A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged...

equilibrium molecular geometry), the resonant frequencies are associated with the normal modes of vibration corresponding to the molecular electronic ground...

states. Molecular spectra can be obtained due to electron spin states (electron paramagnetic resonance), molecular rotations, molecular vibration, and electronic...

diatomic molecule Bertrand's theorem – Physics theorem Mehler kernel Molecular vibration – Periodic motion of the atoms of a molecule The normalization constant...

is molecular vibration, which corresponds to internal motions of the atoms such as bond stretching and bond angle variation. The molecular vibrations are...

measuring molecular vibrations using inelastic electron tunneling as Turin claimed, rather than responding to molecular keys fitting molecular locks, working...

Each normal mode of molecular vibration has a symmetry which forms a basis for one irreducible representation of the molecular symmetry group. For example...

strongly at the lower end of this region. This radiation is absorbed by molecular vibrations, where the different atoms in a molecule vibrate around their equilibrium...

the number of vibrational modes is 3N-5, whereas for a non-linear molecule the number of vibrational modes is 3N-6. Molecular vibrational energy is known...

Rotational–vibrational spectroscopy is a branch of molecular spectroscopy that is concerned with infrared and Raman spectra of molecules in the gas phase...

approximation). Simple harmonic motion can also be used to model molecular vibration. Simple harmonic motion provides a basis for the characterization...

influenced by molecular vibration (see heat capacity). However, vibrational modes simply cause gammas which decrease toward 1, since vibration modes in a...

significant vibrational motions and do not keep a fixed structure. However, in a Coulomb explosion imaging experiment, an instantaneous image of the molecular structure...

mechanism of the vibrational frequencies of odorants could be easily suppressed by quantum effects of nonodorant molecular vibrational modes. Hence multiple...

although X-rays can also be used. The laser light interacts with molecular vibrations, phonons or other excitations in the system, resulting in the energy...

atoms also has vibrational energy, where the individual atoms move with respect to one another. A diatomic molecule has one molecular vibration mode: the two...

molecules are bent and stretched by the field and the molecular dipole moment changes. The molecular vibration frequency is roughly the inverse of the time it...

fundamental vibrational transitions. Cotton, Chapter 10 Molecular Vibrations. Cotton p. 327. Califano, S. (1976). "Chapter 9: Anharmonicity". Vibrational states...

temperature by the infrared radiation. EMR in this range causes molecular vibration and heating effects, which is how these animals detect it. Above...

an intermediate as a compound that has a lifetime greater than a molecular vibration, is formed (directly or indirectly) from the reactants, and reacts...

relaxation velocities of molecular vibrational states. The lasing medium gas has such properties that an energetically lower vibrational state relaxes faster...

quantum number. An assumption underlying these expressions is that the molecular vibration follows simple harmonic motion. In the harmonic approximation the...

between electronic and nuclear vibrational motion. The term "vibronic" originates from the combination of the terms "vibrational" and "electronic", denoting...

of picoseconds. The creation and breaking of chemical bonds and molecular vibration happen in femtoseconds. Observing the motion of electrons happens...

requires a change in molecular geometry, unimolecular rate constants cannot be larger than the frequency of a molecular vibration. Thus, in general, a...

The rule of mutual exclusion in molecular spectroscopy relates the observation of molecular vibrations to molecular symmetry. It states that no normal...

state and bending vibrations will cause a large rovibronic coupling. Afterglow plasma Vibronic coupling Jungen, Ch (2019-01-22). Molecular Applications of...

atomic or molecular level, physical absorption in the infrared portion of the spectrum depends on the frequencies of atomic or molecular vibrations or chemical...

Pauling's notion of shape-based molecular interactions to propose a shape-based theory of odor. This superseded the older vibration theory of olfaction, and...

Watson, James K.G. (1968). "Simplification of the molecular vibration-rotation hamiltonian". Molecular Physics. 15 (5): 479–490. Bibcode:1968MolPh..15....