• Oxidative decarboxylation is a decarboxylation reaction caused by oxidation. Most are accompanied by α- Ketoglutarate α- Decarboxylation caused by dehydrogenation...
    12 KB (1,563 words) - 10:53, 6 August 2024
  • uncatalyzed decarboxylation of a picolinic acid gives a stable carbene that attacks a carbonyl electrophile. Oxidative decarboxylations are generally...
    12 KB (1,289 words) - 13:41, 26 May 2025
  • Thumbnail for Cellular respiration
    or 2 × 2.5 ATP (malate-aspartate shuttle) 2 NADH+H+ from the oxidative decarboxylation of pyruvate and 6 from Krebs cycle: 8 × 2.5 ATP 2 FADH2 from the...
    31 KB (3,390 words) - 04:11, 1 June 2025
  • Thumbnail for N-Bromosuccinimide
    by decarboxylation and release of an imine. Further hydrolysis will yield an aldehyde and ammonia. (cf. non-oxidative PLP dependent decarboxylation) NBS...
    14 KB (1,191 words) - 22:03, 26 April 2025
  • Thumbnail for Pentose phosphate pathway
    in the pathway. The first is the oxidative phase, in which NADPH is generated, and the second is the non-oxidative synthesis of five-carbon sugars. For...
    11 KB (1,111 words) - 10:38, 20 May 2025
  • the acid has not been reported. This reaction is different from oxidative decarboxylation, which proceeds through a radical mechanism and is characterised...
    10 KB (883 words) - 04:12, 2 June 2025
  • Thumbnail for Methylene cyclopropyl acetic acid
    α-ketomethylene-cyclopropylpropionic acid (KMCPP), which then forms MCPA through oxidative decarboxylation. Hypoglycin A (and hypoglycin B) is found in the ackee fruit,...
    8 KB (741 words) - 00:55, 17 April 2025
  • Thumbnail for Pyruvate decarboxylation
    Pyruvate decarboxylation or pyruvate oxidation, also known as the link reaction (or oxidative decarboxylation of pyruvate), is the conversion of pyruvate...
    4 KB (338 words) - 21:27, 23 May 2025
  • Nitrile (redirect from Nitrile oxide)
    and carbon dioxide via various means of oxidative decarboxylation. Henry Drysdale Dakin discovered this oxidation in 1916. From aryl carboxylic acids (Letts...
    32 KB (3,681 words) - 01:17, 20 May 2025
  • Thumbnail for Glyoxylate cycle
    two carbon acetate units. The glyoxylate cycle bypasses the two oxidative decarboxylation reactions of the TCA cycle and directly converts isocitrate through...
    19 KB (2,510 words) - 19:27, 25 May 2025
  • Thumbnail for Glutaryl-CoA dehydrogenase
    to the acyl-CoA dehydrogenase family (ACD). It catalyzes the oxidative decarboxylation of glutaryl-CoA to crotonyl-CoA and carbon dioxide in the degradative...
    6 KB (836 words) - 01:17, 7 March 2024
  • mitochondrial inner membrane. This enzyme complex catalyzes the oxidative decarboxylation of branched, short-chain alpha-ketoacids. BCKDC is a member of...
    16 KB (1,781 words) - 18:08, 24 April 2024
  • Thumbnail for Pyruvate decarboxylase
    dehydrogenase, an oxidoreductase (EC 1.2.4.1), that catalyzes the oxidative decarboxylation of pyruvate to acetyl-CoA. Pyruvate decarboxylase occurs as a...
    9 KB (1,155 words) - 11:37, 3 June 2024
  • Thumbnail for 3-Iodophenol
    thiolate and amine nucleophiles. 3-Iodophenol can be prepared by oxidative decarboxylation of 3-iodobenzoic acid: IC6H4CO2H + "O" → IC6H4OH + CO2 Haynes...
    4 KB (208 words) - 16:16, 21 October 2024
  • Thumbnail for Isocitrate dehydrogenase
    (EC 1.1.1.42) and (EC 1.1.1.41) is an enzyme that catalyzes the oxidative decarboxylation of isocitrate, producing alpha-ketoglutarate (α-ketoglutarate)...
    33 KB (3,330 words) - 15:00, 22 April 2025
  • coproporphyrinogen III oxidase is a radical SAM enzyme that catalyzes the oxidative decarboxylation of coproporphyrinogen III to protoporhyrinogen IX, an intermediate...
    55 KB (6,104 words) - 18:20, 23 May 2025
  • Thumbnail for ME2 (gene)
    NAD-dependent malic enzyme, a homotetrameric protein, that catalyzes the oxidative decarboxylation of malate to pyruvate. It had previously been weakly linked to...
    7 KB (871 words) - 03:52, 18 December 2023
  • Thumbnail for Benzyl cyanide
    nitrile synthesis between benzyl chloride and sodium cyanide and by oxidative decarboxylation of phenylalanine. Benzyl cyanides can also be prepared by arylation...
    11 KB (868 words) - 14:50, 29 May 2025
  • Thumbnail for Citric acid cycle
    results in increased oxidative stress within the cell as it is a required cofactor in the production of GSH, and this oxidative stress can result in DNA...
    55 KB (6,095 words) - 01:17, 25 May 2025
  • ammoxidation to give acrylonitrile. The glutamic acid route employs oxidative decarboxylation to 3-cyanopropanoic acid, followed by a decarbonylation-elimination...
    25 KB (2,299 words) - 05:03, 2 June 2025
  • Thumbnail for Benzoic acid
    Benzoic acid is mainly consumed in the production of phenol by oxidative decarboxylation at 300−400 °C: C6H5CO2H + ½ O2 → C6H5OH + CO2 The temperature...
    28 KB (2,424 words) - 21:18, 26 April 2025
  • Thumbnail for Acetyl-CoA
    α-ketoacids by transamination and eventually to isovaleryl-CoA through oxidative decarboxylation by an α-ketoacid dehydrogenase complex. Isovaleryl-CoA undergoes...
    22 KB (2,061 words) - 08:23, 20 May 2025
  • initiating oxidative dearomatization, and oxidative decarboxylation of β-ketolactones. Similar to the β-ketolactone reaction, oxidative ether formation...
    4 KB (429 words) - 23:56, 8 February 2025
  • Thumbnail for Isocitrate/isopropylmalate dehydrogenase family
    important enzyme of carbohydrate metabolism which catalyses the oxidative decarboxylation of isocitrate into alpha-ketoglutarate. IDH is either dependent...
    4 KB (388 words) - 15:47, 28 April 2022
  • the E2 domain from undergoing oxidative damage, which helps spare the Oxoglutarate dehydrogenase complex from oxidative stress. Oxoglutarate dehydrogenase...
    17 KB (1,893 words) - 10:49, 25 May 2025
  • Thumbnail for Carboxylic acid
    additional methylene in the aliphatic chain. Many acids undergo oxidative decarboxylation. Enzymes that catalyze these reactions are known as carboxylases...
    27 KB (2,706 words) - 03:04, 26 May 2025
  • Thumbnail for Petrobactin
    iron-chelated petrobactin complex readily undergoes a photolytic oxidative decarboxylation due to its α-hydroxy carboxylate group, converting iron(III) to...
    11 KB (885 words) - 21:14, 17 March 2025
  • Thumbnail for Mersacidin decarboxylase
    decarboxylase EC 4.1.1.. MrsD is an enzyme that catalyzes the oxidative decarboxylation of the C-terminal cysteine residue of mersacidin to an aminoenethiol...
    1 KB (101 words) - 14:54, 26 August 2023
  • Thumbnail for Isocitrate dehydrogenase 1
    gene on chromosome 2. Isocitrate dehydrogenases catalyze the oxidative decarboxylation of isocitrate to 2-oxoglutarate. These enzymes belong to two distinct...
    36 KB (3,994 words) - 21:12, 29 May 2025
  • Thumbnail for 6-Phosphogluconic acid
    ribulose 5-phosphate by phosphogluconate dehydrogenase, in an oxidative decarboxylation which also produces NADPH. In those microorganisms which host...
    2 KB (96 words) - 07:01, 11 May 2024