The Michaelis–Arbuzov reaction (also called the Arbuzov reaction) is the chemical reaction of a trivalent phosphorus ester with an alkyl halide to form...
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Phosphonate (section Michaelis-Arbuzov reaction)
palladium-catalyzed coupling reaction with an aryl halide to form a phosphonate. Phosphonic esters are prepared using the Michaelis–Arbuzov reaction. For example, methyl...
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alkyl (thio)phosphonate. Yields of this reaction are often lower than the corresponding Michaelis–Arbuzov reaction. Savignac, Philippe; Iorga, Bogdan (2003)...
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bipyramidal molecular geometry in apolar solution. The Michaelis–Arbuzov reaction is the chemical reaction of a trivalent phosphorus ester with an alkyl halide...
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dialkyl vinyl phosphate and an alkyl halide.[1] In the related Michaelis–Arbuzov reaction the same reactants are known to form a beta-keto phosphonate which...
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Nucleophilic substitution (redirect from Nucleophilic substitution reaction)
the Michaelis–Arbuzov reaction. The Kolbe nitrile synthesis, the reaction of alkyl halides with cyanides. An example of a substitution reaction taking...
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August Michaelis (26 December 1847 – 31 January 1916) was a German chemist and discovered the Michaelis–Arbuzov reaction. Michaelis studied at the University...
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Hirao coupling (redirect from Hirao reaction)
This builds on previous work by August Michaelis and Alexandr Arbuzov, who developed the Michaelis-Arbuzov reaction to deliver alkyl phosphonates from alkyl...
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Distillation is generally sufficient to isolate pure products. Michaelis–Arbuzov reaction - the reaction of a trialkyl phosphite and an alkyl halide to form a...
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(disambiguation) Michaelis–Arbuzov reaction, a chemical reaction St. Michaelis, Hamburg This page lists people with the surname Michaelis. If an internal...
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oxaphosphetane intermediates. Wittig reaction Michaelis–Arbuzov reaction Michaelis–Becker reaction Peterson reaction Tebbe olefination Wadsworth, W. Org...
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alkylation Angeli–Rimini reaction Andrussov oxidation Appel reaction Arbuzov reaction, Arbusow reaction Arens–Van Dorp synthesis, Isler modification Aromatic...
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acid can be prepared from triethylphosphite by first using a Michaelis-Arbuzov reaction to generate the phosphorus(V) centre: CH3Cl + P(OC2H5)3 → CH3PO(OC2H5)2...
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Triethyl phosphite (section Reactions)
can react with electrophiles in a Michaelis–Arbuzov reaction to produce organophosphonates. For example, the reaction between triethyl phosphite and ethyl...
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Russian and Soviet chemist who discovered the Michaelis–Arbuzov reaction. A native of Bilyarsk, Arbuzov studied in the Kazan University under Alexander...
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reaction is general, thus a vast number of such species are known. Phosphites are employed in the Perkow reaction and the Michaelis–Arbuzov reaction....
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esters are used in the Perkow reaction for the formation of vinyl phosphonates, and in the Michaelis–Arbuzov reaction to form phosphonates. Aryl phosphite...
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trimethyl phosphite and a halomethane (e.g. iodomethane) via the Michaelis–Arbuzov reaction. Dimethyl methylphosphonate is a schedule 2 chemical as it may...
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the corresponding esters, they do not undergo a variant of the Michaelis-Arbuzov reaction with electrophiles. Instead, they revert to another phosphorus(III)...
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phosphorus atom is retained. Nucleoside phosphoramidites undergo Michaelis-Arbuzov reaction to form the respective phosphonamidates. One example describes...
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Dominique François Jean Arago Michaelis–Arbuzov reaction – Aleksandr Erminingeldovich Arbuzov and August Karl Arnold Michaelis Archimedean spiral, Archimedes...
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bromomethyl intermediate. The synthesis of fostedil concludes with a Michaelis-Arbuzov reaction with triethyl phosphite. Ibrolipim Calcium channel blocker Triggle...
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cationic complex of trimethylphosphite {(C5H5)Co[P(OCH3)3]3}2+ via an Arbuzov reaction. Using other phosphites and other cyclopentadienyl ligands, a large...
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developing with the help of A. W. von Hofmann, Carl Arnold August Michaelis and Aleksandr Arbuzov. It was not until 1932 before the first adverse effects of...
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