• Thumbnail for Matrix isolation
    Matrix isolation is an experimental technique used in chemistry and physics. It generally involves a material being trapped within an unreactive matrix...
    9 KB (1,135 words) - 01:00, 28 October 2023
  • Thumbnail for Cyclobutadiene
    degrades by a bimolecular process, the species can be observed by matrix isolation techniques at temperatures below 35 K. It is thought to adopt a rectangular...
    9 KB (877 words) - 18:19, 2 April 2025
  • Thumbnail for Phosphine oxide
    oxytrichloride as well as with chromyl chloride. The product was obtained by matrix isolation. It has also been reported relatively stable in a water-ethanol solution...
    5 KB (441 words) - 22:52, 3 March 2025
  • terbium, neodymium and dysprosium, the last two known only under matrix isolation conditions. All of the lanthanides form trihalides with fluorine, chlorine...
    109 KB (10,480 words) - 05:13, 5 May 2025
  • Thumbnail for Uranium trioxide
    some work has been done on the molecular form in the gas phase, in matrix isolations studies, and computationally. At elevated temperatures gaseous UO3...
    26 KB (2,442 words) - 09:57, 30 November 2024
  • methylene were also studied around 1960 by infrared spectroscopy using matrix isolation experiments. Many of methylene's electronic states lie relatively close...
    16 KB (1,675 words) - 16:55, 26 March 2025
  • atom. However, compounds of argon have been detected in inert gas matrix isolation, cold gases, and plasmas, and molecular ions containing argon have...
    134 KB (15,925 words) - 04:46, 4 April 2025
  • observation of these reactive molecules are generally accomplished by matrix-isolation methods. The simplest non-Kekulé molecules are biradicals. A biradical...
    17 KB (1,603 words) - 01:13, 14 December 2024
  • Thumbnail for Spin isomers of hydrogen
    their excellent optical qualities. Parahydrogen is used as a host for matrix isolation studies: since hydrogen interacts weakly with other molecules, the...
    28 KB (3,390 words) - 17:58, 11 March 2025
  • Thumbnail for Adenine
    Lapinski; J. S. Kwiatkowski; J. Leszczynski (1994). "Experimental matrix isolation and theoretical ab initio HF/6-31G(d, p) studies of infrared spectra...
    12 KB (1,024 words) - 22:47, 29 April 2025
  • can these compounds be isolated and stored, e.g. low temperatures, matrix isolation. When their existence is indicated, reactive intermediates can help...
    4 KB (420 words) - 09:00, 27 December 2023
  • Thumbnail for Silanone
    are extremely reactive and until 2013 were only detected by argon matrix isolation or in the gas phase but not isolated. A synthesis of a stable silanone...
    5 KB (597 words) - 17:53, 16 November 2024
  • Kulkarni; S.R. Gadre (2002). "H-π Complexes of acetylene-ethylene: A matrix isolation and computational study". J. Phys. Chem. A. 106 (8): 1504. Bibcode:2002JPCA...
    8 KB (968 words) - 13:24, 18 February 2025
  • Thumbnail for Martyn Poliakoff
    (16): 1008. doi:10.1039/C29700001008. Poliakoff, Martyn (1973). The matrix isolation of large molecules. The photochemistry of transition metal carbonyls...
    22 KB (1,863 words) - 00:27, 27 February 2025
  • Thumbnail for Silicone
    N. Khabashesku; Z. A. Kerzina; K. N. Kudin; O. M. Nefedov (1998). "Matrix isolation infrared and density functional theoretical studies of organic silanones...
    44 KB (5,110 words) - 04:06, 3 April 2025
  • Thumbnail for Praseodymium
    generated by oxidation with ozone. Praseodymium(V) has been observed by matrix isolation (in 2016) and in the bulk state (in 2025). The existence of praseodymium...
    38 KB (5,038 words) - 17:38, 4 May 2025
  • science education and public service. He developed the technique of matrix isolation in low-temperature chemistry. He also developed time-resolved infrared...
    10 KB (829 words) - 01:13, 5 March 2025
  • Thumbnail for John D. Baldeschwieler
    Baldeschwieler, John Dickson (1960). Structure of unstable compounds by matrix isolation techniques (Ph.D.). University of California, Berkeley. OCLC 29101714...
    6 KB (372 words) - 01:23, 17 April 2025
  • Thumbnail for Iridium
    Sr2MgIrO6 and Sr2CaIrO6. iridium(VIII) oxide (IrO4) was generated under matrix isolation conditions at 6 K in argon. The highest oxidation state (+9), which...
    81 KB (7,830 words) - 18:54, 14 April 2025
  • Thumbnail for Mercury(IV) fluoride
    2007, when HgF4 was first prepared using solid neon and argon for matrix isolation at a temperature of 4 K. The compound was detected using infrared spectroscopy...
    7 KB (740 words) - 00:44, 19 January 2025
  • Thumbnail for Oxocarbon
    reactive that they exist only in gas phase or have only been detected by matrix isolation. Graphene oxide and other stable polymeric carbon oxides with unbounded...
    34 KB (3,238 words) - 20:46, 20 June 2024
  • Thumbnail for Ansoff matrix
    The Ansoff matrix is a strategic planning tool that provides a framework to help executives, senior managers, and marketers devise strategies for future...
    10 KB (1,106 words) - 04:03, 9 September 2024
  • Thumbnail for Dimethyl sulfite
    A.; Gómez-Zavaglia, A.; Simões, P. N. N. L.; Fausto, R. (2005). "Matrix Isolation FTIR Spectroscopic and Theoretical Study of Dimethyl Sulfite" (PDF)...
    4 KB (323 words) - 00:49, 21 November 2024
  • lifetime, but can be stabilized through special laboratory setups such as matrix-isolation. A prominent example is the carbon dioxide dimer, which is likely to...
    14 KB (1,438 words) - 17:55, 31 January 2025
  • a black solid. Lithium superoxide (LiO2) has only been isolated in matrix isolation at 15 K. Sodium superoxide (NaO2) is a yellow-orange solid that melts...
    5 KB (457 words) - 17:49, 9 February 2024
  • Thumbnail for Mercury (element)
    Bridgeman, A. J.; Young, N. A. (2008). "Mercury-fluorine interactions: a matrix isolation investigation of Hg⋯F2, HgF2 and HgF4 in argon matrices". Phys Chem...
    127 KB (13,395 words) - 03:01, 28 April 2025
  • Thumbnail for Noble gas
    HowStuffWorks. Retrieved 3 July 2008. Dunkin, I. R. (1980). "The matrix isolation technique and its application to organic chemistry". Chem. Soc. Rev...
    95 KB (9,705 words) - 14:32, 30 April 2025
  • Cell isolation is the process of separating individual living cells from a solid block of tissue or cell suspension.  While some types of cell naturally...
    13 KB (1,564 words) - 23:27, 2 September 2023
  • Thumbnail for Indium trihydride
    compound with the chemical formula (InH3). It has been observed in matrix isolation and laser ablation experiments. Gas phase stability has been predicted...
    7 KB (571 words) - 21:29, 10 November 2024
  • thallane species has been isolated. Thallanes have been observed only in matrix isolation studies; the infrared spectrum was obtained in the gas phase by laser...
    3 KB (282 words) - 08:03, 27 July 2024