In organometallic chemistry, f-block metallocenes are a class of sandwich compounds consisting of an f-block metal and a set of electron-rich ligands...

related to the metallocenes are the metallocene derivatives, e.g. titanocene dichloride or vanadocene dichloride. Certain metallocenes and their derivatives...

and Subsequent Work by the Research Groups of E. O. Fischer, H. H. Zeiss, F. Hein, C. Elschenbroich, and Others". Organometallics. 21 (14): 2800–2820...

rather than covalent (see lanthanocenes). Organoactinide chemistry f-block metallocene Berkelocene was prepared with an annulated COT ligand,...

bonding. The discovery of ferrocene and its many analogues, known as metallocenes, sparked excitement and led to a rapid growth in the discipline of organometallic...

Gerhard (1998). "Ethene−Norbornene Copolymerization with Homogeneous Metallocene and Half-Sandwich Catalysts: Kinetics and Relationships between Catalyst...

carried out with the use of a special class of metallocene catalysts. They employ bridged bis-metallocene complexes of the type bridge-(Cp1)(Cp2)ZrCl2 where...

stereoregularity of the polymerisation of alkenes using Ziegler–Natta or metallocene catalysts. Stereoregularity is relevant for unsymmetrical alkenes such...

of initiating system contains a metallocene, an initiator, and a heteroaromatic diketo carboxylic acid. Metallocenes in combination with initiators accelerate...

transfer to the co-initiator) and as a result are not considered living. Metallocene initiators are considered as a type of Ziegler-Natta initiators due to...

Chiral auxiliaries on the metallocene ligands were used to dictate the stereochemistry of the product. The first non-metallocene chiral catalysts were reported...

that time, Kiplinger also reported improved synthesis of uranium-based metallocene complexes (C5Me5)U(CH2C6H5)3. Kiplinger continued her research at LANL...

the formula (η5-C5H5)2TiCl2, commonly abbreviated as Cp2TiCl2. This metallocene is a common reagent in organometallic and organic synthesis. It exists...

Mansikkamäki, Akseli; Layfield, Richard A. (2017-09-11). "A Dysprosium Metallocene Single-Molecule Magnet Functioning at the Axial Limit". Angewandte Chemie...

molecules with different molecular vibrations have different smells (metallocene experiment and deuterium replacement of molecular hydrogen). However...

a cocatalyst, MAO is well known for their use in metallocene chemistry as they activate metallocene complexes for olefin polymerization. To remove the...

structures in solution, though in the gaseous state they are often monomeric. Metallocene compounds with group 2 elements are rare, but some do exist....

crystals. It is an example of an s-block main group sandwich compound, structurally related to the d-block element metallocenes, and consists of a central magnesium...

"A WAXD/SAXS/DSC study on the melting behavior of Ziegler-Natta and metallocene catalyzed isotactic polypropylene". Journal of Polymer Science Part B:...

Groshens, T. J.; Furche, F. P.; Harvey, B. G.; Long, J. R. (2019-08-21). "Synthesis and Magnetism of Neutral, Linear Metallocene Complexes of Terbium(II)...

NiCp2 with +2 Ni oxidation state and 20 valence electrons is the main metallocene of nickel. It can be oxidized by one electron. The corresponding palladocene...

simplest hafnium metallocene is hafnocene dichloride. Hafnium metallocenes are part of a large collection of Group 4 transition metal metallocene catalysts that...

Schwartz's reagent, prepared in 1970 by P. C. Wailes and H. Weigold, is a metallocene used in organic synthesis for transformations of alkenes and alkynes...

main-group cyclopentadienyl complex; these molecules are related to metallocenes but contain p-block elements as the central atom. It is a colorless, air sensitive...

their 5f electrons. Other +3 oxidation states include the sulfide and metallocene. Europium, in the sixth period directly above element 95, was named for...

Polymerization of Methylenecycloalkanes Catalyzed by Highly Electrophilic d 0 /f n Metallocenes. Reactivity, Scope, Reaction Mechanism, and Routes to Functionalized...

said to be "sandwiched". A special class of sandwich complexes are the metallocenes. The term sandwich compound was introduced in organometallic nomenclature...

1000 °C in inert atmosphere. Berkelium forms a trigonal (η5–C5H5)3Bk metallocene complex with three cyclopentadienyl rings, which can be synthesized by...

"A Homologous Series of Regioselectively Tetradeprotonated Group 8 Metallocenes: New Inverse Crown Ring Compounds Synthesized via a Mixed Sodium−Magnesium...

270 °C (518 °F). Syndiotactic polystyrene resin is currently produced under the trade name XAREC by Idemitsu corporation, who use a metallocene catalyst for...