The Perkow reaction is an organic reaction in which a trialkyl phosphite ester reacts with a haloketone to form a dialkyl vinyl phosphate and an alkyl...
4 KB (437 words) - 23:45, 5 April 2023
halide. The Perkow reaction is a competing reaction pathway for α-bromo- and α-chloroketones. Under the reaction conditions a mixture of the Perkow product...
13 KB (1,592 words) - 20:48, 27 January 2025
Nucleophilic substitution (redirect from Nucleophilic substitution reaction)
ring-closing reaction of aminoalcohols. The Finkelstein reaction, a halide exchange reaction. Phosphorus nucleophiles appear in the Perkow reaction and the...
13 KB (1,536 words) - 08:50, 10 May 2025
synthesis Perkin reaction Perkin rearrangement Perkow reaction Petasis reaction Petasis reagent Peterson olefination Peterson reaction Petrenko-Kritschenko...
37 KB (3,428 words) - 16:27, 11 November 2024
reaction is general, thus a vast number of such species are known. Phosphites are employed in the Perkow reaction and the Michaelis–Arbuzov reaction....
19 KB (1,984 words) - 12:31, 10 April 2025
Α-Halo ketone (section Reactions)
1-chloropropane by a factor of 36,000. Halo ketones react with phosphites in the Perkow reaction. The halo group can be removed in reductive dehalogenation of halo...
6 KB (670 words) - 13:34, 30 October 2023
phosphite esters are used in the Perkow reaction for the formation of vinyl phosphonates, and in the Michaelis–Arbuzov reaction to form phosphonates. Aryl phosphite...
9 KB (979 words) - 21:53, 17 June 2024
RXNO Ontology (section Major Reaction Categories)
RXNO:0000157 Nef reaction RXNO:0000183 Perkow reaction RXNO:0000193 Hiyama coupling RXNO:0000210 Fleming–Tamao oxidation RXNO:0000218 Cannizzaro reaction RXNO:0000288...
5 KB (417 words) - 21:10, 1 May 2025
Hexachloroacetone (section Reactions and uses)
hexachloroacetone in the preparation of a novel insect repellent see Perkow reaction. The industrial route to hexafluoroacetone involves treatment of hexachloroacetone...
3 KB (179 words) - 07:43, 25 April 2025
1970. Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel, Perkow, W., Berlin, Verlag Paul Parey, 1971-1976Vol. -, Pg. -, 1971/1976. Bollettino...
18 KB (1,878 words) - 15:58, 13 March 2025