• Thumbnail for Cyclopentadienyl complex
    A cyclopentadienyl complex is a coordination complex of a metal and cyclopentadienyl groups (C 5H− 5, abbreviated as Cp−). Cyclopentadienyl ligands almost...
    8 KB (856 words) - 23:44, 26 May 2025
  • compound with the formula Fe(C5H5)2. The molecule is a complex consisting of two cyclopentadienyl rings sandwiching a central iron atom. It is an orange...
    55 KB (5,401 words) - 05:37, 27 May 2025
  • η5cyclopentadienyl anion (Cp), thus indenyl analogues of many cyclopentadienyl complexes are known. Indenyl ligands lack the 5-fold symmetry of Cp, so...
    12 KB (1,349 words) - 17:46, 30 September 2023
  • air-stable red liquid. It has been reported to be the simplest mono-cyclopentadienyl metal complex. It is prepared by treating nickelocene with nitric oxide. Its...
    5 KB (316 words) - 08:58, 11 July 2024
  • Thumbnail for Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium
    related complex is tris(acetonitrile)cyclopentadienylruthenium hexafluorophosphate, which has three labile MeCN ligands. Chloro(cyclopentadienyl...
    5 KB (343 words) - 18:54, 9 June 2024
  • Thumbnail for Nickelocene
    organonickel compound with the formula Ni(η5-C5H5)2. Also known as bis(cyclopentadienyl)nickel or NiCp2, this bright green paramagnetic solid is of enduring...
    8 KB (650 words) - 03:53, 12 December 2024
  • Thumbnail for Sodium cyclopentadienide
    Johannes Thiele. In 1901 there was not much interest in the topic. Sodium cyclopentadienyl is prepared by treating cyclopentadiene with sodium: 2 Na + 2 C5H6...
    8 KB (797 words) - 19:12, 28 April 2025
  • Thumbnail for Cyclopentadienyliron dicarbonyl dimer
    structure of dicarbonyl-η5-cyclopentadienyl-(η2-tetramethylallenyl)iron tetrafluoroborate. A sterically crowded allene complex". Journal of the Chemical...
    26 KB (2,548 words) - 10:37, 25 May 2025
  • Thumbnail for Metallocene
    A metallocene is a compound typically consisting of two cyclopentadienyl anions (C 5H− 5, abbreviated Cp) bound to a metal center (M) in the oxidation...
    22 KB (2,174 words) - 00:45, 15 January 2025
  • popularly used as a precursor to the cyclopentadienyl anion (Cp−), an important ligand in cyclopentadienyl complexes in organometallic chemistry. Cyclopentadiene...
    13 KB (1,043 words) - 05:40, 13 August 2024
  • Thumbnail for Cyclopentadienyliron dicarbonyl iodide
    Cyclopentadienyliron dicarbonyl iodide (category Cyclopentadienyl complexes)
    and iodide centre. The compound adopts a piano stool structure: the cyclopentadienyl ligand is the "seat" and three other ligands are "legs". Such compounds...
    4 KB (283 words) - 09:35, 7 December 2023
  • Thumbnail for Methylcyclopentadienyl manganese tricarbonyl
    thermal runaway. MMT is a so-called half-sandwich complex, or more specifically a "piano-stool" complex (since the three CO ligands are like the legs of...
    19 KB (2,079 words) - 22:26, 15 February 2025
  • Thumbnail for Cyclopentadienylcobalt dicarbonyl
    an example of a half-sandwich complex. It is a dark red air sensitive liquid. This compound features one cyclopentadienyl ring that is bound in an η5-manner...
    6 KB (484 words) - 11:30, 23 November 2024
  • "WCl4(DME): a facile entry into bis(cyclopentadienyl) complexes of tungsten(IV). Synthesis of bis(cyclopentadienyl)tungsten dihydride". Organometallics...
    60 KB (6,130 words) - 11:46, 22 May 2025
  • chemistry Cross-polarization Cyclopentadienyl complex (Cp), read as "C P", the cyclic C5H5 fragment in a coordination complex The similar symbol Cp* ("C...
    7 KB (920 words) - 15:28, 26 May 2025
  • Thumbnail for Vanadocene
    Vanadocene (category Cyclopentadienyl complexes)
    Vanadocene, bis(η5-cyclopentadienyl) vanadium, is the organometallic compound with the formula V(C5H5)2, commonly abbreviated Cp2V. It is a violet crystalline...
    5 KB (467 words) - 05:36, 16 May 2025
  • Thumbnail for Cobaltocene
    Cobaltocene, known also as bis(cyclopentadienyl)cobalt(II) or even "bis Cp cobalt", is an organocobalt compound with the formula Co(C5H5)2. It is a dark...
    8 KB (620 words) - 19:45, 11 April 2025
  • Thumbnail for Titanocene dichloride
    effected with TiCl4 or by reaction with SOCl2. The sandwich complex (Cycloheptatrienyl)(cyclopentadienyl)titanium is prepared by treatment of titanocene dichloride...
    21 KB (1,771 words) - 20:25, 6 August 2024
  • Thumbnail for Gallium
    diethyl ether to form the trigonal planar gallium cyclopentadienyl complex GaCp3. Gallium(I) forms complexes with arene ligands such as hexamethylbenzene....
    75 KB (8,936 words) - 12:49, 26 May 2025
  • Thumbnail for Chromocene
    in non-polar organic solvents. It is more formally known as bis(η5-cyclopentadienyl)chromium(II). Ernst Otto Fischer, who shared the 1973 Nobel Prize in...
    8 KB (653 words) - 04:39, 28 May 2025
  • Zirconocene dichloride (category Cyclopentadienyl complexes)
    organozirconium compound composed of a zirconium central atom, with two cyclopentadienyl and two chloro ligands. It is a colourless diamagnetic solid that is...
    11 KB (986 words) - 17:38, 23 May 2025
  • Thumbnail for Intermetallic
    to describe compounds involving two or more metals such as the cyclopentadienyl complex Cp6Ni2Zn4. A B2 intermetallic compound has equal numbers of atoms...
    11 KB (1,130 words) - 14:07, 19 March 2025
  • Thumbnail for Bulky cyclopentadienyl ligands
    In the area of organometallic chemistry, a bulky cyclopentadienyl ligand is jargon for a ligand of the type C 5H 5−nR− n where R is a branched alkyl and...
    4 KB (328 words) - 19:01, 27 September 2020
  • Thumbnail for (Cyclopentadienyl)zirconium trichloride
    Being polymeric, complex is insoluble in nonpolar solvents. It dissolves in the presence of basic ligands to give adducts. (Cyclopentadienyl)titanium trichloride...
    2 KB (171 words) - 15:50, 26 December 2023
  • Thumbnail for Organonickel chemistry
    quickly applied in the Mond process for nickel purification. Organonickel complexes are prominent in numerous industrial processes including carbonylations...
    12 KB (1,287 words) - 19:07, 21 April 2025
  • Thumbnail for Manganocene
    Manganocene (category Cyclopentadienyl complexes)
    Manganocene or bis(cyclopentadienyl)manganese(II) is an organomanganese compound with the formula [Mn(C5H5)2]n. It is a thermochromic solid that degrades...
    3 KB (238 words) - 00:22, 19 February 2025
  • Thumbnail for Rhodocene
    between two planar aromatic systems of five carbon atoms known as cyclopentadienyl rings in a sandwich arrangement. It is an organometallic compound as...
    76 KB (7,140 words) - 21:38, 26 May 2025
  • Thumbnail for Ferrocenecarboxylic acid
    Ferrocenecarboxylic acid (category Cyclopentadienyl complexes)
    Ferrocenecarboxylic acid is the organoiron compound with the formula (C5H5)Fe(C5H4CO2H). It is the simplest carboxylic acid derivative of ferrocene. It...
    3 KB (236 words) - 15:31, 2 November 2024
  • Magnesocene (category Cyclopentadienyl complexes)
    Magnesocene, also known as bis(cyclopentadienyl)magnesium(II) and sometimes abbreviated as MgCp2, is an organometallic compound with the formula Mg(η5-C5H5)2...
    15 KB (1,573 words) - 16:01, 4 May 2025
  • Thumbnail for Bis(cyclopentadienyl)titanium(III) chloride
    Bis(cyclopentadienyl)titanium(III) chloride, also known as the Nugent–RajanBabu reagent, is the organotitanium compound which exists as a dimer with the...
    25 KB (2,319 words) - 00:35, 22 November 2024