Selectfluor, a trademark of Air Products and Chemicals, is a reagent in chemistry that is used as a fluorine donor. This compound is a derivative of the...

N-fluoro-o-benzenedisulfonimide (NFOBS), N-fluorobenzenesulfonimide (NFSI), and Selectfluor. The mechanism of electrophilic fluorination remains controversial. At...

reactions of aldehydes and unsaturated ketones and aldehydes. The reagent Selectfluor is derived by alkylation of DABCO with dichloromethane following by treatment...

7F. 1-Fluoronaphthalene can be obtained by reacting naphthalene with Selectfluor. 1-Fluoronaphthalene is a colorless, combustible liquid, which is insoluble...

fluorination is possible with F2/N2 (10%), XeF2, or N-F reagents like Selectfluor, these methods are seldom used, due to the formation of isomeric mixtures...

over several hours to give the quaternized product (see the article on Selectfluor). Due to steric hindrance and unfavorable electronic properties, chloroform...

chiral counteranion. In the example below, the fluorinating reagent Selectfluor exhibits extremely limited solubility in nonpolar solvents and is therefore...

cation ([C5H5NF]+) and the triflate anion. Related reagents include Selectfluor, which is also an N-fluorinated salt. N-Fluoropyridinium cations are...

Fe(C 5H 5)+ 2, and other cationic metallocenes. [Ni(CH3CH2OH)6](BF4)2. Selectfluor, a fluorination agent, and other N–F electrophilic fluorine sources....

salts, useful as fluorine transfer reagents in organic synthesis (e.g., Selectfluor), from the corresponding tertiary amine: [R–+N(CH2CH2)3N:][BF− 4] + XeF2...

arylsilanes, and act as an atomic fluorine source to furnish aryl fluorides. Selectfluor and N-fluorobenzenesulfonimide (NFSI) are traditionally used as electrophilic...

supports a concerted SEAr-type pathway. Aryl germanes are stable against selectfluor. The electrophilic fluorination will selectively place at the –Bu3Sn...