the oxymercuration reaction is an electrophilic addition reaction that transforms an alkene (R2C=CR2) into a neutral alcohol. In oxymercuration, the...

alternative to other hydration reactions such as acid-catalyzed addition and the oxymercuration–reduction process. The reaction was first reported by Herbert...

general oxymercuration reactions of alkenes and alkynes using mercuric compounds proceed via organomercury intermediates. A related reaction forming phenols...

oxidation Oxidation Oxidative addition Oxygenation Oxymercuration reaction Pauson–Khand reaction Photodissociation Pseudorotation Protonation Protonolysis...

producing alcohols, including the hydroboration–oxidation reaction, the oxymercuration–reduction reaction, the Mukaiyama hydration, the reduction of ketones...

product. The reaction shown below involves an alkyne oxymercuration reaction to generate the requisite ketone. Research involving the reaction was relatively...

Ostromyslenskii reaction, Ostromisslenskii reaction Overman rearrangement Oxidative decarboxylation Oxo synthesis Oxy-Cope rearrangement Oxymercuration Oxidation...

Hg(OAc)2 → (RS)2C=O + HgS + 2 HOAc Mercury(II) acetate is used for oxymercuration reactions. A famous use of Hg(OAc)2 was in the synthesis of idoxuridine....

Hydrogenations: H2 Oxymercuration reactions: mercuric acetate, water Hydroboration-oxidation reactions: diborane the Prins reaction: formaldehyde, water...

(protonated organomercury compounds; formed as intermediates in oxymercuration reactions) diphenylcarbenium, (C6H5)2CH+ (di-substituted methenium) triphenylcarbenium...

characterize the different reactions of organic chemistry by reflecting the stereochemistry of the products in a reaction. The type of addition that occurs...

compounds, are commonly used as catalysts in oxymercuration-demercuration, a type of electrophilic addition reaction that results in hydration of an unsaturated...

methods are known, including the Horner–Wadsworth–Emmons reaction. The Wittig reaction involves reaction of an aldehyde or ketone with a Wittig reagent (or...

solvent, yields of 73 % are obtained. Hydration reaction Oxymercuration-reduction Hydroboration-oxidation reaction Isayama, Shigeru; Mukaiyama, Teruaki (1 June...

Alkenes can also react with thallium(III) salts in a fashion analogous to oxymercuration to yield monoalkyl organothallium compounds. Phenylthallium dihalides...

acid in a 37% yield. In this reaction gold(III) was used as a homogeneous catalyst replacing mercury in oxymercuration. This same study lists a published...

be reduced to a hydroxymethyl group using lithium aluminum hydride. Oxymercuration with mercury(II) acetate, followed by treatment with potassium hydroxide/...

addition reactions of alkenes, such as hydroboration, oxymercuration, bromination, the Wacker process, and the Wilkinson's catalyst reaction. In 2011...

construct diastereoselective cyclobutene and a regiocontrolled oxymercuration reaction was proposed. This route achieved in synthesizing highly pure (+)-lineatin...

alkene reduction and hydration is shown: The hydroboration-oxidation and oxymercuration-reduction of alkenes are more reliable in organic synthesis. Alkenes...

K.; Fujita, K.; Itoh, O. (1964). "Relations between Denigés Reaction and Oxymercuration". Bulletin of the Institute for Chemical Research, Kyoto University...

Marjorie C. (1970-07-01). "Stereochemistry of addition reactions of allenes. II. Oxymercuration of 1,3-dimethylallene and solvolysis of the derived adducts"...