A cyclopentadienyl complex is a coordination complex of a metal and cyclopentadienyl groups (C 5H− 5, abbreviated as Cp−). Cyclopentadienyl ligands almost...
8 KB (856 words) - 23:44, 26 May 2025
Ferrocene (redirect from Iron cyclopentadienyl)
compound with the formula Fe(C5H5)2. The molecule is a complex consisting of two cyclopentadienyl rings sandwiching a central iron atom. It is an orange...
55 KB (5,401 words) - 05:37, 27 May 2025
η5cyclopentadienyl anion (Cp), thus indenyl analogues of many cyclopentadienyl complexes are known. Indenyl ligands lack the 5-fold symmetry of Cp, so...
12 KB (1,349 words) - 17:46, 30 September 2023
air-stable red liquid. It has been reported to be the simplest mono-cyclopentadienyl metal complex. It is prepared by treating nickelocene with nitric oxide. Its...
5 KB (316 words) - 08:58, 11 July 2024
related complex is tris(acetonitrile)cyclopentadienylruthenium hexafluorophosphate, which has three labile MeCN ligands. Chloro(cyclopentadienyl...
5 KB (343 words) - 18:54, 9 June 2024
Nickelocene (redirect from Bis(cyclopentadienyl)nickel(II))
organonickel compound with the formula Ni(η5-C5H5)2. Also known as bis(cyclopentadienyl)nickel or NiCp2, this bright green paramagnetic solid is of enduring...
8 KB (650 words) - 03:53, 12 December 2024
Sodium cyclopentadienide (redirect from Cyclopentadienyl radical)
Johannes Thiele. In 1901 there was not much interest in the topic. Sodium cyclopentadienyl is prepared by treating cyclopentadiene with sodium: 2 Na + 2 C5H6...
8 KB (797 words) - 19:12, 28 April 2025
structure of dicarbonyl-η5-cyclopentadienyl-(η2-tetramethylallenyl)iron tetrafluoroborate. A sterically crowded allene complex". Journal of the Chemical...
26 KB (2,548 words) - 10:37, 25 May 2025
A metallocene is a compound typically consisting of two cyclopentadienyl anions (C 5H− 5, abbreviated Cp) bound to a metal center (M) in the oxidation...
22 KB (2,174 words) - 00:45, 15 January 2025
popularly used as a precursor to the cyclopentadienyl anion (Cp−), an important ligand in cyclopentadienyl complexes in organometallic chemistry. Cyclopentadiene...
13 KB (1,043 words) - 05:40, 13 August 2024
Cyclopentadienyliron dicarbonyl iodide (category Cyclopentadienyl complexes)
and iodide centre. The compound adopts a piano stool structure: the cyclopentadienyl ligand is the "seat" and three other ligands are "legs". Such compounds...
4 KB (283 words) - 09:35, 7 December 2023
Methylcyclopentadienyl manganese tricarbonyl (redirect from Cyclopentadienyl manganese thiocarbonate)
thermal runaway. MMT is a so-called half-sandwich complex, or more specifically a "piano-stool" complex (since the three CO ligands are like the legs of...
19 KB (2,079 words) - 22:26, 15 February 2025
Cyclopentadienylcobalt dicarbonyl (redirect from Cyclopentadienyl cobalt carbonyl)
an example of a half-sandwich complex. It is a dark red air sensitive liquid. This compound features one cyclopentadienyl ring that is bound in an η5-manner...
6 KB (484 words) - 11:30, 23 November 2024
"WCl4(DME): a facile entry into bis(cyclopentadienyl) complexes of tungsten(IV). Synthesis of bis(cyclopentadienyl)tungsten dihydride". Organometallics...
60 KB (6,130 words) - 11:46, 22 May 2025
chemistry Cross-polarization Cyclopentadienyl complex (Cp), read as "C P", the cyclic C5H5 fragment in a coordination complex The similar symbol Cp* ("C...
7 KB (920 words) - 15:28, 26 May 2025
Vanadocene (category Cyclopentadienyl complexes)
Vanadocene, bis(η5-cyclopentadienyl) vanadium, is the organometallic compound with the formula V(C5H5)2, commonly abbreviated Cp2V. It is a violet crystalline...
5 KB (467 words) - 05:36, 16 May 2025
Cobaltocene (redirect from Bis(cyclopentadienyl)cobalt(II))
Cobaltocene, known also as bis(cyclopentadienyl)cobalt(II) or even "bis Cp cobalt", is an organocobalt compound with the formula Co(C5H5)2. It is a dark...
8 KB (620 words) - 19:45, 11 April 2025
Titanocene dichloride (redirect from Dichloridobis(η5-cyclopentadienyl)titanium)
effected with TiCl4 or by reaction with SOCl2. The sandwich complex (Cycloheptatrienyl)(cyclopentadienyl)titanium is prepared by treatment of titanocene dichloride...
21 KB (1,771 words) - 20:25, 6 August 2024
diethyl ether to form the trigonal planar gallium cyclopentadienyl complex GaCp3. Gallium(I) forms complexes with arene ligands such as hexamethylbenzene....
75 KB (8,936 words) - 12:49, 26 May 2025
Chromocene (redirect from Bis(cyclopentadienyl)chromium(II))
in non-polar organic solvents. It is more formally known as bis(η5-cyclopentadienyl)chromium(II). Ernst Otto Fischer, who shared the 1973 Nobel Prize in...
8 KB (653 words) - 04:39, 28 May 2025
Zirconocene dichloride (category Cyclopentadienyl complexes)
organozirconium compound composed of a zirconium central atom, with two cyclopentadienyl and two chloro ligands. It is a colourless diamagnetic solid that is...
11 KB (986 words) - 17:38, 23 May 2025
Intermetallic (section Complexes)
to describe compounds involving two or more metals such as the cyclopentadienyl complex Cp6Ni2Zn4. A B2 intermetallic compound has equal numbers of atoms...
11 KB (1,130 words) - 14:07, 19 March 2025
In the area of organometallic chemistry, a bulky cyclopentadienyl ligand is jargon for a ligand of the type C 5H 5−nR− n where R is a branched alkyl and...
4 KB (328 words) - 19:01, 27 September 2020
Being polymeric, complex is insoluble in nonpolar solvents. It dissolves in the presence of basic ligands to give adducts. (Cyclopentadienyl)titanium trichloride...
2 KB (171 words) - 15:50, 26 December 2023
Organonickel chemistry (redirect from Organonickel complex)
quickly applied in the Mond process for nickel purification. Organonickel complexes are prominent in numerous industrial processes including carbonylations...
12 KB (1,287 words) - 19:07, 21 April 2025
Manganocene (category Cyclopentadienyl complexes)
Manganocene or bis(cyclopentadienyl)manganese(II) is an organomanganese compound with the formula [Mn(C5H5)2]n. It is a thermochromic solid that degrades...
3 KB (238 words) - 00:22, 19 February 2025
Rhodocene (redirect from Bis(cyclopentadienyl)rhodium(II))
between two planar aromatic systems of five carbon atoms known as cyclopentadienyl rings in a sandwich arrangement. It is an organometallic compound as...
76 KB (7,140 words) - 21:38, 26 May 2025
Ferrocenecarboxylic acid (category Cyclopentadienyl complexes)
Ferrocenecarboxylic acid is the organoiron compound with the formula (C5H5)Fe(C5H4CO2H). It is the simplest carboxylic acid derivative of ferrocene. It...
3 KB (236 words) - 15:31, 2 November 2024
Magnesocene (category Cyclopentadienyl complexes)
Magnesocene, also known as bis(cyclopentadienyl)magnesium(II) and sometimes abbreviated as MgCp2, is an organometallic compound with the formula Mg(η5-C5H5)2...
15 KB (1,573 words) - 16:01, 4 May 2025
Bis(cyclopentadienyl)titanium(III) chloride, also known as the Nugent–RajanBabu reagent, is the organotitanium compound which exists as a dimer with the...
25 KB (2,319 words) - 00:35, 22 November 2024