Amide reduction is a reaction in organic synthesis where an amide is reduced to either an amine or an aldehyde functional group. Catalytic hydrogenation...
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In organic chemistry, an amide, also known as an organic amide or a carboxamide, is a compound with the general formula R−C(=O)−NR′R″, where R, R', and...
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Organic redox reaction (redirect from Organic reduction)
compounds Carbonyl reduction Amide reduction Nitrile reduction Reduction of nitro compounds Reduction of imines and Schiff bases Reduction of aromatic compounds...
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substrates for the Wolff–Kishner reduction as demonstrated by the example above. Coe and coworkers found however that a twisted amide can be efficiently reduced...
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Nicotinamide (redirect from Nicotinic acid amide)
B family of medications, specifically the vitamin B3 complex. It is an amide of nicotinic acid. Foods that contain niacinamide include yeast, meat, milk...
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Weinreb ketone synthesis (redirect from Weinreb amide)
reported the synthesis of aldehydes by reduction of the amide with an excess of lithium aluminum hydride (see amide reduction). The major advantage of this method...
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Stephen aldehyde synthesis (redirect from Stephen reduction)
salt is obtained from reaction of an amide PhCONHPh with phosphorus pentachloride. Amide reduction Nitrile reduction Pinner reaction – a similar reaction...
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reductive amination. Ester reduction of Eudesmic acid's methyl ester followed by halogenation, Kolbe nitrile synthesis, and nitrile reduction. Amide reduction...
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Rhenium trioxide finds some use in organic synthesis as a catalyst for amide reduction. H. Nechamkin, C. F. Hiskey, "Rhenium(VI): Oxide (Rhenium Trioxide)"...
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forming a thioester or a Weinreb amide, then reducing the new species to an aldehyde through the Fukuyama reduction or Weinreb reaction respectively,...
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(see: carbonyl reduction). Similarly, it converts amide, nitro, nitrile, imine, oxime, and organic azides into the amines (see: amide reduction). It reduces...
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in organic synthesis as a catalyst for ethenolysis, carbonyl reduction and amide reduction. "Rhenium(VII) oxide". pubchem.ncbi.nlm.nih.gov. Retrieved 14...
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Amine (section Reductive routes)
substituted-ammonium carboxylate salt → dehydration heat N | R 2 R 1 | − C O ‖ − R 3 ⏟ amide + H 2 O ⏟ water {\displaystyle {\underbrace {\ce {H-\!\!{\overset {\displaystyle...
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requires the chemist to use a higher ratio of catalyst to reagents. Amide reduction Elements, American. "Copper Chromite". American Elements. Retrieved...
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Ergine (redirect from Lysergic acid amide)
Ergine, also known as d-lysergic acid amide (LSA) and d-lysergamide, is an ergoline alkaloid that occurs in various species of vines of the Convolvulaceae...
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Urea (redirect from Carbonyl amide)
formula CO(NH2)2. This amide has two amino groups (–NH2) joined by a carbonyl functional group (–C(=O)–). It is thus the simplest amide of carbamic acid. Urea...
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and its primary amide, L-glutamine (also a proteinogenic amino acid). Theanine is a derivative of glutamine that is ethylated on the amide nitrogen (as the...
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Acetamide (redirect from Acetic acid amide)
methyl (CH3) groups either side of the carbonyl (CO), and urea which has two amide (NH2) groups in those locations. Acetamide is also a naturally occurring...
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primary amines. In general, oximes can be changed to the corresponding amide derivatives by treatment with various acids. This reaction is called Beckmann...
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the brand name Xylocaine among others, is a local anesthetic of the amino amide type. It is also used to treat ventricular tachycardia. When used for local...
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in place of 'amide' in systematic or retained names of amides. (…) However, names expressing N-substitution by a phenyl group on an amide are preferred...
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Metal bis(trimethylsilyl)amides (redirect from Metal bis(trimethylsilyl)amide)
complexes composed of a cationic metal M with anionic bis(trimethylsilyl)amide ligands (the −N(Si(CH3)3)2 monovalent anion, or −N(Si(CH3)3)2 monovalent...
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Carboxylic acid (section Reduction)
group tends to dimerise to form oxalic acid. Acid anhydride Acid chloride Amide Amino acid Ester List of carboxylic acids Dicarboxylic acid Pseudoacid Thiocarboxy...
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from the Sanskrit word ananda, which means "joy, bliss, delight", plus amide. Anandamide is derived from the non-oxidative metabolism of arachidonic...
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Butyramide is the amide of butyric acid. It has the molecular formula C3H7CONH2. It is a white solid that is freely soluble in water and ethanol, but...
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Anesthetic (section Amide-Based)
suffix "–caine" in their names. Local anesthetics can be either ester- or amide-based. Ester local anesthetics are generally unstable in solution and fast-acting...
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may also increase the length of labor. It is a local anaesthetic of the amide group. Bupivacaine was discovered in 1957. It is on the World Health Organization's...
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15227/orgsyn.012.0062. Fujita, M.; Hiyama, T. (1990). "Directed Reduction of a beta-keto Amide: Erythro-1-(3-hydroxy-2-methyl-3-phenylpropanoyl)piperidine"...
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