In chemistry, a transition metal pincer complex is a type of coordination complex with a pincer ligand. Pincer ligands are chelating agents that binds...

Transition metal dinitrogen complexes are coordination compounds that contain transition metals as ion centers the dinitrogen molecules (N2) as ligands...

A metal-phosphine complex is a coordination complex containing one or more phosphine ligands. Almost always, the phosphine is an organophosphine of the...

resulting complex, but the formal oxidation states nonetheless suggest a complex featuring a neutral Ga(I). The reaction of this pincer Ir complex with tetrabutylammonium...

Metal carbon dioxide complexes are coordination complexes that contain carbon dioxide ligands. Aside from the fundamental interest in the coordination...

Metal-ligand cooperativity (MLC) is a mode of reactivity in which a metal and ligand of a complex are both involved in the bond breaking or bond formation...

and other elements. The earliest examples of bismuthinidene complexes used transition metal chemistry to stabilize the Bi(I) center. These methods generally...

2,6–positions. The three nitrogen centres bind metals in a tridentate fashion, forming pincer complexes. Diiminopyridines are notable as non-innocent ligand...

bisphosphine ligands was selectively cleaved by a number of metals to afford stable pincer complexes under mild conditions. Aromatization is another driving...

stabilized by an N,C,N-pincer ligand. The ligand employed was L = 2,6-bis[N-(2',6'-dimethylphenyl)ketimino]phenyl. The synthesis of this complex was achieved by...

binds metals at three meridional sites giving two adjacent 5-membered MN2C2 chelate rings. Terpyridine forms complexes with most transition metal ion as...

allows them to function as ligands in a variety of main group and transition metal complexes.  Carbone-coordinated elements also exhibit a variety of different...

and alkoxide chemistry. Caulton's work with transition metal complexes is ultimately aimed to create complexes that exhibit unexpected and novel reactivities...

borane complexes with the metals, the geometry of the Tm ligands (and sometimes their bidentate versions Bm) are such that with late transition metals such...

Iridium Pincer Complexes". Chemical Reviews. 111 (3): 1761–1779. doi:10.1021/cr1003503. PMID 21391566. "1". Alkane C-H Activation by Single-Site Metal Catalysis...

Nitrogenase: enzymes used by organisms to fix nitrogen Transition metal dinitrogen complex Metal nitrido complex Chalkley, Matthew J.; Drover, Marcus W.; Peters...

that is typically considered to be "unreactive", interacts with a transition metal center M, resulting in its cleavage and the generation of an organometallic...

compared to heterogeneous catalysts. Many organometallic complexes degrade below 100 °C. Some pincer-based catalysts, however, operate near 200 °C. Concurrent...

research by Goldberg on the study of transition metal-catalyzed reactions places additional emphasis on the metal-complex ligands. Recent publications have...

organoplatinum complex with the formula [(CH3)3PtI]4. It is a white, air-stable solid that was one of the first σ-alkyl metal complexes reported. It arises...

hybrid or heteroditopic ligands form complexes where one coordinating group is easily displaced from the metal centre while the other group remains firmly...

replaced by a transition metal complex. The parent metallacyclopentane has the formula LnM(CH2)4. Such compounds are intermediates in the metal catalysed...

A. S. (2011). "Autocatalytic O2 Cleavage by an OCO3− Trianionic Pincer CrIII Complex: Isolation and Characterization of the Autocatalytic Intermediate...

cross-coupling systems may exist. Poyatos et al. immobilized a Pd pincer carbene complex (Figure 3) on MK-10 clay and observed that while high TON (ca. 103)...

hydride (i.e., lacking a metal-carbon bond). With an interest in cyclometallation, he discovered one of the first pincer complexes via the orthometalation...

that contain carbon directly bonded to metals or metalloids. The importance of main-group and transition-metal centers has long been recognized as important...

elements, transition metals and actinides to even alkali metals and lanthanides. A periodic table of elements gives some idea of the complexes which have...

character resulting from homolysis of a bismuth(III) dichloride complex with N,C,N-pincer ligand (Scheme 4). This Bi(III) compound was reacted with two...

unusual reactivity. The pincer based germylene is of great importance not only for their ability to stabilize transition metal species via chelation effects...

new catalyst designs. Their structure can be summarized as a transition metal carbene complex in which the central atom is iron, and one of the ligands is...