Oxidative decarboxylation is a decarboxylation reaction caused by oxidation. Most are accompanied by α- Ketoglutarate α- Decarboxylation caused by dehydrogenation...
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uncatalyzed decarboxylation of a picolinic acid gives a stable carbene that attacks a carbonyl electrophile. Oxidative decarboxylations are generally...
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Cellular respiration (redirect from Oxidative metabolism)
or 2 × 2.5 ATP (malate-aspartate shuttle) 2 NADH+H+ from the oxidative decarboxylation of pyruvate and 6 from Krebs cycle: 8 × 2.5 ATP 2 FADH2 from the...
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by decarboxylation and release of an imine. Further hydrolysis will yield an aldehyde and ammonia. (cf. non-oxidative PLP dependent decarboxylation) NBS...
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the acid has not been reported. This reaction is different from oxidative decarboxylation, which proceeds through a radical mechanism and is characterised...
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Pentose phosphate pathway (redirect from Phosphogluconate oxidative pathway)
in the pathway. The first is the oxidative phase, in which NADPH is generated, and the second is the non-oxidative synthesis of five-carbon sugars. For...
11 KB (1,111 words) - 10:38, 20 May 2025
Pyruvate decarboxylation or pyruvate oxidation, also known as the link reaction (or oxidative decarboxylation of pyruvate), is the conversion of pyruvate...
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α-ketomethylene-cyclopropylpropionic acid (KMCPP), which then forms MCPA through oxidative decarboxylation. Hypoglycin A (and hypoglycin B) is found in the ackee fruit,...
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Nitrile (redirect from Nitrile oxide)
and carbon dioxide via various means of oxidative decarboxylation. Henry Drysdale Dakin discovered this oxidation in 1916. From aryl carboxylic acids (Letts...
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two carbon acetate units. The glyoxylate cycle bypasses the two oxidative decarboxylation reactions of the TCA cycle and directly converts isocitrate through...
19 KB (2,510 words) - 19:27, 25 May 2025
mitochondrial inner membrane. This enzyme complex catalyzes the oxidative decarboxylation of branched, short-chain alpha-ketoacids. BCKDC is a member of...
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dehydrogenase, an oxidoreductase (EC 1.2.4.1), that catalyzes the oxidative decarboxylation of pyruvate to acetyl-CoA. Pyruvate decarboxylase occurs as a...
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to the acyl-CoA dehydrogenase family (ACD). It catalyzes the oxidative decarboxylation of glutaryl-CoA to crotonyl-CoA and carbon dioxide in the degradative...
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thiolate and amine nucleophiles. 3-Iodophenol can be prepared by oxidative decarboxylation of 3-iodobenzoic acid: IC6H4CO2H + "O" → IC6H4OH + CO2 Haynes...
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(EC 1.1.1.42) and (EC 1.1.1.41) is an enzyme that catalyzes the oxidative decarboxylation of isocitrate, producing alpha-ketoglutarate (α-ketoglutarate)...
33 KB (3,330 words) - 15:00, 22 April 2025
coproporphyrinogen III oxidase is a radical SAM enzyme that catalyzes the oxidative decarboxylation of coproporphyrinogen III to protoporhyrinogen IX, an intermediate...
55 KB (6,104 words) - 18:20, 23 May 2025
NAD-dependent malic enzyme, a homotetrameric protein, that catalyzes the oxidative decarboxylation of malate to pyruvate. It had previously been weakly linked to...
7 KB (871 words) - 03:52, 18 December 2023
nitrile synthesis between benzyl chloride and sodium cyanide and by oxidative decarboxylation of phenylalanine. Benzyl cyanides can also be prepared by arylation...
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important enzyme of carbohydrate metabolism which catalyses the oxidative decarboxylation of isocitrate into alpha-ketoglutarate. IDH is either dependent...
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initiating oxidative dearomatization, and oxidative decarboxylation of β-ketolactones. Similar to the β-ketolactone reaction, oxidative ether formation...
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Benzoic acid (section Oxidation of benzyl compounds)
Benzoic acid is mainly consumed in the production of phenol by oxidative decarboxylation at 300−400 °C: C6H5CO2H + ½ O2 → C6H5OH + CO2 The temperature...
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results in increased oxidative stress within the cell as it is a required cofactor in the production of GSH, and this oxidative stress can result in DNA...
55 KB (6,095 words) - 01:17, 25 May 2025
α-ketoacids by transamination and eventually to isovaleryl-CoA through oxidative decarboxylation by an α-ketoacid dehydrogenase complex. Isovaleryl-CoA undergoes...
22 KB (2,061 words) - 08:23, 20 May 2025
additional methylene in the aliphatic chain. Many acids undergo oxidative decarboxylation. Enzymes that catalyze these reactions are known as carboxylases...
27 KB (2,706 words) - 03:04, 26 May 2025
ammoxidation to give acrylonitrile. The glutamic acid route employs oxidative decarboxylation to 3-cyanopropanoic acid, followed by a decarbonylation-elimination...
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Electrosynthesis (section Anodic oxidations)
form nitriles and carbon dioxide via oxidative decarboxylation at AgO anodes (the latter is formed in-situ by oxidation of Ag2O):[verification needed] Cyanoacetic...
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the E2 domain from undergoing oxidative damage, which helps spare the Oxoglutarate dehydrogenase complex from oxidative stress. Oxoglutarate dehydrogenase...
17 KB (1,893 words) - 10:49, 25 May 2025
ribulose 5-phosphate by phosphogluconate dehydrogenase, in an oxidative decarboxylation which also produces NADPH. In those microorganisms which host...
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further course of the metabolism, it can be completely degraded via oxidative decarboxylation, the citric acid cycle (synonym Krebs cycle) and the respiratory...
124 KB (13,033 words) - 20:59, 29 May 2025
gene on chromosome 2. Isocitrate dehydrogenases catalyze the oxidative decarboxylation of isocitrate to 2-oxoglutarate. These enzymes belong to two distinct...
36 KB (3,994 words) - 21:12, 29 May 2025