tert-Butyllithium is a chemical compound with the formula (CH3)3CLi. As an organolithium compound, it has applications in organic synthesis since it is...

nBuLi sec-Butyllithium, abbreviated sec-BuLi or sBuLi, has 2 stereoisomers, but is commonly used as racemate tert-Butyllithium, abbreviated tert-BuLi or...

n-Butyllithium C4H9Li (abbreviated n-BuLi) is an organolithium reagent. It is widely used as a polymerization initiator in the production of elastomers...

"Monomeric organolithium compounds in tetrahydrofuran: tert-butyllithium, sec-butyllithium, supermesityllithium, mesityllithium, and phenyllithium....

octahedron structures. For example, methyllithium, ethyllithium and tert-butyllithium all exist in the tetramer [RLi]4. Methyllithium exists as tetramers...

Golob "Alkylation of pyridine with tert-butyllithium. Convenient syntheses of 2,6-di-tert-butylpyridine and 2,4,6-tri-tert-butylpyridine" J. Org. Chem. 1971...

readily (e.g., gasoline, acetylene, propane, hydrogen gas, diborane, tert-Butyllithium). Includes pyrophoric substances. Flash point below room temperature...

benzaldehyde with n-butyllithium and N-tert-butylbenzenesulfinimidoyl chloride in THF gives 1-phenyl-1-pentanone in good yield. N-tert-Butylbenzenesulfinimidoyl...

directly to tert-butyllithium. Photochemical cheletropic decarbonylation then gave the target. Heating tetra-tert-butyltetrahedrane gives tetra-tert-butylcyclobutadiene...

(81%) by addition of tert-butyllithium to hexamethylacetone. Z. Malarski (1974). "Solid rotator phases in 2,2,4,4-tetramethyl-3-tert-butyl-3-pentanol (t-Bu3COH)"...

aluminium, gallium, indium, zinc, cadmium, etc.) Triethylborane tert-Butyllithium Diethylzinc Triethylaluminium Nonmetal hydrides (arsine, phosphine...

participate in reactions with certain strong nucleophiles however. Tert-butyllithium deprotonates DCM: H2CCl2 + RLi → HCCl2Li + RH Methyllithium reacts...

aluminium hydride (LiAlH4), lithium triethylborohydride, n-butyllithium and tert-butyllithium. Metallic lithium and its complex hydrides, such as lithium...

T. (13 June 2018). "Improved Safety during Transfer of Pyrophoric tert-Butyllithium from Flasks with Protective Seals". Organic Process Research & Development...

hydroxyl group is reacted with a phosphonic acid derivative, using tert-butyllithium as base to ensure selective O-alkylation, with the formation of an...

types of salts, providing that not too much LiOH is present in the n-butyllithium used to make the lithium amide. Titration of lithium amide can be used...

mononuclear dimethylaluminum aminidate complex, which when treated with tert-butyllithium formed an aggregate compound. This compound consisted of two separate...

mixture called Schlosser's base is produced by combining n-butyllithium and potassium tert-butoxide in a one-to-one ratio. The high reactivity of Schlosser's...

plastic syringe she was using to transfer the pyrophoric reagent tert-butyllithium from one sealed container to another came apart, spilling the chemical...

which is insoluble in water. 1-Fluoronaphthalene was used for the tert-butyllithium-mediated synthesis of 6-substituted phenanthridines. It has also been...

n-butyllithium and (S)-tert-butyl tert-butanethiosulfinate to enantiopure an sulfoxide followed by DOM reaction initiated again by n-butyllithium with...

with one equivalent of butyllithium mainly affords dilithioferrocene. Monolithioferrocene can be obtained using tert-butyllithium. Butler, Ian R.; Cullen...

T. (13 June 2018). "Improved Safety during Transfer of Pyrophoric tert-Butyllithium from Flasks with Protective Seals". Organic Process Research & Development...

height of the donor vessel. While handling pyrophoric material (e.g. tert-butyllithium and trimethylaluminum), traces of the compound at the tip of the needle...

1,3-propanedithiol. Sulfide 3 is first silylated by reaction with tert-butyllithium and then trimethylsilyl chloride 4 and then the second acyl proton...

as low as −100 °C. The derivative 1,3,5-tri-tert-butylpentalene was synthesized in 1973. Because of the tert-butyl substituents this compound is thermally...

dianion was first synthesized by reacting triquinacene with n-butyllithium and potassium tert-amylate (also called potassium t-pentoxide) in hexane solution...

Buffer solution Bunsen burner Burette Burmite Butane N-Butyllithium Tert-Butyllithium Sec-Butyllithium Bytownite Cadmium Calamine Calcite Calcium Calcium...

chemistry. Common silyl ethers are: trimethylsilyl (TMS), tert-butyldiphenylsilyl (TBDPS), tert-butyldimethylsilyl (TBS/TBDMS) and triisopropylsilyl (TIPS)...

auxiliaries Acylation of the oxazolidinone is achieved by deprotonation with n-butyllithium and quench with an acyl chloride. Acylation of a chiral oxazolidinone...