Silylene is a chemical compound with the formula SiH2. It is the silicon analog of methylene, the simplest carbene. Silylene is a stable molecule as a...

An N-Heterocyclic silylene (NHSi) is an uncharged heterocyclic chemical compound consisting of a divalent silicon atom bonded to two nitrogen atoms. The...

This distortion is rationalized by the stability of the corresponding silylene fragments, although disilenes do not typically dissociate. The distorted...

48 hours and with heat induces cage opening in the same manner as the silylene reaction to generate H2C=P(tBuC)3. Reaction of this product with tBu3C3P...

monoxide (CO) reacting with main-group starting materials such as ylides, silylene, and phosphinidene to synthesize and isolate for further steps. As CO becomes...

employed in the trapping: Another classic but elusive family of targets are silylenes, analogues of carbenes. It was proposed that dechlorination of dimethyldichlorosilane...

are the silicon pendants of carbenoid and both compounds have carbene or silylene like properties. Silylenoids are encountered as reactive intermediates...

ω-(trimethylsilyloxy)poly[oxy(dimethyl)silylene]- co-[oxy(methyl)(2-{4-[2,2-bis(ethoxycarbonyl)vinyl]phenoxy}- 1-methyleneethyl)silylene]- co-[oxy(methyl)(2-(4-[2...

formation of radical intermediates, polysilanes decompose by eliminating silylenes :SiH 2 or :SiHR, as the activation energy of this process (~210 kJ/mol)...

organogermanium compounds, organotin compounds, organolead compounds Silylenes, the carbene counterparts Silylenoids, the carbenoid counterparts Decamethylsilicocene...

compounds Related compounds Methyl (CH3) Methylidyne (CH) Carbide (C) Silylene (SiH2) Except where otherwise noted, data are given for materials in their...

P4O9, trimethylamuminium and its adducts with NMe3, and the first stable silylene. Haaland was the author of many contributions on chemical bonding, in particular...

decamethylsilicocene through salt metathesis from an N-heterocyclic carbene-stabilized silylene. This synthetic route avoids the synthesis of the bis(pentamethylcyclo...

Dichlorosilane Names IUPAC name Dichlorosilane Other names Silylene dichloride Identifiers CAS Number 4109-96-0 Y 3D model (JSmol) Interactive image Abbreviations...

interactions. It was also inspired by previous reports of trisilaallene: a silylene complex featuring a bent geometry about the Si-Si-Si center. The unexpected...

Phosphasilenes with 4-coordinate silicon, which can also be viewed as silylene-stabilized phosphinidene, can be synthesized based on the reactivities...

Latvia Silenė [lv], one of the lands of the historical Semigallia, Latvia Silylene, another class of silicon compounds Silanes Selene (disambiguation) Seline...

; Tilley, T. Don (1999-10-01). "Silylene Extrusion from a Silane: Direct Conversion of Mes2SiH2 to an Iridium Silylene Dihydride". Journal of the American...

tropylium, C7H+7 (protonated tropylidene) silylium cations, R3Si+ (protonated silylenes) nitrenium cations, R2N+ (protonated nitrenes) phosphinidenium cations...

form double bonds). West later discovered the first example of a stable silylene, a form of divalent silicon, acting as the silicon analog to the now catalytically...

Gerard (2014-12-31). "σ-Silane, Disilanyl, and [W(μ-H)Si(μ-H)W] Bridging Silylene Complexes via the Reactions of W(PMe 3 ) 4 (η 2 -CH 2 PMe 2 )H with Phenylsilanes"...

chemical entities including arenes, CO/HCl, HMgBr, H2Zn, H2O, carbene, silylene, sulfenium have also been shuttled under this catalysis platform. Bhawal...

ligand substituents. There are also a handful of reported N-heterocyclic silylene and other NHC-type Cu complexes. Of the three coinage metals discussed...

silanimine -NHSiH3, With a double bond between silicon and the metal a silylene complex is formed. With a triple bond, M≡SiH forms with metals such as...

D. "Synthetic Development and Chemical Reactivity of Transition-Metal Silylene Complexes." Acc. Chem. Res. 40.8 (2007): 712–719. Tilley, T.D. "The Coordination...

involve units of arsenic with more than four atoms. In reaction with the silylene compound [PhC(NtBu)2SiN(SiMe3)2], an aggregation of As4 was observed to...

Haaf, Michael; Schmedake, Thomas A.; West, Robert (2000-10-01). "Stable Silylenes". Accounts of Chemical Research. 33 (10): 704–714. doi:10.1021/ar950192g...

substituted with halogen atoms. In the monomeric silicon dihalide (aka dihalo-silylene and dihalosilene) molecule, which is analogous to carbene molecules, the...

1021/ct050154a. ISSN 1549-9618. PMID 26633055. Kira, Mitsuo (2005-03-29). "Isolable Silylene, Disilenes, Trisilaallene, and Related Compounds". ChemInform. 36 (13)...

reductive elimination, yielding O- or N-B bond formation. Carbene analogs Silylene Sasamori, T.; Tokitoh, N. (2005). Encyclopedia of Inorganic Chemistry II...