The Corey–Itsuno reduction, also known as the Corey–Bakshi–Shibata (CBS) reduction, is a chemical reaction in which a prochiral ketone is enantioselectively...

been named after him: Corey-Itsuno reduction, also known as the Corey-Bakshi-Shibata reduction, is an enantioselective reduction of ketones to alcohols...

catecholborane with a small amount of one enantiomer of CBS catalyst (a Corey–Itsuno reduction). The choice of chirality of the catalyst thus gives selectivity...

aprepitant. CBS catalyst Corey-Itsuno reduction Hirao, A.; Itsuno, S.; Nakahama, S.; Yamazaki, N. (1981). "Asymmetric reduction of aromatic ketones with...

oxidation Reduction Birch reduction Bouveault-Blanc reduction CBS reduction Clemmensen reduction Corey-Bakshi-Shibata reduction Corey–Itsuno reduction Fukuyama...

portal Corey-Itsuno reduction Asymmetric hydrogenation R-Alpine-Borane and S-Alpine-Borane at Sigma-Aldrich M. M. Midland (1989). "Asymmetric reductions with...

dimethylsulfide is one of the most common bulk reducing agents used in the Corey–Itsuno reduction. The dimethylsulfide ligand attenuates the reactivity of the borane...

chemistry Reactions of organoborates and boranes Corey–Itsuno reduction Midland Alpine borane reduction Petasis reaction Suzuki reaction Boryl radicals...

Another method, first developed in the 1980s, is called the Corey–Bakshi–Shibata reduction (CBS), and it features the use of an oxazaborolidine catalyst...

a ketone reducing agent by the laboratory of Itsuno, and thus is more properly called the Itsuno-Corey oxazaborolidine. Proline derivative 3d is prepared...

auxiliaries and catalysts, including the Enders hydrazone reaction and Corey–Itsuno reduction, have been reviewed, as have MacMillan’s iminium catalysts, Miller...

An early example of such is the Corey–Itsuno reduction. One proposed mechanism for this enantioselective reduction involves the in situ generation of...

is one such strategy. In the followingexample, enantioselective Corey-Itsuno reduction sets up a diastereoselective ligand substitution reaction. After...