Cycloadditions)
efficient intra- and intermolecular [2+2] cycloadditions of activated olefins: particularly enones and styrenes. Enones, or electron-poor olefins, were discovered...
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theory of 1,3-dipolar cycloadditions, see 1,3-dipolar cycloaddition#Frontier molecular orbital theory. 1,3-Dipolar cycloaddition reactions of azomethine...
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Carvone (category Enones)
to "Italian sunlight" for one year gives carvone-camphor. See enone–alkene cycloadditions. In the body, in vivo studies indicate that both enantiomers...
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Pauson–Khand reaction (category Cycloadditions)
reaction is a chemical reaction, described as a [2+2+1] cycloaddition. In it, an alkyne, an alkene, and carbon monoxide combine into a α,β-cyclopentenone...
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product where the terminal carbon of the alkene is linked to the α {\displaystyle \alpha } -carbon of the enone. When the tether consists only two carbons...
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Stannylene (section Cycloaddition)
its lighter carbene analogs, they readily undergo [2+4] cycloaddition reaction with Z-alkenes. The addition of (CH(SiMe3)2)2Sn, to 2,7-diphenylocta-2...
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Ketals Alcohols and diols Haloalkanes Thiols Alkanes and cycloalkanes Alkenes Alkynes Amines Amino acids, peptides, proteins Aromatics Acetophenones...
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Conia-ene reaction (category Cycloadditions)
between an enolizable carbonyl such as an ester or ketone and an alkyne or alkene, giving a cyclic product with a new carbon-carbon bond. As initially reported...
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Organic photochemistry (section [2+2] Cycloadditions)
; Morton, G. H.; Caldwell1, W. E. (1984). "Photocyclization of an Enone to an Alkene: 6-Methylbicyclo[4.2.0]Octan-2-One". Organic Syntheses. 62: 118. doi:10...
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including an indoline system. It has a tertiary amine group, an amide, an alkene and an ether group. The naturally occurring compound is also chiral with...
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Electron-Demand Diels-Alder Cycloaddition of a Ketene Dithioacetal. Copper Hydride-Promoted Reduction of a Conjugated Enone. 9-Dithiolanobicyclo[3.2.2]non-6-en-2-one"...
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Phosphetane (section [2+2] cycloaddition)
François (1990-01-01). "[2 + 2] Cycloadditions between electron-poor phospha-alkene complexes and electron-rich alkenes or alkynes, a new route to phosphetane...
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Pantazis, D. A.; McDonald, R.; Rosenberg, L. (2010). "Concerted [2+2] Cycloaddition of Alkenes to a Ruthenium-Phosphorus Double Bond". Angewandte Chemie International...
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and alkenes (Scheme 2). The initial oxidation yields the corresponding aldehyde, which can then undergo a Prins reaction with the neighboring alkene. After...
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'bromohydroxyphorone': 3-bromo-5-hydroxy-4,4,5,5-tetramethylcyclopent-2-enone", Journal of the Chemical Society C: Organic (10): 1346–1349, doi:10.1039/J39690001346...
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Silyl enol ether (category Alkene derivatives)
In the Saegusa–Ito oxidation, certain silyl enol ethers are oxidized to enones with palladium(II) acetate. Reacting a silyl enol ether with PhSCl, a good...
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Reaction of Tungsten-Containing Carbonyl Ylides: [3 + 2]-Cycloaddition Reaction with Electron-Rich Alkenes". Journal of the American Chemical Society. 127 (8):...
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Liu, Lei; Montgomery, John (2007-09-01). "[3+2] Cycloaddition Reactions of Cyclopropyl Imines with Enones". Organic Letters. 9 (20): 3885–3887. doi:10.1021/ol071376l...
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has for example been found that double bond migration in α,β-unsaturated enones and functional group elimination of certain α-substituted ketones are less...
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eliminate water following the monooxidation by Fétizon's reagent to form an enone. Under differing structural conditions, [1,2] diols can form diketones in...
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highly unstable cyclobutanolate intermediate which readily decomposes to the enone product. This reaction was utilized as the key step in Carreira's total...
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(2003-10-13). "CuH-Catalyzed Asymmetric Conjugate Reductions of Acyclic Enones". Angewandte Chemie International Edition. 42 (39): 4789–4792. doi:10.1002/anie...
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(2014). "Palladium-catalyzed 1,4-Addition of Terminal Alkynes to Conjugated Enones". Organic Syntheses. 91: 72. doi:10.15227/orgsyn.091.0072.{{cite journal}}:...
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Carpanone (category Enones)
intermediate. A particular conformation of this dimer then places a 4-electron enone of one ring over the 2-electron enol of the other (shown adjacent in image...
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Ptaquiloside (category Alkene derivatives)
treated with stannic chloride to effect Friedel-Crafts acylation to give enone 3. Hydride reduction, selective oxidation of the allylic alcohol, and silylation...
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chlorides, chromium catalyzed aerobic oxidation, an alkene isomerization catalyst, a highly active alkene polymerization catalyst, and a highly active alkyne...
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catalyst then reduced the alkyne to the alkene in 1.4 and Swern oxidation converted the alcohol group to the enone group in 1.5. Fragment C11-C15-C16-C17...
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