• Partition equilibrium is a special case of chemical equilibrium wherein one or more solutes are in equilibrium between two immiscible solvents. The most...
    4 KB (451 words) - 03:40, 28 May 2025
  • Thumbnail for Thermal equilibrium
    its own state of internal thermal equilibrium. It could be subjected to a fictive thermodynamic operation of partition into two subsystems separated by...
    17 KB (2,334 words) - 12:33, 30 November 2024
  • starts from an equilibrium state, in which portions of it are held at different states by more or less permeable or impermeable partitions, and a thermodynamic...
    57 KB (7,950 words) - 15:23, 26 May 2025
  • at equilibrium provides a definition of an equilibrium constant. Applications include acid–base, host–guest, metal–complex, solubility, partition, chromatography...
    44 KB (6,468 words) - 04:51, 23 February 2025
  • at the same rate Equilibrium constant, a quantity characterizing a chemical equilibrium in a chemical reaction Partition equilibrium, a type of chromatography...
    11 KB (903 words) - 10:44, 24 March 2025
  • Thumbnail for Partition function (statistical mechanics)
    In physics, a partition function describes the statistical properties of a system in thermodynamic equilibrium.[citation needed] Partition functions are...
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  • i} 's information partition. Then ( ( Ω , π ) , P i , s i ) {\displaystyle ((\Omega ,\pi ),P_{i},s_{i})} is a correlated equilibrium of the strategic game...
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  • Thumbnail for Partitions of Poland
    The Partitions of Poland were three partitions of the Polish–Lithuanian Commonwealth that took place between 1772 and 1795, toward the end of the 18th...
    46 KB (4,951 words) - 20:49, 25 May 2025
  • immiscible solvents at equilibrium. This ratio is therefore a comparison of the solubilities of the solute in these two liquids. The partition coefficient generally...
    57 KB (6,373 words) - 07:40, 20 October 2024
  • Equilibrium partitioning Sediment Benchmarks (ESBs) are a type of Sediment Quality Guideline (SQG) derived by the US Environmental Protection Agency (EPA)...
    12 KB (1,617 words) - 08:51, 15 August 2023
  • silica for capillary columns. Gas chromatography is based on a partition equilibrium of analyte between a solid or viscous liquid stationary phase (often...
    58 KB (7,243 words) - 05:40, 23 May 2025
  • potential defines chemical equilibrium. Other constants for dynamic equilibrium involving phase changes, include partition coefficient and solubility...
    7 KB (1,188 words) - 17:12, 5 June 2025
  • Thumbnail for Quasistatic process
    In thermodynamics, a quasi-static process, also known as a quasi-equilibrium process (from Latin quasi, meaning ‘as if’), is a thermodynamic process that...
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  • primarily concerned with thermodynamic equilibrium, statistical mechanics has been applied in non-equilibrium statistical mechanics to the issues of microscopically...
    43 KB (5,068 words) - 08:53, 3 June 2025
  • Thumbnail for Creosote
    non-polar. Bioaccumulation for un-ionized compounds comes from partitioning equilibrium between the aqueous phase and the lipids in the organism. If the...
    95 KB (10,410 words) - 17:34, 29 May 2025
  • Thumbnail for Molecular diffusion
    still in motion, but an equilibrium has been established, the result of molecular diffusion is called a "dynamic equilibrium". In a phase with uniform...
    16 KB (2,108 words) - 18:11, 21 April 2025
  • assess bioaccumulation and bioconcentration. These include: octanol-water partition coefficients (KOW), bioconcentration factors (BCF), bioaccumulation factors...
    16 KB (1,887 words) - 17:00, 26 November 2024
  • quantitative measure of the strength of an acid in solution. It is the equilibrium constant for a chemical reaction HA ↽ − − ⇀ A − + H + {\displaystyle...
    103 KB (11,534 words) - 07:28, 2 June 2025
  • In thermodynamics and chemical engineering, the vapor–liquid equilibrium (VLE) describes the distribution of a chemical species between the vapor phase...
    22 KB (3,245 words) - 19:11, 29 September 2024
  • Fluctuation theorem (category Non-equilibrium thermodynamics)
    It is then easy to prove the Second Law Inequality and the NonEquilibrium Partition Identity. When combined with the central limit theorem, the FT also...
    25 KB (3,388 words) - 19:44, 9 June 2025
  • finite number of values (m1, m2, . . . , mN). Thus an equilibrium may be characterized by a partition (t0(N), t1(N). . . tN(N)) of the set of types [0, 1]...
    13 KB (1,873 words) - 15:30, 25 May 2025
  • The distribution constant (or partition ratio) (KD) is the equilibrium constant for the distribution of an analyte in two immiscible solvents. In chromatography...
    3 KB (362 words) - 01:12, 13 August 2023
  • Thumbnail for Liquid–liquid extraction
    is important. The partition coefficient is a thermodynamic equilibrium constant and has a fixed value for the solute’s partitioning between the two phases...
    47 KB (5,883 words) - 17:37, 23 May 2025
  • Thumbnail for Zeroth law of thermodynamics
    zeroth law, these subsets consist of systems which are in mutual equilibrium. This partitioning allows any member of the subset to be uniquely "tagged" with...
    20 KB (2,670 words) - 06:09, 12 May 2025
  • The n-octanol-water partition coefficient, Kow is a partition coefficient for the two-phase system consisting of n-octanol and water. Kow is also frequently...
    12 KB (1,466 words) - 01:58, 29 March 2025
  • highly ordered equilibrium state. For instance, imagine dividing a container with a partition and placing a gas on one side of the partition, with a vacuum...
    18 KB (2,621 words) - 19:57, 18 March 2025
  • wikidata descriptions as a fallback Partition coefficient – Ratio of concentrations in a mixture at equilibrium Scientific laws named after people Graham's...
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  • Thumbnail for Boltzmann distribution
    ) The partition function can be calculated if we know the energies of the states accessible to the system of interest. For atoms the partition function...
    20 KB (2,496 words) - 00:43, 18 May 2025
  • Jarzynski equality (category Non-equilibrium thermodynamics)
    Provides a fluctuation theorem between two equilibrium states. Implies Jarzynski equality. Nonequilibrium partition identity Jarzynski, C. (1997), "Nonequilibrium...
    11 KB (1,629 words) - 12:35, 7 November 2023
  • exists a price such that the allocation and the price are a competitive equilibrium (CE) with equal incomes (EI). Thus, it connects two research fields which...
    20 KB (3,428 words) - 15:23, 24 March 2025