Wilkinson's catalyst (chlorido­tris(triphenylphosphene)­rhodium(I)) is a coordination complex of rhodium with the formula [RhCl(PPh3)3], where 'Ph' denotes...

the complexes of transition metals. Wilkinson is well known for his popularisation of the use of Wilkinson's catalyst RhCl(PPh3)3 in catalytic hydrogenation...

carvone using a homogeneous catalyst (Wilkinson's catalyst). Partial hydrogenation of phenylacetylene using the Lindlar catalyst. Hydrogenation of an imine...

Prominent examples of metal phosphine complexes include Wilkinson's catalyst (Rh(PPh3)3Cl), Grubbs' catalyst, and tetrakis(triphenylphosphine)palladium(0). Many...

homogeneous catalysis is catalysis where the catalyst is in same phase as reactants, principally by a soluble catalyst a in solution. In contrast, heterogeneous...

this transformation, hence the induction period. For example, with Wilkinson's catalyst, one triphenylphosphine ligand must dissociate to give the coordinatively...

Crabtree’s catalyst is effective for the hydrogenations of mono-, di-, tri-, and tetra-substituted substrates. Whereas Wilkinson’s catalyst and the Schrock–Osborn...

Some so-called catalysts are really precatalysts. Precatalysts convert to catalysts in the reaction. For example, Wilkinson's catalyst RhCl(PPh3)3 loses...

best-known rhodium-halogen compound is the Wilkinson's catalyst chlorotris(triphenylphosphine)rhodium(I). This catalyst is used in the hydroformylation or hydrogenation...

Wilkinson Wilkinson Creek (disambiguation) Wilkinson v. United States, a law case heard by the US Supreme Court Wilkinson's catalyst, a chemical catalyst Wilkinson's...

name recognizes Jirō Tsuji, whose team first reported the use of Wilkinson's catalyst (RhCl(PPh3)3) for these reactions: RC(O)X + RhCl(PPh3)3 → RX + RhCl(CO)(PPh3)2...

that catalyze hydrogenation are often effective catalysts for hydrosilylation, e.g. Wilkinson's catalyst. "Hydrosilylation A Comprehensive Review on Recent...

and other purposed aspects of a hydrogen economy. Hydride complexes are catalysts and catalytic intermediates in a variety of homogeneous and heterogeneous...

to degradation by various chemicals as well as ozone. Typically, Wilkinson's catalyst is used to promote the hydrogenation. The nitrile groups are unaffected...

{aldehydes}{RCH2CH2CHO}}}}} Wilkinson's catalyst is used as a homogeneous catalyst for the hydrogenation of olefins. The mechanism...

carboplatin. Many homogeneous catalysts are square planar in their resting state, such as Wilkinson's catalyst and Crabtree's catalyst. Other examples include...

examples of homogeneous catalysis. In 1975, Kono and Ito reported that Wilkinson's catalyst (Rh(PPh3)3Cl) can undergo oxidative addition with catecholborane...

Well's salt (CsAuCl3) White catalyst ((PhS(O)CH2CH2S(O)Ph).Pd(OAc)2) Wij's Solution (ICl / acetic acid) Wilkinson's catalyst (RhCl(PPh3)3) Wolffram's Red...

products are easily separated from the catalyst. Dehydrogenative coupling of primary silanes using Wilkinson's catalyst is slow and dependent on the removal...

Tris(o-tolyl)phosphine Decyl(triphenyl)phosphonium Vaska's complex Wilkinson's catalyst Bis(triphenylphosphine)nickel(II) dichloride Bis(triphenylphosphine)palladium(II)...

achiral triphenylphosphine ligands in Wilkinson's catalyst with chiral phosphine ligands. This experimental catalyst was employed in an asymmetric hydrogenation...

work on the iridium analogue of Wilkinson's catalyst which he began at University College with Milner. Wilkinson's catalyst can be prepared by reducing rhodium(III)...

31P-NMR spectrum of Wilkinson's catalyst (RhCl(PPh3)3) in toluene solution. In addition to 31P–31P coupling between the two types of phosphine centers...

reaction required tin tetrachloride and a stoichiometric amount of Wilkinson's catalyst: An equal amount of a cyclopropane was formed as the result of decarbonylation...

rhodium(I) derivatives. A famous derivative is [RhCl(PPh3)3] known as Wilkinson's catalyst. Either the ethanol solvent or the phosphine serves as reductant:...

catalyze the cyclooligomerization of allene. Using a suitable catalyst (e.g. Wilkinson's catalyst), it is possible to reduce just one of the double bonds of...

increases the turnover rate of the catalyst. Unlike other Rh(I) catalysts, the rhodium analogue of Wilkinson's catalyst RhCl(PHCy2)3 (Cy=cyclohexyl) behaves...

hydrogenation catalysts by replacing the achiral triphenylphosphine ligands in Wilkinson's catalyst with chiral phosphine ligands. This experimental catalyst was...

example with chalcone, a reaction catalysed by diethyl zinc and Wilkinson's catalyst: Trifluoromethyl sulfone (PhSO2CF3) and trifluoromethyl sulfoxide...

acyl hydrides. An example of this is the Tsuji–Wilkinson decarbonylation reaction using Wilkinson's catalyst. (Strictly speaking, the noncatalytic version...