A transition metal carbene complex is an organometallic compound featuring a divalent carbon ligand, itself also called a carbene. Carbene complexes have...

dichlorocarbene. Transition metal carbene complexes Atomic carbon a single carbon atom with the chemical formula :C:, in effect a twofold carbene. Also has been...

carbene is a type of transition metal carbene complex, which is an organometallic compound containing a divalent organic ligand. In a Fischer carbene...

carbyne complexes react with electrophiles at C-carbyne followed by association of the anion. The net reaction gives a transition metal carbene complex: LnM≡CR...

In coordination chemistry, a transition metal NHC complex is a metal complex containing one or more N-heterocyclic carbene ligands. Such compounds are...

  No carbene complex with element known Carbenes can be stabilised as organometallic species. These transition metal carbene complexes fall into two...

effective In this reaction type the active intermediate is a transition metal carbene complex. A diazo cross-coupling reaction has also been reported between...

Metal carbonyls are coordination complexes of transition metals with carbon monoxide ligands. Metal carbonyls are useful in organic synthesis and as catalysts...

carbene formation at an open-shell transition metal complex (in particular low-spin cobalt(II) complexes) using diazo compounds and related carbene precursors...

A transition metal imidazole complex is a coordination complex that has one or more imidazole ligands. Complexes of imidazole itself are of little practical...

hrs. 80% chemical yield. The first step is formation of the Transition metal carbene complex 2. Acetic acid adds to this intermediate in a nucleophilic...

In chemistry, a transition metal pincer complex is a type of coordination complex with a pincer ligand. Pincer ligands are chelating agents that binds...

scholarly and practical interest. transition metal carbene complexes catalyze the olefin metathesis reaction. Metal oxo intermediates are pervasive in...

In coordination chemistry and organometallic chemistry, transition metal imido complexes is a coordination compound containing an imido ligand. Imido ligands...

diazo compound on the metal center generates a zwitterionic metal alkyl complex, which expels nitrogen gas to afford a metal carbene intermediate. Concerted...

Coinage metal N-heterocyclic carbene (NHC) complexes refer to transition metal complexes incorporating at least one coinage metal center (M = Cu, Ag,...

An N-heterocyclic carbene boryl anion is an isoelectronic structure of an N-heterocyclic carbene (NHC), where the carbene carbon is replaced with a boron...

Transition metal isocyanide complexes are coordination compounds containing isocyanide ligands. Because isocyanides are relatively basic, but also good...

two alkenes. It is a catalytic reaction with carbene, or more accurately, transition metal carbene complex intermediates. In this example (ethenolysis...

Numerous mesoionic carbene transition metal complexes are known with metals including Fe, Os, Rh, Ir, Ni, Pd, Pt, Cu, and Ag. Metal complexes with Sm and Y...

palladium-NHC complexes are a family of organopalladium compounds in which palladium forms a coordination complex with N-heterocyclic carbenes (NHCs). They...

Metal acetylacetonates are coordination complexes derived from the acetylacetonate anion (CH 3COCHCOCH− 3) and metal ions, usually transition metals. The...

removes metal molecules to form a highly porous, near-pure carbon material capable of high-density energy storage. transition metal carbene complexes. two-dimensional...

Grubbs catalysts are a series of transition metal carbene complexes used as catalysts for olefin metathesis. They are named after Robert H. Grubbs, the...

(2005-09-05). "Stable Cyclic (Alkyl)(Amino)Carbenes as Rigid or Flexible, Bulky, Electron-Rich Ligands for Transition-Metal Catalysts: A Quaternary Carbon Atom...

figure below. Terminal transition-metal-complexed phosphinidenes LnM=P-R are phosphorus analogs of transition metal carbene complexes where L is a spectator...

Tung-Ying; Lee, Gene-Hsiang; Peng, Shie-Ming (1998-03-01). "Carbene Transfer between Transition-Metal Ions". Organometallics. 17 (6): 993–995. doi:10.1021/om9709897...

allows them to function as ligands in a variety of main group and transition metal complexes.  Carbone-coordinated elements also exhibit a variety of different...

shield the germanium center. Dicationic complexes of Ge(II) have been isolated with bulky isocyanide and carbene ligands. Much more weakly coordinated Germanium...

First Example of a Bis(trifluoromethyl)carbene Transition-Metal Complex and Its Reduction to a Perfluoroallene Complex". European Journal of Inorganic Chemistry...