In chemistry, a metal carbonyl cluster is a compound that contains two or more metal atoms linked in part by metal–metal bonds and containing carbon monoxide...

Metal carbonyls are coordination complexes of transition metals with carbon monoxide ligands. Metal carbonyls are useful in organic synthesis and as catalysts...

featuring significant metal-metal interactions. The development of metal carbonyl clusters such as Ni(CO)4 and Fe(CO)5 led quickly to the isolation of Fe2(CO)9...

the chemical compound with the formula Ru3(CO)12. Classified as metal carbonyl cluster, it is a dark orange-colored solid that is soluble in nonpolar organic...

Hexadecacarbonylhexarhodium is a metal carbonyl cluster with the formula Rh6(CO)16. It exists as purple-brown crystals that are slightly soluble in dichloromethane...

This yellow-colored metal carbonyl cluster is an important precursor to organo-osmium compounds. Many of the advances in cluster chemistry have arisen...

octacarbonyl is an organocobalt compound with composition Co2(CO)8. This metal carbonyl is used as a reagent and catalyst in organometallic chemistry and organic...

carboranes, the higher boranes and borane anions, and various transition-metal carbonyl cluster compounds". J. Chem. Soc. D. 1971 (15): 792–793. doi:10.1039/C29710000792...

carboranes, the higher boranes and borane anions, and various transition-metal carbonyl cluster compounds". J. Chem. Soc. D. 1971 (15): 792–793. doi:10.1039/C29710000792...

common spiro [4.3] cluster compound. Adding to the transition metal-bismuth carbonyl clusters, the dibismuth clusters with transition metals have also been...

source of iron(0) than iron pentacarbonyl. It was one of the first metal carbonyl clusters synthesized. It was occasionally obtained from the thermolysis...

insoluble in water and easily oxidized by air. It is an example of a metal carbonyl cluster. This compound is synthesized by decarbonylation of Co2(CO)8. 2...

is an organometallic cobalt cluster with the chemical formula Co3(CO)9CH that contains a metal carbonyl core with the methylidyne ligand, first...

In organic chemistry, carbonyl reduction is the conversion of any carbonyl group, usually to an alcohol. It is a common transformation that is practiced...

ketenylidene in organometallic chemistry, it is a ligand observed in metal carbonyl clusters, e.g. [OC2Co3(CO)9]+. Ketenylidenes are proposed as intermediates...

Clusters". He was a pioneer in metal carbonyl cluster syntheses. He developed and improved quantitative methods for the synthesis of large carbonyl clusters...

accommodate doubly bridging halides. In the area of metal carbonyl clusters, a prototypical octahedral cluster is [Fe6C(CO)16]2−, which is obtained by heating...

nonacarbonyl is an organometallic compound with the formula Fe2(CO)9. This metal carbonyl is a reagent in organometallic chemistry and of occasional use in organic...

fluxional properties of metal carbonyl and metal isocyanide complexes. Some complexes that exhibit this process are cobalt carbonyl and cyclopentadienyliron...

RPCl2 with [Cp2MHLi]4. Metal clusters containing RP substituents are numerous. They typically arise by the reaction of metal carbonyls with primary phosphines...

homoleptic carbonyl and magnesium a mononuclear heteroleptic carbonyl, both with only two carbonyl ligands instead of eight to each metal atom. The first...

phosphorus atom) capping a cyclopropyl trianion also exist. Several metal carbonyl clusters are referred to as tetrahedranes, e.g. tetrarhodium dodecacarbonyl...

direct reaction of nickel metal with carbon monoxide. This pioneering work foreshadowed the existence of many other metal carbonyl compounds, including those...

formula Mn2(CO)10, is a binary bimetallic carbonyl complex centered around the first row transition metal manganese. The first reported synthesis of...

and a metal follows the same principles as the bonding in carbonyl complexes. The nitrosyl cation serves as a two-electron donor to the metal and accepts...

dedicated to magnetic properties of metal complexes. He achieved significant acclaim for contributions to metal carbonyl clusters. Together with his longtime...

of organic halides to metal carbonyl anions (M-44). From this period a very short intellectual step took her to metal carbonyl hydrides; a functionality...

configuration by covalent bonding. The lowest oxidation states are exhibited in metal carbonyl complexes such as Cr(CO) 6 (oxidation state zero) and [Fe(CO) 4]2− (oxidation...

In the area of metal cluster chemistry, a butterfly cluster compound usually describes tetrametallic clusters containing five M-M bonds. A prototype of...

carbonyl complex. In the 1930s Robert Mond developed methods which used increased pressure and temperature to produce various forms of metal carbonyl...