organometallic chemistry, transition metal complexes of nitrite describes families of coordination complexes containing one or more nitrite (−NO2) ligands. Although...
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Metal nitrosyl complexes are complexes that contain nitric oxide, NO, bonded to a transition metal. Many kinds of nitrosyl complexes are known, which vary...
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Sodium hexanitritocobaltate(III) (category Nitrites)
Na3[Co(NO2)6]. The anion of this yellow-coloured salt consists of the transition metal nitrite complex [Co(NO2)6]3−. It was a reagent for the qualitative test for...
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Pentaamminenitritocobalt(III) chloride (category Cobalt complexes)
academic interest as a source of the transition metal nitrite complex [Co(NH3)5(NO2)]2+. The coordination complexes [Co(NH3)5(NO2)]2+ and [Co(NH3)5(ONO)]2+...
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turn known as ligands or complexing agents. Many metal-containing compounds, especially those that include transition metals (elements like titanium that...
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A transition metal nitrate complex is a coordination compound containing one or more nitrate ligands. Such complexes are common starting reagents for the...
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(96 kJ/mol). Organonitroso compounds serve as a ligands giving transition metal nitroso complexes. Many reactions make use of an intermediate nitroso compound...
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A nitrate nitrite, or nitrite nitrate, is a coordination complex or other chemical compound that contains both nitrite (NO−2) and nitrate (NO−3) anions...
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Azide (section Destruction by oxidation by nitrite)
strong acids: H+ + N−3 → HN3 Azide as a ligand forms numerous transition metal azide complexes. Some such compounds are shock sensitive. Many inorganic covalent...
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Cyanide (section Metal complexation)
com/MEMCyanideTreatment.pdf Sharpe, A. G. The Chemistry of Cyano Complexes of the Transition Metals; Academic Press: London, 1976[page needed] Holleman, A. F...
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stump. In heat treatment of metals as a medium temperature molten salt bath, usually in combination with sodium nitrite. A similar bath is used to produce...
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green smoke. Nickel nitrite was the second transition element anhydrous nitrite discovered after silver nitrite. Nickel nitrite decomposes when heated...
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Diazonium compound (redirect from Metal diazonium complex)
initiator: Alternatively similar borylation can be achieved using transition metal carbonyl complexes including dimanganese decacarbonyl. [C6H5N2]+X− + pinB−Bpin...
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Example for Type-I blue copper protein are plastocyanine , azurin, and nitrite reductase, haemocyanin and tyrosinase. The Blue Copper Proteins, a class...
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stress cracking Transition metal chloride complex Transition metal thiosulfate complex Frankel, G. S. (1998-06-01). "Pitting corrosion of metals: A review of...
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Dinitrogen tetroxide (redirect from Nitronium nitrite)
anhydrous transition metal nitrate complexes can be prepared from N2O4 and base metal. 2 N2O4 + M → 2 NO + M(NO3)2 where M = Cu, Zn, or Sn. If metal nitrates...
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Ligand (section Metal–ligand multiple bond)
functional group that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one...
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3–28, ISBN 978-94-007-0427-5. Baranoff E. 2015, "First-row transition metal complexes for the conversion of light into electricity and electricity into...
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Nitric oxide (section Coordination complexes)
with nitrous oxide release. Nitric oxide reacts with transition metals to give complexes called metal nitrosyls. The most common bonding mode of nitric oxide...
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Nitrogen compounds (section Dinitrogen complexes)
than side-on (η2) donation. Today, dinitrogen complexes are known for almost all the transition metals, accounting for several hundred compounds. They...
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Vanadium(III) chloride (category Metal halides)
1016/S0020-1693(00)86863-2. Manzer, L. E. (1982). "31. Tetragtdrfuran Complexes of Selected Early Transition Metals". Inorganic Syntheses. Vol. 21. pp. 135–140. doi:10...
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Nitrogen (section Dinitrogen complexes)
temperature, but it will nevertheless react with lithium metal and some transition metal complexes. This is due to its bonding, which is unique among the...
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HSAB theory (redirect from Soft metal ion)
so in transition metal chemistry, where numerous experiments have been done to determine the relative ordering of ligands and transition metal ions in...
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certain organic nitrates, nitrosylated metal complexes, dinitrosyl iron complexes (DNIC), and even nitrite anions (NO2− ) under hypoxic conditions A...
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TNT or tetryl. Under certain conditions a deflagration to detonation transition can occur, just like that of ammonium nitrate. It is rarely used alone...
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diazotisation reaction of 2-aminothiophenol or its disulfide with sodium nitrite, as originally reported in 1887 and reviewed in several subsequent publications...
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Pentamethylcyclopentadienyl iridium dichloride dimer (category Pentamethylcyclopentadienyl complexes)
chloride ligands can also be replaced by other anions such as carboxylates, nitrite, and azide. Reduction of [Cp*IrCl2]2 in the presence of CO affords [Cp*Ir(CO)2]...
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Cumulene (section Transition metal heterocumulenes)
terminal vinylidene metal complex chemistry through the dicyanomethylene/oxygen analogy: dicyanovinylidene transition metal complexes". Coordination Chemistry...
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β-Elimination, Stability and Trapping of Transient Species by Coordination to Transition Metal Atoms". Chemistry – A European Journal. 25 (18): 4793–4807. doi:10...
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Trofimenko, Swiatoslaw (1970). "Poly(1-pyrazolyl)borates, Their Transition-Metal Complexes, and Pyrazaboles". Inorganic Syntheses. Vol. 12. pp. 99–109. doi:10...
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