Silyl ethers are a group of chemical compounds which contain a silicon atom covalently bonded to an alkoxy group. The general structure is R1R2R3Si−O−R4...

In organosilicon chemistry, silyl enol ethers are a class of organic compounds that share the common functional group R3Si−O−CR=CR2, composed of an enolate...

namely silyl ethers and silyl amines, are resilient toward basic conditions. Protection is typically done by reacting the functional group with a silyl halide...

extremely unstable. Silyl ethers have the connectivity Si-O-C. They are typically prepared by the reaction of alcohols with silyl chlorides: (CH 3) 3SiCl...

alkali. The alkoxysilanes (silyl ethers) of the type R3Si(OR') are slow to hydrolyze. Compared to the silyl ethers, silyl acetates are faster to hydrolyze...

addition to retaining all the known features that are associated with silyl ethers, such as their ease and selectivity of formation, their adaptability...

direction, these silyl migrations produce silyl ethers as products which is driven by the stability of the oxygen-silicon bond. The silyl substituents can...

Ge, Sn, Pb). Such compounds are considered ethers as well. Examples of such ethers are silyl enol ethers R3Si−O−CR=CR2 (containing the Si−O−C linkage)...

(3-Aminopropyl)triethoxysilane (APTES) is an aminosilane frequently used in the process of silanization, the functionalization of surfaces with alkoxysilane...

Rubottom oxidation is a useful, high-yielding chemical reaction between silyl enol ethers and peroxyacids to give the corresponding α-hydroxy carbonyl product...

a solid elastomer. Curing entails crosslinking by the hydrolysis of silyl ethers: 2 RSi(OCH3)2R' + H2O → [RSi(OCH3)R']2O + 2 CH3OH In a hydrolysis reaction...

tert-butyldimethylsilyl ethers: (Me3C)Me2SiCl + ROH → (Me3C)Me2SiOR + HCl These silyl ethers hydrolyze much more slowly than the trimethylsilyl ethers. It also can...

Vinyltriethoxysilane is an organosilicon compound with the formula (C2H5O)3SiCH=CH2. It is a colorless liquid. The compound is bifunctional, featuring...

not isolated but trapped in situ with trimethylsilyl chloride to the silyl ether 9. In the next step, Gilman reagent 8 is a methylating reagent in nucleophilic...

chloride is converted with the trimethyl silyl ether of the alcohol component and production of trimethyl silyl chloride is obtained Aliphatic polyesters...

the most industrially-important silicon α‑effect instead occurs with silyl ethers. Under hydrolysis condition, certain α-silane-terminated prepolymers...

alkyl and vinyl silanes; aldehydes and ketones give silyl ethers, while esters provide alkyl silyl mixed acetals. Hydrosilylation has been called the "most...

bonds, triethoxysilane exhibits relatively low reactivity. Like most silyl ethers, triethoxysilane is susceptible to hydrolysis. As reducing agent, triethoxysilane...

was converted to the silyl ether via asymmetric allylboration and silylation of the resulting alcohol. Ozonolysis of the silyl ether and Lindgren–Pinnick...

preferred due to its lower cost. TMSI reacts with alkyl ethers (ROR′), forming silyl ethers (ROSiMe3) and iodoalkanes (RI) that can be hydrolyzed to...

Methyltrimethoxysilane is an organosilicon compound with the formula CH3Si(OCH3)3. It is a colorless, free-flowing liquid. It is a crosslinker in the preparation...

unsaturases to give the vinyl ethers called plasmalogens: HOCH2CH(OH)CH2OC18H37 + [O] → HOCH2CH(OH)CH2OCH=CHC16H35 + H2O Silyl enol ether Jonathan Clayden; Greeves...

2 HCl + O[Si(CH3)3]2 It also results from the hydrolysis of silyl ethers and other silyl-protected functional groups. HMDSO can be converted back to the...

hydrosilylation in the presence of hydrosilanes and fluoride. The resulting silyl ethers can be hydrolyzed with 1 M hydrochloric acid. Optimal yields of the hydrosilylation...

-magnesium halide methylmagnesium chloride Alkylaluminium Al2R6 -aluminium trimethylaluminium Silyl ether R3SiOR -silyl ether trimethylsilyl triflate...

used in organic synthesis as a reducing agent and as a precursor to silyl ethers. As one of the simplest trialkylsilanes that is a liquid at room temperature...

protecting the acidic site of the reactant by turning it into an ether or a silyl ether to eliminate the labile proton from the solution prior to the Grignard...

addition is an organic reaction and a type of aldol reaction between a silyl enol ether (R2C=CR−O−Si(CH3)3) and an aldehyde (R−CH=O) or formate (R−O−CH=O)...

in this aza Diels-Alder reaction: In the cycloaddition product, the silyl ether is a synthon for a carbonyl group through the enol. The methoxy group...

to give a separable mixture of the starting lactone and the silyl ether. The silyl ether on hydrogenolysis followed by Collins oxidation gave the aldehyde...