Oxidation with chromium(VI) complexes involves the conversion of alcohols to carbonyl compounds or more highly oxidized products through the action of...

Chromium(VI) oxide peroxide is a chemical compound with the chemical formula CrO(O2)2. The name "chromium(VI) oxide peroxide" is also given to a collection...

chromium (III), the oxidation-reduction conversions between the two oxidation states have implications for movement and bioavailability of chromium in...

sigmatotropic reaction as for tertiary alcohols. Oxidation with chromium(VI) complexes Oxoammonium-catalyzed oxidation Other reactions of PCC Killoran, Patrick...

Hexavalent chromium (chromium(VI), Cr(VI), chromium 6) is any chemical compound that contains the element chromium in the +6 oxidation state (thus hexavalent)...

within chromium compounds, followed by +2; charges of +1, +4 and +5 for chromium are rare, but do nevertheless occasionally exist. Many Cr(0) complexes are...

over oxidation to carboxylic acids. Chromium(VI) reagents are commonly used for these oxidations. One family of Cr(VI) reagents employs the complex CrO3(pyridine)2...

chromium trioxide. The oxidation is very rapid and quite exothermic. Yields are typically high. The reagent is convenient and cheap. However, Cr(VI)...

The Sarett oxidation is an organic reaction that oxidizes primary and secondary alcohols to aldehydes and ketones, respectively, using chromium trioxide...

trioxide is the anhydride. Chromic acid features chromium in an oxidation state of +6 (and a valence of VI or 6). It is a strong and corrosive oxidizing...

popularized by J. C. Collins several years later. Sarett oxidation Oxidation with chromium(VI)-amine complexes Collins reagent can be used as an alternative to...

In chemistry, the oxidation state, or oxidation number, is the hypothetical charge of an atom if all of its bonds to other atoms are fully ionic. It describes...

bis(benzene)chromium. The compound reacts with carboxylic acids to give chromium(II) carboxylates, such as chromium(II) acetate. Oxidation affords [Cr(C6H6)2]+...

Common oxidation states of manganese are +2, +3, +4, +6, and +7, although all oxidation states from −3 to +7 have been observed. Manganese in oxidation state...

Transition metal complexes of thiocyanate describes coordination complexes containing one or more thiocyanate (SCN−) ligands. The topic also includes...

is its toxicity, which it shares with other hexavalent chromium compounds. Oxidation with chromium(VI)-amine complexes Piancatelli, G.; Luzzio, F. A. (2007)...

primarily of iron(II) oxide and chromium(III) oxide compounds. It can be represented by the chemical formula of FeCr2O4. It is an oxide mineral belonging...

contain the dichromate anion, Cr2O2−7. They are oxyanions of chromium in the +6 oxidation state and are moderately strong oxidizing agents. In an aqueous...

reagent, a complex of chromium(VI) oxide with pyridine in dichloromethane. The mechanism of the Collins oxidation is a relatively simple oxidation process...

hydrochloric acid and aqueous methanol. Slow reaction rates are common with chromium(III) complexes. The low reactivity of the d3 Cr3+ ion can be explained using...

give Fischer carbene complexes: Treatment of chromium hexacarbonyl with sodium cyclopentadienide gives Na+[Cr(CO)3(C5H5)]−. Oxidation of this salt affords...

Chromium(II) acetate hydrate, also known as chromous acetate, is the coordination compound with the formula Cr2(CH3CO2)4(H2O)2. This formula is commonly...

to prevent the oxidation of trivalent chromium to the anodes. A sulfate-based bath that uses lead anodes surrounded by boxes filled with sulfuric acid...

mid-level oxidation states are often associated with metal clusters, and very low oxidation states are typically associated with CO complexes. The chemistries...

often consumed stoichiometrically. chromium(VI) reagents are popular. Oxidation can be achieved by heating the alcohol with an acidified solution of potassium...

along with iron. The most common oxidation state of nickel is +2, but compounds of Ni0, Ni+, and Ni3+ are well known, and the exotic oxidation states...

reactions, reacts vigorously with water. The inventory of complexes is very large. Starting with higher oxidation states, complexes of Co(IV) and Co(V) are...

ammonia with borohydride and sodium metal, respectively) yields the anionic carbonyl complexes [W2(CO)10]2- & [W(CO)4]4-. Also known are the complexes [W(CO)5]2-...

in its low oxidation states similar to that of iron, but osmium does not, favoring high oxidation states in which it forms anionic complexes. In the second...

dithiocarbamate complexes are coordination complexes containing one or more dithiocarbamate ligand, which are typically abbreviated R2dtc−. Many complexes are known...