The principle of microscopic reversibility in physics and chemistry is twofold: First, it states that the microscopic detailed dynamics of particles and...

principle. The arguments in favor of this property are founded upon microscopic reversibility. Five years before Boltzmann, James Clerk Maxwell used the principle...

their average distance apart. Due to the time reversibility of microscopic dynamics (microscopic reversibility), the kinetic theory is also connected to the...

relations. T-symmetry of the microscopic description together with its kinetic consequences are called microscopic reversibility. Classical variables that...

equilibrium Chemical equilibrium Irreversibility Microscopic reversibility Static equilibrium "Reversible Reaction". lumenlearning.com. Retrieved 2021-01-08...

statistical mechanics as a consequence of the time reversibility of microscopic dynamics (microscopic reversibility). The theory developed by Onsager is much more...

are derived from statistical mechanics under the principle of microscopic reversibility (in the absence of external magnetic fields). Given a set of extensive...

7850. doi:10.1155/S1026022604401046. Lebowitz, Joel L. (1995). "Microscopic reversibility and macroscopic behavior: Physical explanations and mathematical...

relations as a consequence of the time reversibility of microscopic dynamics, also known as microscopic reversibility. A body at temperature T radiates electromagnetic...

organic reactions Mass balance Microscopic reversibility Organic reaction Reaction progress kinetic analysis Reversible reaction IUPAC, Compendium of Chemical...

In mathematics and physics, time-reversibility is the property of a process whose governing rules remain unchanged when the direction of its sequence...

way to achieve catalysis. All chemical processes are reversible (law of microscopic reversibility) although some processes have such an energy bias, they...

notoriously unreactive towards SN2 reactions. Based on the principle of microscopic reversibility, the inert nature of the neopentyl halides towards the SN2 reaction...

relations were proved on the basis of the time reversibility of microscopic dynamics (microscopic reversibility) as Onsager reciprocal relations. Many physical...

cannot catalyse just one direction, according to the principle of microscopic reversibility). We consider the case of an enzyme that catalyses the reaction...

{x}}(t)} . The theorem says if the dynamics of the system satisfies microscopic reversibility, then the probability distribution of entropy production in the...

way to achieve catalysis. All chemical processes are reversible (law of microscopic reversibility) although some processes have such an energy bias, they...

Loschmidt criticises Boltzmann's H theorem as being incompatible with microscopic reversibility (Loschmidt's paradox). 1877 – Boltzmann states the relationship...

achieved starting all the way from an atomistic particle-based microscopically reversible Hamiltonian and subsequently generalized from classical mechanics...

due to microreversal. Bema Hapothle Curtin–Hammett principle Microscopic reversibility Bell–Evans–Polanyi principle Fox MA, Whiteshell JK (2004). Organic...

proved the principle of semi-detailed balance for kinetics without microscopic reversibility. In 1953 he and the mathematician André Petermann discovered the...

"Nonequilibrium measurements of free energy differences for microscopically reversible Markovian systems", J. Stat. Phys., 90 (5/6): 1481, Bibcode:1998JSP...

follow the same chemical mechanisms as gluconeogenesis, due to microscopic reversibility, and in this view would have occurred at the same time. Fructose...

positive definite. Statistical mechanics considerations involving microscopic reversibility of dynamics imply that the matrix L {\displaystyle L} is symmetric...

1945 wrote a well-known paper on Lars Onsager's principle of microscopic reversibility. He became a co-director of Philips NatLab in 1946 and a member...

Loschmidt's paradox (named for Josef Loschmidt), also known as the reversibility paradox, irreversibility paradox, or Umkehreinwand (from German 'reversal...

position is occupied by the incoming ligand; due to the principle of microscopic reversibility, the departing ligand must also leave from an equatorial position...

Hammond Postulate, the Curtin-Hammett principle, and the theory of microscopic reversibility are often applied to organic chemistry. Chemists have also used...

metal-hydrogen bond is β-hydride elimination. The Principle of Microscopic Reversibility requires that the mechanism of β-hydride elimination follow the...

thermodynamics. In other words, Laplace's demon was based on the premise of reversibility and classical mechanics; however, Ulanowicz points out that many thermodynamic...