Transition metal dinitrogen complexes are coordination compounds that contain transition metals as ion centers the dinitrogen molecules (N2) as ligands...

Metal nitrido complexes are coordination compounds and metal clusters that contain an atom of nitrogen bound only to transition metals. These compounds...

In chemistry, a transition metal ether complex is a coordination complex consisting of a transition metal bonded to one or more ether ligand. The inventory...

A transition metal nitrate complex is a coordination compound containing one or more nitrate ligands. Such complexes are common starting reagents for the...

Pentaamine(dinitrogen)ruthenium(II), the first metal dinitrogen complex. Hexamminecobalt(III) chloride, the trichloride salt of the hexammine complex [Co(NH3)6]3+...

Nitrogenase: enzymes used by organisms to fix nitrogen Transition metal dinitrogen complex Metal nitrido complex Chalkley, Matthew J.; Drover, Marcus W.; Peters...

laboratory setting. Dinitrogen tetroxide can also be produced by heating metal nitrates. The oxidation of copper by nitric acid is a complex reaction forming...

Light on Dinitrogen Cleavage: Structural Features, Redox Chemistry, and Photochemistry of the Key Intermediate Bridging Dinitrogen Complex". Journal...

accomplished than side-on (η2) donation. Today, dinitrogen complexes are known for almost all the transition metals, accounting for several hundred compounds...

While the first dinitrogen complex was discovered in 1965, reports of dinitrogen complexes of main group elements have been significantly limited relative...

silylated. Transition metal dinitrogen complex Nitrogen fixation Hidai, Masanobu.; Mizobe, Yasushi. (1995). "Recent Advances in the Chemistry of Dinitrogen Complexes"...

−196 °C. Dinitrogen is mostly unreactive at room temperature, but it will nevertheless react with lithium metal and some transition metal complexes. This...

the only stable alkali metal nitride. Nitrogen is an unreactive gas because breaking the strong triple bond in the dinitrogen molecule (N2) requires a...

salt, and molybdenum and iron dinitrogen complexes. The electrons are partially transferred from a d-orbital of the metal to anti-bonding molecular orbitals...

necessary, without the inevitable oxidation (breaking down) of everything. Transition metal ions, due to their multiple oxidation states, were the only elements...

Council. Using the transition metal dinitrogen complex W(N2)2(dppe)2, his group first demonstrated the conversion of a dinitrogen ligand into ammonia...

Retrieved 21 September 2014. Crabtree, Robert Howard (1973). Transition Metal Dinitrogen Complexes Adduct Formation and Base Character (PhD thesis). University...

the Greenhouse Gas Dinitrogen Monoxide by Nitrous Oxide Reductase". In Peter M.H. Kroneck; Martha E. Sosa Torres (eds.). The Metal-Driven Biogeochemistry...

5, hydrated 18-crown-6 ether alkali metal ions, hydrated alkali metal ions, transition metal acetylene complexes, protonated ethylene, and IrO4+. Argon...

concerned with the activation of main group and transition metal compounds; in the case of transition metal complexes, As4 has demonstrated competent reactivity...

square-pyramidal bis(nitrogen) complex Fe(II)(DIP)(N2)2. This complex is a precursor to other derivatives by exchange of the dinitrogen ligands, e.g. with H2 and...

within these complexes is controversial with some arguing the bonding resembles a model similar to bonding in transition metal carbonyl complexes which abide...

number of transition-metal species have been found to bind (and even functionalize) N2. The prevalence of transition metals in dinitrogen activation...

nitric acid and dinitrogen pentoxide mixture yields the hexanitratoaluminate complex. In water is it converted to the hexaaqua complex with six water molecules...

borylene complex [(OC)5WBN(SiMe3)2] was reported by Holger Braunschweig et al. in 1998. In this compound a borylene is coordinated to a transition metal. Borylenes...

activation including carbon dioxide complexes and dinitrogen complexes. He prepared several transition metal mesityl complexes such as tetramesityldiiron and...

by Cornella et al. The earliest examples of bismuthinidene complexes used transition metal chemistry to stabilize the Bi(I) center. These methods generally...

treating a mixture of caesium chloride and caesium tetracloroaluminate with dinitrogen tetroxide and methyl nitrate, and pumping off the NOCl gas produced. If...

tetrafluoroborate is 1.083(3) Å, which is almost identical to that for dinitrogen molecule (N≡N). The linear free energy constants σm and σp indicate that...

intensely blue dinitrogen trioxide: •NO + •NO2 ⇌ ON−NO2 Nitric oxide rarely sees organic chemistry use. Most reactions with it produce complex mixtures of...