Lithium aluminium hydride, commonly abbreviated to LAH, is an inorganic compound with the chemical formula Li[AlH4] or LiAlH4. It is a white solid, discovered...

Lithium hydride is an inorganic compound with the formula LiH. This alkali metal hydride is a colorless solid, although commercial samples are grey. Characteristic...

generated in THF from lithium aluminium hydride. The reaction with lithium hydride in ether produces lithium aluminium hydride: AlH3 + LiH → Li[AlH4]...

metal hydrides react with metal halides. Lithium aluminium hydride (often abbreviated as LAH) arises from reactions of lithium hydride with aluminium chloride...

reagent, SMEAH is comparable with lithium aluminium hydride (LAH, LiAlH4). It is a safer alternative to LAH and related hydrides. SMEAH exhibits similar reducing...

suspension in diethyl ether, it reacts with lithium chloride to give the popular reagent lithium aluminium hydride: LiCl + NaAlH4 → LiAlH4 + NaCl The compound...

sodium hydride (NaH), lithium hydride (LiH) or lithium aluminium hydride (LiAlH4): 8 BF3 + 6 LiH → B2H6 + 6 LiBF4 Lithium hydride used for this purpose must...

soluble in ethers, whilst remaining safer to handle than lithium aluminium hydride. Lithium borohydride may be prepared by the metathesis reaction, which...

(nitro group, nitrile, ester). In their handling properties, lithium aluminium hydride and sodium borohydride (and their derivatives) strongly differ...

stronger reducing agent than lithium borohydride and lithium aluminium hydride. LiBHEt3 is prepared by the reaction of lithium hydride (LiH) and triethylborane...

refer to the reduction of a ketone by lithium aluminium hydride, but not to the oxidation of lithium aluminium hydride by a ketone. Many oxidations involve...

accomplish this task include lithium aluminium hydride, sodium borohydride, alkoxy borohydrides, alkoxy aluminium hydrides, and boranes. Although stoichiometric...

synthesized in 1951 by treating dimethylberyllium, Be(CH3)2, with lithium aluminium hydride, LiAlH4. Purer BeH2 forms from the pyrolysis of di-tert-butylberyllium...

Mg(anthracene) + H2 → MgH2 the reaction of diethylmagnesium with lithium aluminium hydride product of complexed MgH2 e.g. MgH2.THF by the reaction of phenylsilane...

nitro compounds with metal hydrides gives good yields of azo compounds. For example, one could use: Lithium aluminium hydride Zinc metal with sodium hydroxide...

agents for the non-catalytic conversion to amines include lithium aluminium hydride, lithium borohydride, diborane, or elemental sodium in alcohol solvents...

Metal hydrides (sodium hydride, lithium aluminium hydride, uranium trihydride) Partially or fully alkylated derivatives of metal and nonmetal hydrides (diethylaluminium...

group with hydrogen by metal alkoxyaluminium hydride reagents. Sodium borohydride and lithium aluminium hydride are commonly used for the reduction of organic...

azetidinones (β-lactams) with lithium aluminium hydride. Even more effective is a mixture of lithium aluminium hydride and aluminium trichloride, a source of...

tri-sec-butylborohydride), a more strongly reducing derivative. Lithium aluminium hydride, a more strongly reducing reagent, capable of reducing esters...

include lithium aluminium hydride (LiAlH4), lithium triethylborohydride, n-butyllithium and tert-butyllithium. Metallic lithium and its complex hydrides, such...

These parts (functional groups) must be protected. For example, lithium aluminium hydride is a highly reactive reagent that usefully reduces esters to alcohols...

important aluminium hydride is lithium aluminium hydride (LiAlH4), which is used as a reducing agent in organic chemistry. It can be produced from lithium hydride...

agents able to effect this reaction include metal hydrides such as lithium aluminium hydride, or lithium borohydride in mixed solvents of tetrahydrofuran...

synthesis include the reaction of polonium tetrachloride (PoCl4) with lithium aluminium hydride (LiAlH4), which only produces elemental polonium, and the reaction...

nucleophilicity of these lithium diorganocopper compounds. Acyl chlorides are reduced by lithium aluminium hydride and diisobutylaluminium hydride to give primary...

a medical qualification awarded in Dublin, Ireland until 1968 Lithium aluminium hydride, an inorganic compound used as a reducing agent 1st SS Panzer...

hydrogenation are practiced in refineries. They can be effected by using lithium aluminium hydride, Clemmenson reduction and other specialized routes. Coal is a...

example occurred in taxol total synthesis (ring C): The hydride is lithium aluminium hydride and the leaving group a phosphonium salt; the allylic shift...

laboratory scale reactions it was made obsolete by the introduction of lithium aluminium hydride. Sodium metal is a one-electron reducing agent. Four equivalents...