• Arrow pushing or electron pushing is a technique used to describe the progression of organic chemistry reaction mechanisms. It was first developed by...
    18 KB (2,084 words) - 12:14, 24 May 2025
  • Thumbnail for Pericyclic reaction
    approach to analyzing the transition state of a pericyclic reaction. The arrow-pushing convention for pericyclic reactions has a somewhat different meaning...
    10 KB (1,162 words) - 16:49, 21 April 2024
  • Thumbnail for Reaction mechanism
    products, all products formed and the amount of each. The electron or arrow pushing method is often used in illustrating a reaction mechanism; for example...
    14 KB (1,614 words) - 07:39, 13 June 2025
  • Thumbnail for Paraben
    Arrow pushing mechanism showing the degradation of a parent paraben into PHBA through base-catalyzed hydrolysis of the ester bond...
    19 KB (2,325 words) - 21:48, 29 May 2025
  • Thumbnail for Hydrohalogenation
    by attack of HX/X− to give the product (AdE2) (see electrophile for arrow pushing). As in the case of alkenes, the regioselectivity is determined by the...
    6 KB (791 words) - 07:43, 16 November 2023
  • Thumbnail for Oxytetracycline
    Figure 2 shows the biosynthesis as described above, as well as an arrow-pushing mechanism of NADPH being used as the final cofactor in the biosynthesis...
    17 KB (1,709 words) - 08:52, 27 May 2025
  • α-ketoisovalerate combines with TPP and is then decarboxylated. The proper arrow-pushing mechanism is shown in Figure 3. STEP 2: The 2-methylpropanol-TPP is...
    16 KB (1,781 words) - 18:08, 24 April 2024
  • orbital on a sp2 hybridized oxygen) to π*C=C (LUMO), corresponding, in arrow-pushing terms, to formation of one C-O bond and cleavage of the O-O bond and...
    6 KB (471 words) - 02:57, 23 October 2024
  • Thumbnail for Abhik Ghosh
    science book on careers in chemistry research. In 2014, he coauthored Arrow Pushing in Inorganic Chemistry: A Logical Approach to the Chemistry of the Main...
    32 KB (3,257 words) - 19:02, 22 May 2025
  • Thumbnail for SN2 reaction
    around once before the actual SN2 displacement mechanism takes place. Arrow pushing Christopher Kelk Ingold Finkelstein reaction Neighbouring group participation...
    21 KB (2,555 words) - 13:23, 25 May 2025
  • Thumbnail for Prilezhaev reaction
    reaction mechanism using the arrow pushing shown here and has a discussion on using proper electron sources in Appendix 5 ("Pushing Electrons," pp. 1061-1074)...
    8 KB (844 words) - 20:30, 22 July 2024
  • Arrow pushing for the Robinson annulation between 2-methylcyclohexan-1-one and but-3-en-2-one in the presence of sodium ethoxide as the base...
    15 KB (1,742 words) - 15:32, 24 May 2025
  • Thumbnail for Organic reaction
    progression of reaction mechanisms can be represented using arrow pushing techniques in which curved arrows are used to track the movement of electrons as starting...
    14 KB (1,182 words) - 20:28, 22 July 2024
  • Thumbnail for Darzens reaction
    Arrow-pushing mechanism for the Darzens reaction....
    7 KB (717 words) - 00:06, 16 January 2025
  • Thumbnail for Radical (chemistry)
    single-headed arrows to depict the movement of single electrons: The homolytic cleavage of the breaking bond is drawn with a "fish-hook" arrow to distinguish...
    41 KB (4,609 words) - 22:34, 15 June 2025
  • Thumbnail for Avro Canada CF-105 Arrow
    The Avro Canada CF-105 Arrow was a delta-winged interceptor aircraft designed and built by Avro Canada. The CF-105 held the promise of Mach 2 speeds at...
    82 KB (10,421 words) - 01:55, 10 June 2025
  • Thumbnail for Organic chemistry
    given reaction mechanism can be represented using arrow pushing techniques in which curved arrows are used to track the movement of electrons as starting...
    38 KB (4,341 words) - 23:30, 7 May 2025
  • −2.3, 50% ethanol in water Y = +1.65 and 15% concentration Y = +3.2. Arrow pushing Nucleophilic acyl substitution Neighbouring group participation SN2...
    15 KB (1,970 words) - 03:54, 24 October 2024
  • Thumbnail for Aconitase
    Aconitase arrow-pushing mechanism...
    15 KB (1,527 words) - 12:48, 27 May 2025
  • currently held by John F. Hartwig. Daniel E. Levy dedicated his book Arrow Pushing in Organic Chemistry: An Easy Approach to Understanding Reaction Mechanisms...
    3 KB (340 words) - 18:13, 4 June 2025
  • Thumbnail for Glucose
    Widely proposed arrow-pushing mechanism for acid-catalyzed dynamic equilibrium between the α- and β- anomers of D-glucopyranose...
    124 KB (13,033 words) - 17:20, 8 June 2025
  • The first season of the American action television series Arrow premiered on The CW on October 10, 2012, at 8:00 pm (ET) and concluded on May 15, 2013...
    114 KB (5,696 words) - 02:38, 28 May 2025
  • Thumbnail for Lactate dehydrogenase
    Arrow pushing mechanism for the reaction catalyzed by lactate dehydrogenase...
    42 KB (4,795 words) - 15:37, 5 February 2025
  • Arrow pushing mechanism of DAINV. Bonds broken are labelled in red; bonds made are labelled in blue....
    26 KB (2,637 words) - 09:48, 7 January 2025
  • Wiley-Interscience, ISBN 0-471-19957-5. Ghosh, Abhik; Berg, Steffen (2014). Arrow Pushing in Inorganic Chemistry: A logical approach to the chemistry of the main-group...
    64 KB (1,444 words) - 07:25, 1 June 2025
  • Thumbnail for Robert Robinson (chemist)
    Andrews University in 1923. He is known for inventing the use of the curly arrow to represent electron movement, and he is also known for discovering the...
    16 KB (1,243 words) - 22:30, 31 May 2025
  • Arrow pushing mechanism for the acid catalyzed rearrangement for the synthesis of 2-furylcarbinols....
    7 KB (702 words) - 16:45, 23 January 2025
  • Arrow is an American superhero television series developed by Greg Berlanti, Marc Guggenheim, and Andrew Kreisberg based on the DC Comics character Green...
    131 KB (16,278 words) - 13:10, 24 April 2025
  • The sixth season of the American television series Arrow premiered on The CW on October 12, 2017, and concluded on May 17, 2018, with a total of 23 episodes...
    112 KB (5,531 words) - 19:55, 4 April 2025
  • Methylglyoxal synthase arrow-pushing mechanism....
    18 KB (2,053 words) - 05:32, 23 September 2024