Inner sphere electron transfer (IS ET) or bonded electron transfer is a redox chemical reaction that proceeds via a covalent linkage—a strong electronic...
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event. In such cases, the electron transfer is termed intermolecular electron transfer. A famous example of an inner sphere ET process that proceeds via...
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for inner sphere electron transfer the participating redox sites undergoing ET become connected by a chemical bridge. Because the ET in outer sphere electron...
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Marcus theory (section Inner sphere electron transfer)
outer sphere electron transfer. Outer sphere ET is the main focus of traditional Marcus Theory. The other kind or redox reactions is inner sphere where...
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Inner Sphere may refer to: Inner sphere complex, a type of ion-surface binding Inner sphere electron transfer, a chemical reaction involving closely associated...
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Redox (redirect from One-electron reduction)
reactions occur by two distinct pathways, inner sphere electron transfer and outer sphere electron transfer. Analysis of bond energies and ionization...
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Creutz–Taube complex, a metal complex that was used to study Inner sphere electron transfer. Creutz earned her undergraduate degree in chemistry at University...
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coordination sphere. These effects are relevant to practical applications such as contrast agents used in MRI. The energetics of inner sphere electron transfer reactions...
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an effort to understand the intimate details of inner sphere electron transfer, that is, how electrons move from one metal complex to another. The ion...
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adiabatic electron-transfer is a type of oxidation-reduction process. The mechanism is ubiquitous in nature in both the inorganic and biological spheres. Adiabatic...
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Copper-based reversible-deactivation radical polymerization (section Single electron transfer living radical polymerization (SET-LRP))
of all alkyl halides occurs by inner sphere electron transfer (ISET). Another model is called single-electron transfer living radical polymerization (SET-LRP)...
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binding with perchlorate to form a transient inner sphere complex more favourable to electron transfer considerably hinders the redox reaction. The redox...
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on Endovascular Therapy - trade conference Inner sphere electron transfer, a mechanism of electron transfer in inorganic chemistry Institut Supérieur des...
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Mixed-valence complex (category Electron)
complex serves as a model for the bridged intermediate invoked in inner-sphere electron transfer. Odd-Numbered Ring Cluster Tc9(μ-O)9Cl6(OOCCCl3)15 where Tc...
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reactants and products, all products formed and the amount of each. The electron or arrow pushing method is often used in illustrating a reaction mechanism;...
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These valence electrons also facilitate all types of chemical reactions by being transferred or shared between atoms. The inner electron shells make up...
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to the superoxide anion on its oxygen binding site, through inner-sphere electron transfer. (Mn) is reduced by superoxide, yielding molecular oxygen and...
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formulated to address outer sphere electron transfer reactions, in which two chemical species change only in their charge, with an electron jumping. For redox...
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effect one-electron oxidations, which is invoked in this conversion. Oxidative phenol couplings can occur through either inner sphere or outer sphere processes...
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1983 Nobel Prize in Chemistry for "his work in the mechanisms of electron-transfer reactions, especially in metal complexes." He was the second Canadian-born...
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Disproportionation Dötz reaction Eder reaction Electromerism Electron transfer (inner sphere and outer sphere) Étard reaction Fenton oxidation Fischer–Tropsch process...
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to detect in secondary electron images. Characteristic X-rays are emitted when the electron beam removes an inner shell electron from the sample, causing...
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electron transfer. The active site of a type-I blue copper protein. Two 2-histidines, 1 methionine and 1 cysteine present in the coordination sphere....
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spheres must be the atoms that make up the molecule – two hydrogen atoms bonded to a single oxygen atom. And I see that it's the orbiting electrons that...
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Atom (section Discovery of the electron)
that the balance of electrostatic forces would distribute the electrons throughout the sphere in a more or less even manner. Thomson's model is popularly...
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only the "inner sphere" of an atom's electron distribution; the electron redistribution associated with Lewis adducts affects the "outer sphere" instead...
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aqueous Fe2+ and does not contribute to the electron transfer by favoring the formation of an inner sphere complex giving rise to a possible reorganisation...
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reactivities: Electron transfers Electron transfer (ET) between metal ions can occur via two distinct mechanisms, inner and outer sphere electron transfers. In...
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predicted role of the [4Fe-4S]2+cofactor is to transfer an electron onto SAM through an inner sphere mechanism, forcing it into an unstable high energy...
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to the sphere, and the lower one (7) to ground. When a motor is used to drive the belt, the triboelectric effect causes the transfer of electrons from the...
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