enol ether is an alkene with an alkoxy substituent. The general structure is R2C=CR-OR where R = H, alkyl or aryl. A common subfamily of enol ethers are...

In organosilicon chemistry, silyl enol ethers are a class of organic compounds that share the common functional group R3Si−O−CR=CR2, composed of an enolate...

electrophiles at oxygen. Silylation gives silyl enol ether. Acylation gives esters such as vinyl acetate. In general, enols are less stable than their keto equivalents...

Ge, Sn, Pb). Such compounds are considered ethers as well. Examples of such ethers are silyl enol ethers R3Si−O−CR=CR2 (containing the Si−O−C linkage)...

Thebaine (paramorphine), also known as codeine methyl enol ether, is an opiate alkaloid, its name coming from the Greek Θῆβαι, Thēbai (Thebes), an ancient...

Ethyl vinyl ether is an organic compound with the chemical formula CH3CH2OCH=CH2. It is the simplest enol ether that is liquid at room temperature. It...

oxidation is a useful, high-yielding chemical reaction between silyl enol ethers and peroxyacids to give the corresponding α-hydroxy carbonyl product...

3-cyclopentyl enol ethers of 17α-hydroxyprogesterone and 17α-hydroxyprogesterone acetate, respectively, while progesterone 3-acetyl enol ether (never marketed)...

Methyl vinyl ether is an organic compound with the chemical formula CH3OCH=CH2. A colorless gas, it is the simplest enol ether. It is used as a synthetic...

addition is an organic reaction and a type of aldol reaction between a silyl enol ether (R2C=CR−O−Si(CH3)3) and an aldehyde (R−CH=O) or formate (R−O−CH=O). The...

Progesterone 3-acetyl enol ether, also known as progesterone acetate, as well as 3-acetoxypregna-3,5-dien-20-one, is a progestin which was never marketed...

occur. One way to get around this is to turn the aldehyde into a silyl enol ether using trimethylsilyl chloride and a base, such as triethylamine, and then...

"Regio- AND Stereoselective Intramolecular Hydrosilylation of a-Hydroxy Enol Ethers: 2,3-syn-2-Methoxymethoxy-1,3-nonanediol". Organic Syntheses. 73: 94...

Silyl triflate is more reactive and also converts ketones to silyl enol ethers. Silyl triflates are water sensitive and must be run under inert atmosphere...

is transformed into an enol ether by the Tebbe reagent (Cp2Ti=CH2), and then the glycosyl acceptor is tethered to the enol ether under acid-catalysed conditions...

antioxidant activity comes from the enol ether double bond being targeted by a variety of reactive oxygen species. Synthetic ether lipid analogs have cytostatic...

intermediate between that of an enol ether and an aromatic ring. It is dissimilar vs ethers such as tetrahydrofuran. Like enol ethers, 2,5-disubstituted furans...

1990). "Triethylborane induced perfluoroalkylation of silyl enol ethers or germyl enol ethers with perfluoroalkyl iodides". Tetrahedron Letters. 31 (44):...

instead of an alkene yields an enol, which tautomerizes into a ketone. Using an alcohol instead of water yields an ether (see also Hofmann-Sand reaction)...

by electron donating groups proceed rapidly and easily. For example, enol ethers like trimethylsilyloxy-substituted olefins are often used because of...

that have at least one alpha-hydrogen, undergo keto-enol tautomerization; the tautomer is an enol. Tautomerization is catalyzed by both acids and bases...

Carbonyl compounds, such as aldehydes and ketones, can be converted to enols or enol ethers. These species, being nucleophilic at the α-carbon, can attack especially...

Rifampicin, also known as rifampin, is an ansamycin antibiotic used to treat several types of bacterial infections, including tuberculosis (TB), Mycobacterium...

Methyltestosterone 3-hexyl ether (brand names Androgénol, Enoltestovis, Enoltestovister), or 17α-methyltestosterone 3-hexyl enol ether, also known as 17α-methylandrost-3...

Vinyl ether may refer to: Any enol ether Divinyl ether, a volatile chemical compound once used as an anestethic This disambiguation page lists articles...

uses other, similar functional groups as ersatz enols. In the Mukaiyama aldol reaction, silyl enol ethers add to carbonyls in the presence of a Lewis acid...

Quingestrone, also known as progesterone 3-cyclopentyl enol ether (PCPE) and sold under the brand name Enol-Luteovis, is a progestin medication which was previously...

compounds. The reaction as originally reported involved formation of a silyl enol ether followed by treatment with palladium(II) acetate and benzoquinone to yield...

Azoxystrobin is a broad spectrum systemic fungicide widely used in agriculture to protect crops from fungal diseases. It was first marketed in 1996 using...

intermediates in the synthesis of heterocycles. Aromatic imines react with an enol ether to a quinoline in the Povarov reaction. Imines react, thermally, with...