The Reformatsky reaction (sometimes transliterated as Reformatskii reaction) is an organic reaction which condenses aldehydes or ketones with α-halo esters...
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Organozinc chemistry (redirect from Frankland-Duppa reaction)
The Reformatsky reaction has been employed in numerous total syntheses such as the synthesis of C(16),C(18)-bis-epi-cytochalasin D: The Reformatsky reaction...
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discovered the Reformatsky reaction, during which a zinc organic compound is the key component. The use of zinc in organic reactions was common at that...
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paper. Chemistry portal Aldol–Tishchenko reaction Baylis–Hillman reaction Ivanov reaction Reformatsky reaction Claisen–Schmidt condensation It is typically...
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Hell–Volhard–Zelinsky halogenation (redirect from Hell-Volhard-Zelinsky reaction)
(1834–1910) and the Russian chemist Nikolay Zelinsky (1861–1953). Reformatsky reaction Allen, C. Freeman; Kalm, Max J. (1958). "2-Methylenedodecanoic Acid"...
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of halo ketones Reed reaction Reformatskii reaction, Reformatsky reaction Reilly–Hickinbottom rearrangement Reimer–Tiemann reaction Reissert indole synthesis...
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Zinc chloride (section Reactions)
of polythiophenes and for the Reformatsky reaction. Zinc chloride is used as a catalyst or reagent in diverse reactions conducted on an industrial scale...
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such as those found in the Grignard reaction, Blaise reaction, Reformatsky reaction, and Barbier reaction or reactions involving organolithium reagents and...
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into a ketone, forming the β-ketoester. Blaise ketone synthesis Reformatsky reaction ^ Edmond E. Blaise; Compt. Rend. 1901, 132, 478. ^ Rinehart, K. L...
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"building block" approach using ethyl bromodifluoroacetate. Then, Reformatsky reaction under standard conditions will yield a 3:1 anti/syn diastereomeric...
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acid (PPA) cyclization leads to 5-fluoro-2-methyl-3-indanone (4). A Reformatsky reaction with zinc amalgam and bromoacetic ester leads to carbinol (5), which...
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a versatile alkylating agent. Its major application involves the Reformatsky reaction, wherein it reacts with zinc to form a zinc enolate. The resulting...
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after the reduction of only one aromatic ring. Morton method: The Reformatsky reaction between Cyclohexyl phenyl ketone (BzCy) [712-50-5] (1) and Ethyl...
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Sergey Reformatsky, discoverer of the Reformatsky reaction in organic chemistry Nikolay Semyonov, physical chemist, author of the chain reaction theory...
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reacts with bromoesters to give organozinc reagents of value for the Reformatsky reaction. Rieke magnesium reacts with aryl halides, some even at −78 °C, to...
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Sergey Reformatsky, discoverer of Reformatsky reaction in organic chemistry Nikolay Semyonov, physical chemist, author of the chain reaction theory,...
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Sergey Reformatsky, discoverer of Reformatsky reaction in organic chemistry Nikolay Semyonov, chemical physicist, author of the chain reaction theory...
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Ethyl bromodifluoroacetate (section Reactions)
similar compounds containing a CF2 units can be generated using the Reformatsky reagent with aldehydes and ketones. This yields 2,2-difluoro-3-hydroxy...
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Reductive dehalogenation of halo ketones (category Organic reduction reactions)
an aldehyde leads to reductive aldol products, analogous to the Reformatsky reaction of haloesters. Zinc dust may be used alone; or as an amalgam, in...
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Organometallic chemistry (redirect from Organometallic reaction)
contain only Li-O bonds and are not organometallic, while zinc enolates (Reformatsky reagents) contain both Zn-O and Zn-C bonds, and are organometallic in...
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; Traxler, M. D. (1957). "The Stereochemistry of the Ivanov and Reformatsky Reactions". Journal of the American Chemical Society. 79 (8): 1920–1923. Bibcode:1957JAChS...
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inhibitor. Pirandamine can be synthesized starting from 1-indanone. The Reformatsky reaction between 1-indanone (1) and ethyl bromoacetate in the presence of...
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Ketonization Reaction of Enols," Zimmerman, H. E. J. Org. Chem., 1955, 20, 549-557. ISSN 0022-3263 "The Stereochemistry of the Ivanov and Reformatsky Reactions. I...
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transformations like the Claisen condensation, the Reformatsky reaction, the Arndt–Eistert reaction, and the Dieckmann condensation. Nicolaou described...
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affecting Barbier allylations and Reformatsky-type reactions. While Mn(0) is capable of reducing Pb(II), these reactions do not proceed solely in the presence...
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Phenylphosphine (section Reactions)
indoles, and secondary and tertiary alcohols by reduction, Grignard, and Reformatsky reagents. Phenylphosphine reacts with many metal complexes to give complexes...
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Bjerrum, Ellen Swallow Richards, Alice Ball, Vladimir Palladin, Sergey Reformatsky, Prafulla Chandra Ray, Alexey Favorsky, Rosalind Franklin and Joseph...
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2-methylpent-4-en-2-ol with chromic acid (H2CrO4); in 1880 and 1889, Schirokoff and Reformatsky (respectively) reported that the oxidative cleavage of the vicinal diol...
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as Nikolay Zelinsky, Sergey Namyotkin (organic chemistry), Alexander Reformatsky (inorganic and analytical chemistry), Sergey Krapivin (physical chemistry)...
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