chemistry, a reaction intermediate, or intermediate, is a molecular entity arising within the sequence of a stepwise chemical reaction. It is formed...

a reactive intermediate or an intermediate is a short-lived, high-energy, highly reactive molecule. When generated in a chemical reaction, it will quickly...

cationic intermediate loses a proton to give an allylic alcohol (4). With an excess of formaldehyde and a low reaction temperature the reaction product...

than that of the intermediate. Instead, the rate equation may be more accurately described using steady-state kinetics. The reaction involves a carbocation...

A tetrahedral intermediate is a reaction intermediate in which the bond arrangement around an initially double-bonded carbon atom has been transformed...

a reaction intermediate is a reaction product that serves as a precursor for other reactions A reactive intermediate is a highly reactive reaction intermediate...

intermediates (see next section) or other quantitative and qualitative characteristics of the reaction. It also describes each reactive intermediate,...

reaction in which a reaction intermediate (or, for the first step, the reactants) is converted into the next reaction intermediate (or, for the last step...

equilibration of Wittig intermediates and termed the process "stereochemical drift". For many years, the stereochemistry of the Wittig reaction, in terms of carbon-carbon...

reduction-sensitive intermediates may form in the reaction which can affect chemoselectivity. The amine substrate, imine intermediate, or amine product...

Bischler–Napieralski reaction. Mechanism I involves a dichlorophosphoryl imine-ester intermediate, while Mechanism II involves a nitrilium ion intermediate (both shown...

Shapiro reaction or tosylhydrazone decomposition is an organic reaction in which a ketone or aldehyde is converted to an alkene through an intermediate hydrazone...

organopalladium intermediate B. Reaction (metathesis) with base gives intermediate C, which via transmetalation with the boron-ate complex D (produced by reaction of...

a concerted reaction is a chemical reaction in which all bond breaking and bond making occurs in a single step. Reactive intermediates or other unstable...

imine product. Throughout the development of the reaction the group sought to identify reaction intermediates through fundamental mechanistic studies. These...

The Stille reaction is a chemical reaction widely used in organic synthesis. The reaction involves the coupling of two organic groups, one of which is...

intermediate in the synthesis of the antipsychotic drug Fluanxol is synthesized by a cyanation through the Sandmeyer reaction. The Sandmeyer reaction...

an additional covalent intermediate to the reaction, and helps to reduce the energy of later transition states of the reaction. The covalent bond must...

products, and sometimes intermediate products and reaction conditions. Chemical reactions happen at a characteristic reaction rate at a given temperature...

The Simmons–Smith reaction is an organic cheletropic reaction involving an organozinc carbenoid that reacts with an alkene (or alkyne) to form a cyclopropane...

formation of the oxyphosphonium intermediate 8 is slow and facilitated by the alkoxide. Therefore, the overall rate of reaction is controlled by carboxylate...

effect of simplifying a single chemical entity (normal molecule, reaction intermediate, etc.) into two or more fragments. Chemical decomposition is usually...

subsequent reaction occurs only in virtue of the chemical functionality formed in the previous step. In cascade reactions, isolation of intermediates is not...

enzyme-catalysed chemical reactions. In enzyme kinetics, the reaction rate is measured and the effects of varying the conditions of the reaction are investigated...

cycle for respiration, concentrations of TCA intermediates remain constant; however, many biosynthetic reactions also use these molecules as a substrate....

typical reaction above), V is the volume of reaction, and Ci is the concentration of substance i. When side products or reaction intermediates are formed...

aromatic hydrocarbon is important in the petrochemical industry as a reaction intermediate in the production of styrene, the precursor to polystyrene, a common...

concentration of the intermediate is low, the reaction follows the producing pathway, leading then to a relatively high concentration of intermediate. When the concentration...

theoretical studies suggest that the reaction proceeds through the same Criegee intermediate as observed in the chemical reaction. After the rearrangement step...

syn-addition intermediate is displaced by a hydroxyl group and the reaction product contains a dihydrofuran ring. In the amino-Heck reaction a nitrogen...