reagent, catalyst or environment. Asymmetric induction is a key element in asymmetric synthesis. Asymmetric induction was introduced by Hermann Emil Fischer...

through interactions at the transition state. This biasing is known as asymmetric induction and can involve chiral features in the substrate, reagent, catalyst...

effect, change in electron density Asymmetric induction, preferring one stereoisomer over another Grammar induction Inductive bias Inductive probability...

"Preparation of an Optically Active Prostaglandin Intermediate via Asymmetric Induction". J. Am. Chem. Soc. 97 (23): 6908–6909. Bibcode:1975JAChS..97.6908C...

carbonyl groups. The catalysts were found to afford high levels of asymmetric induction in several processes, including the ene reaction of ethyl glyoxylate...

Sharpless asymmetric dihydroxylation (also called the Sharpless bishydroxylation) is the chemical reaction of an alkene with osmium tetroxide in the presence...

Asymmetric hydrogenation is a chemical reaction that adds two atoms of hydrogen to a target (substrate) molecule with three-dimensional spatial selectivity...

used in Sharpless asymmetric dihydroxylation While the presence of any symmetry element within a ligand intended for asymmetric induction might appear counterintuitive...

Asymmetric induction in allylic alkylations." J. Am. Chem. Soc. 1973, 95, 8200–8201. doi:10.1021/ja00805a056. Trost, B. M.; Strege, P. E. "Asymmetric...

chiral auxiliaries and chiral catalysts, and the application of asymmetric induction. The use of enzymes (biocatalysis) may also produce the desired compound...

in particular Rh2[(S)-DOSP]4 and Rh2[(S)-BPTV]4 can induce modest asymmetric induction and was used to synthesize the antifungal agent pseudolaric acid...

structure. He also did work in stereochemistry and Cram's rule of asymmetric induction is named after him. In 1973, Cram collaborated on research with Irish...

transfer of an H2 molecule from the reductant to the substrate. Asymmetric induction in transition metal catalyzed reactions is achieved through the use...

predictable stereodirecting effects resulting in high levels of asymmetric induction. Racemization of the newly created carbon-nitrogen stereo center...

= OR*). (1) Asymmetric versions of the above reaction have taken advantage of a number of strategies for achieving asymmetric induction. The highest...

et al. (1981). "Asymmetric total synthesis of erythromcin. 1. Synthesis of an erythronolide A secoacid derivative via asymmetric induction". J. Am. Chem...

H. (1981). "Asymmetric total synthesis of erythromcin. 1. Synthesis of an erythronolide a secoacid derivative via asymmetric induction". Journal of the...

2010. Other chiral additives can be used as the initial source of asymmetric induction, with the major product of that first reaction being rapidly amplified...

chiral chemical synthesis, and specifically of the phenomenon of asymmetric induction during nucleophilic attack at hindered carbonyl centers (see the...

also be influenced through conformational control and often exhibit asymmetric induction. Disadvantages: Because the reaction is reversible and thermodynamically...

employing chiral starting materials have been used to effect either asymmetric induction or simple diastereoselection (1) After carbanion formation, the [2...

one enantiomer or diastereomer over the other is formally known as asymmetric induction. In this kind of Lewis acid, the electron-accepting atom is typically...

bulky tosyl group on the imine electrophile is responsible for the asymmetric induction taking place. In another application DOM is applied in placing a...

"Studies in Stereochemistry. X. The Rule of "Steric Control of Asymmetric Induction" in the Syntheses of Acyclic Systems". Journal of the American Chemical...

the imine, which generally results in a trans product. Reviews on asymmetric induction of the Staudinger synthesis, including the use of organic and organometallic...

insertions are seen. Both inter- and intra-molecular insertions admit asymmetric induction from a chiral metal catalyst. Carbenes can form adducts with nucleophiles...

deprotonation to occur. In an intramolecular Diels-Alder reaction, asymmetric induction can be induced through allylic 1,3 strain on the diene or the dienophile...

(June 1981). "Asymmetric Total Synthesis of Erythromycin. 1. Synthesis of an Erythronolide A Seco Acid Derivative via Asymmetric Induction". Journal of...

rearrangement Coupling reaction Crabbé reaction Craig method Cram's rule of asymmetric induction Creighton process Criegee reaction Criegee rearrangement Cross metathesis...

Etter, Jeffrey B. (1987). "Lanthanides in organic synthesis. 8. 1.3-Asymmetric induction in intramolecular Reformatskii-type reactions promoted by samarium...