• Thumbnail for Michaelis–Arbuzov reaction
    The MichaelisArbuzov reaction (also called the Arbuzov reaction) is the chemical reaction of a trivalent phosphorus ester with an alkyl halide to form...
    13 KB (1,592 words) - 20:48, 27 January 2025
  • Thumbnail for Phosphonium
    bipyramidal molecular geometry in apolar solution. The MichaelisArbuzov reaction is the chemical reaction of a trivalent phosphorus ester with an alkyl halide...
    13 KB (1,237 words) - 19:01, 12 February 2025
  • alkyl (thio)phosphonate. Yields of this reaction are often lower than the corresponding MichaelisArbuzov reaction. Savignac, Philippe; Iorga, Bogdan (2003)...
    1 KB (129 words) - 16:44, 5 November 2024
  • Thumbnail for Phosphonate
    palladium-catalyzed coupling reaction with an aryl halide to form a phosphonate. Phosphonic esters are prepared using the MichaelisArbuzov reaction. For example, methyl...
    23 KB (2,533 words) - 09:10, 11 February 2025
  • Thumbnail for August Michaelis
    August Michaelis (26 December 1847 – 31 January 1916) was a German chemist and discovered the MichaelisArbuzov reaction. Michaelis studied at the University...
    3 KB (138 words) - 22:12, 9 January 2024
  • dialkyl vinyl phosphate and an alkyl halide.[1] In the related MichaelisArbuzov reaction the same reactants are known to form a beta-keto phosphonate which...
    4 KB (437 words) - 23:45, 5 April 2023
  • the MichaelisArbuzov reaction. The Kolbe nitrile synthesis, the reaction of alkyl halides with cyanides. An example of a substitution reaction taking...
    13 KB (1,536 words) - 08:50, 10 May 2025
  • demons Susanne Maria Michaelis, German linguist De Michelis (disambiguation) MichaelisArbuzov reaction, a chemical reaction St. Michaelis, Hamburg This page...
    2 KB (207 words) - 07:22, 4 February 2025
  • oxaphosphetane intermediates. Wittig reaction MichaelisArbuzov reaction Michaelis–Becker reaction Peterson reaction Tebbe olefination Wadsworth, W. Org...
    9 KB (963 words) - 12:22, 16 October 2024
  • Distillation is generally sufficient to isolate pure products. MichaelisArbuzov reaction - the reaction of a trialkyl phosphite and an alkyl halide to form a...
    10 KB (1,098 words) - 04:28, 23 June 2022
  • Thumbnail for Phosphite ester
    esters are used in the Perkow reaction for the formation of vinyl phosphonates, and in the MichaelisArbuzov reaction to form phosphonates. Aryl phosphite...
    9 KB (979 words) - 21:53, 17 June 2024
  • reaction is general, thus a vast number of such species are known. Phosphites are employed in the Perkow reaction and the MichaelisArbuzov reaction....
    19 KB (1,984 words) - 12:31, 10 April 2025
  • This reaction is named after Toshikazu Hirao and is related to the MichaelisArbuzov reaction. In contrast to the classic MichaelisArbuzov reaction, which...
    2 KB (176 words) - 00:14, 14 March 2025
  • Thumbnail for Triethyl phosphite
    can react with electrophiles in a MichaelisArbuzov reaction to produce organophosphonates. For example, the reaction between triethyl phosphite and ethyl...
    5 KB (453 words) - 17:30, 17 December 2024
  • alkylation Angeli–Rimini reaction Andrussov oxidation Appel reaction Arbuzov reaction, Arbusow reaction Arens–Van Dorp synthesis, Isler modification Aromatic...
    37 KB (3,428 words) - 16:27, 11 November 2024
  • Thumbnail for Methylphosphonic acid
    acid can be prepared from triethylphosphite by first using a Michaelis-Arbuzov reaction to generate the phosphorus(V) centre: CH3Cl + P(OC2H5)3 → CH3PO(OC2H5)2...
    3 KB (202 words) - 03:17, 19 January 2024
  • Thumbnail for Aleksandr Arbuzov
    Russian and Soviet chemist who discovered the MichaelisArbuzov reaction. A native of Bilyarsk, Arbuzov studied in the Kazan University under Alexander...
    4 KB (235 words) - 07:35, 24 January 2025
  • Thumbnail for Dimethyl methylphosphonate
    trimethyl phosphite and a halomethane (e.g. iodomethane) via the MichaelisArbuzov reaction. Dimethyl methylphosphonate is a schedule 2 chemical as it may...
    5 KB (359 words) - 12:52, 6 April 2025
  • Thumbnail for Phosphorus
    the corresponding esters, they do not undergo a variant of the Michaelis-Arbuzov reaction with electrophiles. Instead, they revert to another phosphorus(III)...
    88 KB (10,109 words) - 12:11, 25 April 2025
  • Thumbnail for Nucleoside phosphoramidite
    phosphorus atom is retained. Nucleoside phosphoramidites undergo Michaelis-Arbuzov reaction to form the respective phosphonamidates. One example describes...
    25 KB (2,992 words) - 09:28, 23 April 2025
  • Dominique François Jean Arago MichaelisArbuzov reaction – Aleksandr Erminingeldovich Arbuzov and August Karl Arnold Michaelis Archimedean spiral, Archimedes...
    72 KB (6,840 words) - 15:42, 10 April 2025
  • Thumbnail for Kläui ligand
    cationic complex of trimethylphosphite {(C5H5)Co[P(OCH3)3]3}2+ via an Arbuzov reaction. Using other phosphites and other cyclopentadienyl ligands, a large...
    3 KB (266 words) - 18:55, 3 November 2024
  • Thumbnail for Fostedil
    bromomethyl intermediate. The synthesis of fostedil concludes with a Michaelis-Arbuzov reaction with triethyl phosphite. Ibrolipim Calcium channel blocker Triggle...
    4 KB (353 words) - 16:53, 15 August 2023
  • Thumbnail for Tetraethyl pyrophosphate
    developing with the help of A. W. von Hofmann, Carl Arnold August Michaelis and Aleksandr Arbuzov. It was not until 1932 before the first adverse effects of...
    14 KB (1,535 words) - 19:49, 27 January 2025