+ (pz–px–q) H2O Hydrolysis constants (log values) in critical compilations at infinite dilution and T = 298.15 K: Hydrolysis constants (log values) in...
123 KB (5,143 words) - 15:46, 26 May 2025
molecules by hydrolysis (e.g., sucrose being broken down into glucose and fructose), this is recognized as saccharification. Hydrolysis reactions can...
18 KB (2,227 words) - 23:15, 22 March 2025
radius, r, increases. Aqua ions are subject to hydrolysis. The logarithm of the first hydrolysis constant is proportional to z2/r for most aqua ions. The...
71 KB (7,653 words) - 21:25, 1 May 2024
Baes, C. F.; Mesmer, R. E. (1976). "Chapter 18. Survey of Hydrolysis Behaviour". The Hydrolysis of Cations. Wiley. pp. 397–430. Schwarzenbach, G.; Flaschka...
42 KB (6,736 words) - 13:46, 8 March 2025
stability constant explicitly, as illustrated above. The formation of a hydroxo complex is a typical example of a hydrolysis reaction. A hydrolysis reaction...
60 KB (7,556 words) - 10:18, 14 May 2025
addition, the metal ion is subject to hydrolysis, that is, it behaves as a weak acid, so the pK values for the hydrolysis reactions must also be known. Assessing...
103 KB (11,534 words) - 07:28, 2 June 2025
implications for all protonation equilibria in aqueous solution and for hydrolysis constants in particular. It is quite usual to omit from the model those species...
47 KB (7,173 words) - 08:20, 1 June 2025
phosphate, the hydrolysis of ATP has the effect of lowering the pH of the reaction medium. Under certain conditions, high levels of ATP hydrolysis can contribute...
10 KB (1,228 words) - 08:44, 9 February 2025
and 845 nm were observed for the mononuclear and dinuclear hydrolysis species. Hydrolysis of plutonyl is important for an understanding of pollution of...
7 KB (911 words) - 19:58, 27 May 2025
Hammett equation (section Substituent constants)
(+0.417) the hydrolysis of substituted benzyl chlorides in acetone-water at 69.8 °C (−1.875). The reaction constant, or sensitivity constant, ρ, describes...
34 KB (4,056 words) - 16:23, 22 April 2025
extent of hydrolysis can be quantified when the values of the hydrolysis constants can be determined experimentally. The first hydrolysis constant refers...
41 KB (2,770 words) - 15:47, 19 January 2025
hypochlorous acid: RR′NCl + H2O ⇌ RR′NH + HOCl The quantitative hydrolysis constant (K value) is used to express the bactericidal power of chloramines...
21 KB (2,109 words) - 01:04, 21 February 2025
(NIOSH). Rai, Dhanpat; Sass, Bruce M.; Moore, Dean A. "Chromium(III) hydrolysis constants and solubility of chromium(III) hydroxide" Inorganic Chemistry 1987...
3 KB (212 words) - 20:42, 2 May 2025
Rate equation (redirect from Second order rate constant)
bimolecular reaction and a simultaneous hydrolysis (which can be treated as pseudo order one) takes place: the hydrolysis complicates the study of the reaction...
44 KB (7,579 words) - 06:10, 25 May 2025
oxygen by hemoglobin in blood Acid–base equilibria: acid dissociation constant, hydrolysis, buffer solutions, indicators, acid–base homeostasis Metal–ligand...
44 KB (6,725 words) - 10:14, 16 May 2025
Lactone (section Hydrolysis and aminolysis)
because although the enthalpies of the hydrolysis of esters and lactones are about the same, the entropy of the hydrolysis of lactones is less than the entropy...
17 KB (1,824 words) - 06:26, 5 May 2025
Ester (section Hydrolysis and saponification)
Alton; Andrews, Roy C. (1928). "The Relation Between the Hydrolysis Equilibrium Constant of Esters and the Strengths of the Corresponding Acids". Journal...
45 KB (4,636 words) - 19:04, 2 June 2025
Ethyl acetate (redirect from Acid hydrolysis of ethyl acetate)
acetate is rarely selected as a reaction solvent because it is prone to hydrolysis, transesterification, and condensations. Ethyl acetate is the most common...
22 KB (1,974 words) - 20:47, 29 May 2025
Solubility equilibrium (redirect from Solubility constant)
"Nobel lecture" (PDF). Nobel Prize. Baes, C. F.; Mesmer, R. E. (1976). The Hydrolysis of Cations. New York: Wiley. Payghan, Santosh (2008). "Potential Of Solubility...
29 KB (4,103 words) - 20:14, 13 February 2025
Michaelis–Menten kinetics (redirect from Michaelis-Menten constant)
investigated the kinetics of invertase, an enzyme that catalyzes the hydrolysis of sucrose into glucose and fructose. In 1913 they proposed a mathematical...
47 KB (6,248 words) - 13:53, 26 May 2025
total amount of ATP + ADP remains fairly constant. The energy used by human cells in an adult requires the hydrolysis of 100 to 150 mol/L of ATP daily, which...
52 KB (5,657 words) - 03:17, 19 May 2025
Nitrile (section Hydrolysis)
second-order rate constant for hydroxide-ion catalyzed hydrolysis of acetonitrile to acetamide is 1.6×10−6 M−1 s−1, which is slower than the hydrolysis of the amide...
32 KB (3,681 words) - 01:17, 20 May 2025
Taft equation (section Polar substituent constants, σ*)
hydrolysis of methyl esters (RCOOMe). The use of ester hydrolysis rates to study polar effects was first suggested by Ingold in 1930. The hydrolysis of...
15 KB (1,888 words) - 23:51, 22 May 2025
from hydrolysis and oxidation. AlP crystals are dark grey to dark yellow in color and have a zincblende crystal structure with a lattice constant of 5...
12 KB (1,014 words) - 03:33, 11 March 2025
the same polymer.”; a simple reversible polymer can’t treadmill; ATP hydrolysis is required. GTP is hydrolyzed for microtubule treadmilling. The cytoskeleton...
12 KB (1,476 words) - 21:34, 5 December 2024
Reuleaux triangle (category Constant width)
Reuleaux triangle [ʁœlo] is a curved triangle with constant width, the simplest and best known curve of constant width other than the circle. It is formed from...
57 KB (6,500 words) - 06:52, 2 June 2025
3, Hydrolases: catalyze the hydrolysis of various bonds EC 4, Lyases: cleave various bonds by means other than hydrolysis and oxidation EC 5, Isomerases:...
99 KB (10,086 words) - 19:06, 23 May 2025
PET bottle recycling (section Hydrolysis)
MEG and PTA or DMT. The main processes are glycolysis, methanolysis or hydrolysis. After purification, the oligomers or monomers can be used to prepare...
54 KB (6,429 words) - 17:46, 4 May 2025
Solubility (redirect from Salt hydrolysis)
numerical value of solubility constant. While the solubility constant is not as simple as solubility, the value of this constant is generally independent of...
50 KB (6,544 words) - 16:44, 17 March 2025
intermediate in esterification, transesterification, ester hydrolysis, formation and hydrolysis of amides and peptides, hydride reductions, and other chemical...
18 KB (2,329 words) - 20:47, 22 July 2024