Hydroboration–oxidation reaction is a two-step hydration reaction that converts an alkene into an alcohol. The process results in the syn addition of...
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is stereospecific, this oxidation reaction will be diastereoselective when the alkene is trisubstituted. Hydroboration-oxidation is thus an excellent way...
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for producing alcohols, including the hydroboration–oxidation reaction, the oxymercuration–reduction reaction, the Mukaiyama hydration, the reduction...
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between atoms. A reaction may be classified as redox in which oxidation and reduction occur or non-redox in which there is no oxidation and reduction occurring...
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In organic chemistry, the Swern oxidation, named after Daniel Swern, is a chemical reaction whereby a primary or secondary alcohol (−OH) is oxidized to...
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oxymercuration–reaction can give R–CH=CH–CH2–O–CH=CH2, which is suitable for a Claisen rearrangement. Hydroboration–oxidation reaction Mukaiyama hydration...
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Disiamylborane (section Reactions)
colorless waxy solid that is used in organic synthesis for hydroboration–oxidation reactions. Like most dialkyl boron hydrides, it has a dimeric structure...
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Electrophilic addition (category Reaction mechanisms)
Hydrogenations: H2 Oxymercuration reactions: mercuric acetate, water Hydroboration-oxidation reactions: diborane the Prins reaction: formaldehyde, water March...
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Organoboron chemistry (redirect from Reactions of organoborates and boranes)
hydroboration-oxidation reaction pair oxidizes the borane to an alcohol with hydrogen peroxide or to a carbonyl group with chromium oxide. Oxidation of...
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Allylic strain (section Hydroboration reaction)
induction in the hydroboration oxidation reaction. The reaction is regioselective and stereoselective. The regioselectivity of the reaction is due to the...
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Boron (section Reactions of the element)
boron Boron deficiency Boron oxide Boron nitride Boron neutron capture therapy Boronic acid Hydroboration-oxidation reaction Suzuki coupling The earth's...
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Hydrogen peroxide (section Oxidation reactions)
for the oxidation of alkylboranes to alcohols, the second step of hydroboration-oxidation. It is also the principal reagent in the Dakin oxidation process...
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oxidized to form an alcohol. This two-step reaction is now called hydroboration-oxidation and is a reaction that converts alkenes into anti-Markovnikov...
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Germanium(II) hydrides (section Hydroboration)
transition metal catalyzed hydroborations using HBpin. Reaction of the β-diketiminato germylene hydride with nitrous oxide produces a germylene hydroxide...
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In chemistry, metal-catalysed hydroboration is a reaction used in organic synthesis. It is one of several examples of homogeneous catalysis. In 1975,...
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catalyst and a base. The organoboron species is usually synthesized by hydroboration or carboboration, allowing for rapid generation of molecular complexity...
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oxidation Boyer Reaction Bredt's rule Brook rearrangement Brown hydroboration Bucherer carbazole synthesis Bucherer reaction Bucherer–Bergs reaction Buchner...
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coupling Nicholas reaction Nitrosylation Noyori asymmetric hydrogenation Olefin polymerization Oppenauer oxidation Oxidation Oxidative addition Oxygenation...
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oxygen to form the corresponding chiral alcohol (cf. hydroboration–oxidation reaction). The reaction can also be applied to dienes, where the least sterically...
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Tetrahydrofuran (redirect from Tetramethylene oxide)
complexes with Li+, Mg2+, and boranes. It is a popular solvent for hydroboration reactions and for organometallic compounds such as organolithium and Grignard...
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Wilkinson's catalyst (section Reactions)
other hydrofunctionalization reactions including hydroacylation, hydroboration, and hydrosilylation of alkenes. Hydroborations have been studied with catecholborane...
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Diisopinocampheylborane (section Hydroboration)
with B-H-B bridges. Diisopinocampheylborane was originally prepared by hydroboration of excess α-pinene with borane, but it is now more commonly generated...
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Alkyne (section Cycloadditions and oxidation)
hydrides. The hydroboration of alkynes gives vinylic boranes which oxidize to the corresponding aldehyde or ketone. In the thiol-yne reaction the substrate...
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Syn and anti addition (category Addition reactions)
characterize the different reactions of organic chemistry by reflecting the stereochemistry of the products in a reaction. The type of addition that occurs...
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organoborane compound. This colourless solid is used in organic chemistry as a hydroboration reagent. The compound exists as a hydride-bridged dimer, which easily...
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Sodium borohydride (section Oxidation)
listing. Oxidation with iodine in tetrahydrofuran gives borane–tetrahydrofuran, which can reduce carboxylic acids to alcohols. Partial oxidation of borohydride...
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Hydroxymethylation (category Carbon-carbon bond forming reactions)
hydroxymethylation of aldehydes involves methylenation followed by hydroboration-oxidation: RCHO + Ph3P=CH2 → RCH=CH2 + Ph3PO RCH=CH2 + R2BH → RCH2-CH2BR2...
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quantum yield of 14% and 22%, respectively. Catalytic systems for hydroboration reactions based on magnesium complexes have been investigated, with the pioneering...
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Oxalyl chloride (section Oxidation of alcohols)
Collected Volumes, vol. 9, p. 692. Leopold, E. J. (1990). "Selective hydroboration of a 1,3,7-triene: Homogeraniol". Organic Syntheses; Collected Volumes...
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