• organic chemistry, enonealkene cycloadditions are a version of the [2+2] cycloaddition. This reaction involves an enone and alkene as substrates. Although...
    9 KB (1,024 words) - 15:05, 11 February 2025
  • formal cycloadditions to make the distinction with true pericyclic cycloadditions. One example of a formal [3+3]cycloaddition between a cyclic enone and...
    12 KB (1,317 words) - 23:37, 6 December 2024
  • aza-equivalent of the Paternò–Büchi reaction Enonealkene cycloadditions - photochemical reaction of an enone with an alkene to give a cyclobutene ring unit Paterno...
    4 KB (331 words) - 16:11, 23 January 2025
  • Thumbnail for Photoredox catalysis
    efficient intra- and intermolecular [2+2] cycloadditions of activated olefins: particularly enones and styrenes. Enones, or electron-poor olefins, were discovered...
    50 KB (6,257 words) - 19:09, 31 March 2025
  • Thumbnail for Azomethine ylide
    theory of 1,3-dipolar cycloadditions, see 1,3-dipolar cycloaddition#Frontier molecular orbital theory. 1,3-Dipolar cycloaddition reactions of azomethine...
    18 KB (1,988 words) - 01:46, 19 April 2024
  • Thumbnail for Carvone
    Carvone (category Enones)
    to "Italian sunlight" for one year gives carvone-camphor. See enonealkene cycloadditions. In the body, in vivo studies indicate that both enantiomers...
    19 KB (1,673 words) - 13:39, 24 March 2025
  • Thumbnail for Pauson–Khand reaction
    Pauson–Khand reaction (category Cycloadditions)
    reaction is a chemical reaction, described as a [2+2+1] cycloaddition. In it, an alkyne, an alkene, and carbon monoxide combine into a α,β-cyclopentenone...
    31 KB (2,916 words) - 19:08, 31 March 2025
  • product where the terminal carbon of the alkene is linked to the α {\displaystyle \alpha } -carbon of the enone. When the tether consists only two carbons...
    11 KB (1,212 words) - 22:17, 3 December 2023
  • Thumbnail for Stannylene
    its lighter carbene analogs, they readily undergo [2+4] cycloaddition reaction with Z-alkenes. The addition of (CH(SiMe3)2)2Sn, to 2,7-diphenylocta-2...
    13 KB (1,329 words) - 15:12, 18 March 2025
  • Ketals Alcohols and diols Haloalkanes Thiols Alkanes and cycloalkanes Alkenes Alkynes Amines Amino acids, peptides, proteins Aromatics Acetophenones...
    8 KB (574 words) - 12:46, 7 March 2025
  • Conia-ene reaction (category Cycloadditions)
    between an enolizable carbonyl such as an ester or ketone and an alkyne or alkene, giving a cyclic product with a new carbon-carbon bond. As initially reported...
    15 KB (1,805 words) - 22:19, 27 September 2024
  • ; Morton, G. H.; Caldwell1, W. E. (1984). "Photocyclization of an Enone to an Alkene: 6-Methylbicyclo[4.2.0]Octan-2-One". Organic Syntheses. 62: 118. doi:10...
    15 KB (1,891 words) - 22:17, 5 April 2025
  • Thumbnail for Strychnine total synthesis
    including an indoline system. It has a tertiary amine group, an amide, an alkene and an ether group. The naturally occurring compound is also chiral with...
    39 KB (4,087 words) - 03:50, 29 February 2024
  • Thumbnail for Tropone
    Electron-Demand Diels-Alder Cycloaddition of a Ketene Dithioacetal. Copper Hydride-Promoted Reduction of a Conjugated Enone. 9-Dithiolanobicyclo[3.2.2]non-6-en-2-one"...
    12 KB (1,009 words) - 19:32, 14 September 2024
  • François (1990-01-01). "[2 + 2] Cycloadditions between electron-poor phospha-alkene complexes and electron-rich alkenes or alkynes, a new route to phosphetane...
    49 KB (5,139 words) - 23:19, 21 January 2025
  • Pantazis, D. A.; McDonald, R.; Rosenberg, L. (2010). "Concerted [2+2] Cycloaddition of Alkenes to a Ruthenium-Phosphorus Double Bond". Angewandte Chemie International...
    22 KB (2,316 words) - 20:05, 3 March 2025
  • Thumbnail for Elias James Corey
    and alkenes (Scheme 2). The initial oxidation yields the corresponding aldehyde, which can then undergo a Prins reaction with the neighboring alkene. After...
    56 KB (5,744 words) - 04:17, 5 May 2025
  • 'bromohydroxyphorone': 3-bromo-5-hydroxy-4,4,5,5-tetramethylcyclopent-2-enone", Journal of the Chemical Society C: Organic (10): 1346–1349, doi:10.1039/J39690001346...
    25 KB (2,696 words) - 17:44, 11 September 2024
  • Silyl enol ether (category Alkene derivatives)
    In the Saegusa–Ito oxidation, certain silyl enol ethers are oxidized to enones with palladium(II) acetate. Reacting a silyl enol ether with PhSCl, a good...
    13 KB (1,369 words) - 22:56, 11 March 2025
  • Thumbnail for Pentacarbonyl(tetrahydrofuran)tungsten
    Reaction of Tungsten-Containing Carbonyl Ylides: [3 + 2]-Cycloaddition Reaction with Electron-Rich Alkenes". Journal of the American Chemical Society. 127 (8):...
    32 KB (3,002 words) - 08:18, 1 April 2025
  • Thumbnail for Activation of cyclopropanes by transition metals
    Liu, Lei; Montgomery, John (2007-09-01). "[3+2] Cycloaddition Reactions of Cyclopropyl Imines with Enones". Organic Letters. 9 (20): 3885–3887. doi:10.1021/ol071376l...
    19 KB (2,115 words) - 09:22, 10 June 2024
  • has for example been found that double bond migration in α,β-unsaturated enones and functional group elimination of certain α-substituted ketones are less...
    41 KB (4,213 words) - 14:43, 19 February 2025
  • eliminate water following the monooxidation by Fétizon's reagent to form an enone. Under differing structural conditions, [1,2] diols can form diketones in...
    16 KB (1,734 words) - 08:59, 29 August 2023
  • highly unstable cyclobutanolate intermediate which readily decomposes to the enone product. This reaction was utilized as the key step in Carreira's total...
    13 KB (1,558 words) - 14:21, 5 September 2024
  • Thumbnail for Ugi's amine
    (2003-10-13). "CuH-Catalyzed Asymmetric Conjugate Reductions of Acyclic Enones". Angewandte Chemie International Edition. 42 (39): 4789–4792. doi:10.1002/anie...
    17 KB (1,790 words) - 14:12, 25 February 2024
  • Thumbnail for Ynone
    (2014). "Palladium-catalyzed 1,4-Addition of Terminal Alkynes to Conjugated Enones". Organic Syntheses. 91: 72. doi:10.15227/orgsyn.091.0072.{{cite journal}}:...
    4 KB (447 words) - 23:21, 5 October 2022
  • Thumbnail for Carpanone
    Carpanone (category Enones)
    intermediate. A particular conformation of this dimer then places a 4-electron enone of one ring over the 2-electron enol of the other (shown adjacent in image...
    12 KB (1,206 words) - 00:53, 22 February 2022
  • Thumbnail for Ptaquiloside
    Ptaquiloside (category Alkene derivatives)
    treated with stannic chloride to effect Friedel-Crafts acylation to give enone 3. Hydride reduction, selective oxidation of the allylic alcohol, and silylation...
    29 KB (3,228 words) - 21:36, 20 February 2025
  • Thumbnail for Adam S. Veige
    chlorides, chromium catalyzed aerobic oxidation, an alkene isomerization catalyst, a highly active alkene polymerization catalyst, and a highly active alkyne...
    10 KB (966 words) - 05:47, 30 March 2025
  • Thumbnail for Kuwajima Taxol total synthesis
    catalyst then reduced the alkyne to the alkene in 1.4 and Swern oxidation converted the alcohol group to the enone group in 1.5. Fragment C11-C15-C16-C17...
    11 KB (1,349 words) - 21:47, 16 July 2024